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Urea–formaldehyde resin prepared with concentrated formaldehyde
Journal of Adhesion Science and Technology, 2016AbstractThe characteristics of UF resin prepared with concentrated formaldehyde were studied in this paper. With the molar ratio F/U = 1.1, the UF resin prepared with concentrated formaldehyde showed better mechanical properties than that with formalin. The 13C-NMR and FTIR results indicated that there were more methylene groups, ether groups and urons
Zhigang Wu +5 more
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Journal of Applied Polymer Science, 2006
AbstractColloidal particles formation followed by their clustering have been shown to be the normal way of ageing of aminoplastic resins, namely urea–formaldehyde (UF) resins, melamine–formaldehyde (MF) resins, and melamine–urea–formaldehyde (MUF) resins. Ageing or further advancement of the resin by other means such as longer condensation times causes
A. Despres, A. Pizzi
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AbstractColloidal particles formation followed by their clustering have been shown to be the normal way of ageing of aminoplastic resins, namely urea–formaldehyde (UF) resins, melamine–formaldehyde (MF) resins, and melamine–urea–formaldehyde (MUF) resins. Ageing or further advancement of the resin by other means such as longer condensation times causes
A. Despres, A. Pizzi
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Journal of Polymer Science Part B: Polymer Physics, 2008
AbstractPercolation and effective‐medium theories are applied for calculating the connectivity threshold of colloid particles of given shapes, observed during the physical gelation, distinguished from chemical gelation, of aminoplastic resins. The rigidity threshold, being the critical solid fraction at which a rigid network is first formed, was also ...
Celzard, A., Pizzi, Antonio, Fierro, V.
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AbstractPercolation and effective‐medium theories are applied for calculating the connectivity threshold of colloid particles of given shapes, observed during the physical gelation, distinguished from chemical gelation, of aminoplastic resins. The rigidity threshold, being the critical solid fraction at which a rigid network is first formed, was also ...
Celzard, A., Pizzi, Antonio, Fierro, V.
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The structure of urea—formaldehyde resins
Journal of Applied Polymer Science, 1988Fourier transform infrared (FTIR) spectroscopy has been used as a modern analytical tool to elucidate the structure of urea—formaldehyde (UF) resins. Several low molecular weight condensation products of urea and formaldehyde were synthesized and characterized.
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Decreasing the Content of Free Formaldehyde in Urea-Formaldehyde Resins
Russian Journal of Applied Chemistry, 2005The possibility of decreasing the content of free formaldehyde in urea-formaldehyde resins by varying the pH and urea-formaldehyde ratio in various synthesis steps was examined. Urea-formaldehyde resins containing no free formaldehyde were prepared.
V. Z. Maslosh +2 more
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Fibers from urea–formaldehyde resins
Journal of Applied Polymer Science, 2000The preparation of fibers from aqueous urea–formaldehyde resins has been investigated; a dry spinning process has been developed based on the extrusion of catalyzed resin into a drying chamber at 180–220°C, producing a multifilament yarn at spinning speeds of up to 600 m/min.
V. Rogers‐Gentile +3 more
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Formaldehyde Liberation and Cure Behavior of Urea-Formaldehyde Resins
Holzforschung, 1990On a etudie par calorimetrie differentielle a balayage le comportement au durcissement de plusieurs adhesifs uree-formaldehyde pour bois qui contenaient differents systemes de catalyseurs et agents ...
George E. Myers, James A. Koutsky
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Rheokinetics of urea-formaldehyde resins gelation
Rheologica Acta, 1996Rheokinetics of gelation of aqueous suspensions of urea-formaldehyde oligomers was studied. Experiments were carried out with a rotational viscometry method using two regimes of deformation: constant stress or constant shear rate. It was shown that a maximum on a viscosity vs.
Sergei G. Kulichikhin +2 more
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Hantzsch reaction in urea-formaldehyde resins
Russian Journal of Applied Chemistry, 2008The effect of acetylacetone and ammonia in urea-formaldehyde resins on the reactions occurring in their presence was examined. The formation of 2,6-dimethyl-3,5-diacetyl-l,4-dihydropyridine in urea-formaldehyde resins was confirmed by 1H NMR spectroscopy.
V. V. Kotova +3 more
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Uron and uron-urea-formaldehyde resins
Journal of Applied Polymer Science, 1999The favored pH ranges for the formation of urons in urea-formaldehyde (UF) resins preparation were determined, these being at pH's higher than 6 and lower than 4 at which the equilibrium urons N,N′-dimethylol ureas are shifted in favor of the cyclic uron species. Shifting the pH slowly during the preparation from one favorable range to the other causes
C. Soulard, C. Kamoun, A. Pizzi
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