Results 41 to 50 of about 7,206 (242)
Crystallographic characterization of (C5H4SiMe3)3U(BH4)
Acta Crystallographica Section E: Crystallographic Communications, 2021 New syntheses have been developed for the synthesis of (borohydrido-κ3H)tris[η5-(trimethylsilyl)cyclopentadienyl]uranium(IV), [U(BH4)(C8H13Si)3] or Cp′3U(BH4) (Cp′ = C5H4SiMe3) and its structure has been determined by single-crystal X-ray crystallography.
Cory J. Windorff +4 more
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Advanced Science, EarlyView.Conjugated poly(imide dioxime)‐based microspheres establish a radiometal coordination‐driven conformational interlocked network with ultra‐high radiostability. This platform enables low‐temperature, multi‐radionuclide labeling for SPECT/PET/MRI imaging and radionuclide therapy. Mechanistic insights from EXAFS and DFT reveal enhanced stability, while in
Xiao Xu +10 more
wiley +1 more source
Modern x-ray spectral methods in the study of the electronic structure of actinide compounds: Uranium oxide UO2 as an example [PDF]
Nuclear Technology and Radiation Protection, 2004 Fine X-ray photo electron spectral (XPS) structure of uranium dioxide UO2 in the binding energy (BE) range 0-~č40 eV was associated mostly with the electrons of the outer (OVMO) (0-15 eV BE) and inner (IVMO) (15-40 eV BE) valence molecular orbitals ...
Teterin Yury A., Teterin Anton Yu.
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Advanced Science, EarlyView.2D covalent organic frameworks are promising photocatalysts. Yet, precise synthesis of sub‐stoichiometric COFs remains challenging due to poor kinetic control. We propose a general strategy: tuning polymerization degree of kinetic intermediates via time or solvent polarity directs their thermodynamic repair into highly crystallization. Using [4+3]‐type
Xiang Pei +8 more
wiley +1 more source
Cuadernos de Investigación Geográfica, 2013 Tailings deposits from gold- and uranium mining usually contain elevated amounts of radioactive and chemotoxical heavy metals. By seepage dissolved uranium and other contaminants migrate from tailings deposits via groundwater into adjacent fluvial ...
F. Winde
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Advanced Science, EarlyView.A “reinforced concrete” structural aerogel with directional microchannels is engineered for rapid uranium capture. The interconnected architecture enables ultrafast water permeation, and the nanowire reinforcement yields a 70‐fold increase in mechanical strength.
Ze Liu +8 more
wiley +1 more source
Uranium fluoride micromaterials: a new frontier in nuclear engineering
Frontiers in Nuclear EngineeringThis perspective explores recent advancements in the synthesis and application of uranium fluoride micromaterials, emphasizing their role in the nuclear industry.
Harry Jang, Frederic Poineau
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Вестник войск РХБ защиты, 2023 The intention of the collective West to supply the armed forces of Ukraine with armor-piercing shells with cores (penetrators) made of depleted uranium (DU), is changing the situation in the zone of special military operation (SVO). A new damaging factor
M. V. Supotnitskiy
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Advanced Science, EarlyView.The ABCABC stacking sequence in 2D ZnIn2S4 nanosheets creates intrinsic non‐centrosymmetry, enabling robust piezocatalysis under weak mechanical agitation. The nanosheets achieve a H2O2 yield of 276.7 µmol g−1 h−1 and uranium extraction capacity of 763.2 mg g−1 via a dual mechanism of direct piezoreduction and in situ H2O2 complexation.
Song Li +6 more
wiley +1 more source
Metal‐Half‐Salen Chemistry for One‐Pot Mineralization on Hydrophobic Polymer Membranes
Advanced Science, EarlyView.Here we report a versatile one‐pot synthetic strategy for organic–inorganic composite membranes, which leverages a metal half‐Salen system to precisely govern the competing kinetics of coordination and hydrolysis. In contrast to conventional two‐step metal‐phenol chemistries, our integrated approach substantially simplifies the fabrication process ...
Rou‐Ming Wen +8 more
wiley +1 more source