Results 31 to 40 of about 23,734 (254)

Kinetic‐Directed Thermodynamic Repair Enables the Synthesis of High‐Strain 2D Sub‐Stoichiometric COFs

open access: yesAdvanced Science, EarlyView.
2D covalent organic frameworks are promising photocatalysts. Yet, precise synthesis of sub‐stoichiometric COFs remains challenging due to poor kinetic control. We propose a general strategy: tuning polymerization degree of kinetic intermediates via time or solvent polarity directs their thermodynamic repair into highly crystallization. Using [4+3]‐type
Xiang Pei   +8 more
wiley   +1 more source

Nanowires Reinforce Oriented Macroporous Aerogels for Rapid Uranium Removal from Acidic Radioactive Wastewater

open access: yesAdvanced Science, EarlyView.
A “reinforced concrete” structural aerogel with directional microchannels is engineered for rapid uranium capture. The interconnected architecture enables ultrafast water permeation, and the nanowire reinforcement yields a 70‐fold increase in mechanical strength.
Ze Liu   +8 more
wiley   +1 more source

ABCABC Stacking‐Enabled Non‐Centrosymmetry 3R‐ZnIn2S4 Nanosheets for Piezocatalytic Uranium Extraction

open access: yesAdvanced Science, EarlyView.
The ABCABC stacking sequence in 2D ZnIn2S4 nanosheets creates intrinsic non‐centrosymmetry, enabling robust piezocatalysis under weak mechanical agitation. The nanosheets achieve a H2O2 yield of 276.7 µmol g−1 h−1 and uranium extraction capacity of 763.2 mg g−1 via a dual mechanism of direct piezoreduction and in situ H2O2 complexation.
Song Li   +6 more
wiley   +1 more source

Metal‐Half‐Salen Chemistry for One‐Pot Mineralization on Hydrophobic Polymer Membranes

open access: yesAdvanced Science, EarlyView.
Here we report a versatile one‐pot synthetic strategy for organic–inorganic composite membranes, which leverages a metal half‐Salen system to precisely govern the competing kinetics of coordination and hydrolysis. In contrast to conventional two‐step metal‐phenol chemistries, our integrated approach substantially simplifies the fabrication process ...
Rou‐Ming Wen   +8 more
wiley   +1 more source

A Physically Constrained and Library-Guided Convolutional Autoencoder for Mineral Hyperspectral Unmixing

open access: yesRemote Sensing
Hyperspectral unmixing is an important technique for mineral mapping because natural geological scenes commonly contain mixed pixels composed of multiple spectrally overlapping materials.
Yuxi Hao   +6 more
doaj   +1 more source

Refined Deformable-DETR for Electric Pylon Detection Based on Optical Satellite Image

open access: yesSensors
Automatic detection of electric pylons in optical remote sensing imagery is important for large-scale powerline monitoring, but remains challenging due to complex backgrounds, small target appearances, and large variations in pylon-shadow structures ...
Jun Yang   +5 more
doaj   +1 more source

Uranium–nitride chemistry: uranium–uranium electronic communication mediated by nitride bridges

open access: yesDalton Transactions, 2022
Sequential reduction of a uranium-azide through all the nitride steps is revealed. Experimentally determined U–U coupling in the diuranium(iv)–dinitride is shown byab initiocalculations to stem from the nitride bridges, not U–U bonding.
David M. King   +7 more
openaire   +3 more sources

A Systemic Model for Understanding Business Interactions With Biodiversity and Ecosystems

open access: yesBusiness Strategy and the Environment, EarlyView.
ABSTRACT Biodiversity loss and ecosystem degradation represent critical threats to human well‐being and economic resilience, challenging businesses to understand and manage their interdependence with natural systems. This study develops a systemic framework—the BioModel—that elucidates the reciprocal relationship between businesses, biodiversity, and ...
Lino Cinquini   +2 more
wiley   +1 more source

Evaluation of uranium migration during the maturation of hydrocarbon source rocks

open access: yesScientific Reports
The source of uranium is an important research topic related to the exploration of sandstone-type uranium deposits, and potential uranium sources in deep basins are often overlooked.
Junxian Wang   +6 more
doaj   +1 more source

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