Flavin Catalysts in Organic Synthesis
Flavins and their congeners are potent catalysts for organic synthesis inspired by enzymatic transformations. In addition to catalysis in the flavin ground state via covalent intermediates, the excited singlet and triplet states unlock applications including photooxidation, photoreduction, and energy transfer via sensitization.
Jan Freudenberg, Golo Storch
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<i>Lacticaseibacillus paracasei</i> LP36 Alleviates Lipopolysaccharide-Induced Depression-like Behavior in Mice: A Serum Metabolomics Study. [PDF]
Chen Q +10 more
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Gal‐SeNBD‐oleamide is an activatable photosensitizer (PS) with efficient uptake and selective, β‐galactosidase‐triggered activation in cancer cells, enabling efficient photodynamic ablation of glioma cells directly in brain tissue slices from mouse preclinical models and human glioblastoma patients.
Utsa Karmakar +18 more
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Aza-Michael Quaternization: Addition of Tertiary Amines to Allenic Michael Acceptors Furnishes Quaternary Ammonium Compounds. [PDF]
Lin R +3 more
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Cobalt‐Catalyzed [2σ+2π] Cycloaddition via Site‐Selective Capture of Bicyclobutane Diradical
We report a Co(II)‐catalyzed strategy that combines thermal activation of bicyclo[1.1.0]butane (BCBs) with site‐selective radical capture to furnish head‐to‐head fused bicyclo[2.1.1]hexanes via [2σ+2π] cycloaddition with indoles. Detailed mechanistic studies (31P NMR, EPR, CV, and DFT) support the catalytic pathway, while phosphine‐oxide trapping and X‐
Tanmayee Nanda +8 more
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Structural Evolution of RAFT-Modified Unsaturated Polyester Copolymers: Effects of CPDT Concentration, Acidic Comonomer Structure, and Polyester Matrix Architecture. [PDF]
Zhunissova MS +8 more
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The first nitrile reductive couplings beyond stoichiometric metals or metalloids are described. Using a ruthenium catalyst derived from RuHCl(CO)(PPh3)3 and Cy‐BIPHEP, 2‐propanol‐mediated reductive coupling of phenyl acrylate with aromatic or aliphatic nitriles delivers α,β‐unsaturated β‐amino esters.
Sebastian Höthker +3 more
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UV-Synthesized Polyacrylamide-Based Polymer Sensor for Measuring Soil-Water Characteristic Curves in Unsaturated Soils. [PDF]
Arinova A +6 more
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Recrystallization-Controlled Strength Evolution and Prediction of Compacted Rock-Salt Fills. [PDF]
Wang L +6 more
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Acyclic Hydrocarbon α,ω-Dienes: From Biomass and Plastic Upcycling to Carbocycles, Precision Polymers, and Cross-Linked Elastomers. [PDF]
Villaccio R, Leone G.
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