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Chemical modification of usnic acid 2. Reactions of (+)-usnic acid with amino acids

Russian Chemical Bulletin, 2007
The condensation of amino acids with (+)-usnic acid involves the 2-positioned acetyl group of the latter and gives derivatives containing an enamine fragment.
O. A. Luzina   +3 more
openaire   +1 more source

Anti-inflammatory activity of (+)-usnic acid

Fìtoterapìâ, 2000
(+)-Usnic acid, isolated from the lichen Roccella montagnei, showed a dose-dependent anti-inflammatory activity when tested on rats, employing acute and chronic models.
Ethirajan Sukumar
exaly   +3 more sources

ChemInform Abstract: USNIC ACID. XIV. THE PHOTO‐OXIDATION OF USNIC ACID

Chemischer Informationsdienst, 1979
AbstractDie Belichtung von (I) in Gegenwart von Sauerstoff ergibt das Spaltprodukt (l1).
K. TAKAHASHI, M. TAKANI
openaire   +1 more source

Chemical modification of usnic acid 1. Reaction of (+)-usnic acid with perfluoroolefins

Russian Chemical Bulletin, 2007
The reactions of the natural lichen metabolite, (+)-usnic acid, with a series of commercially available polyfluoroolefins (tetrafluoroethylene, chlorotrifluoroethylene, hexafluoropropene, perfluoro-2-methylpent-2-ene, and 1,2-dichlorooctafluorocyclohex-1-ene) afford its 7-O-polyfluoroalkyl and perfluorovinyl ethers.
G. G. Furin   +5 more
openaire   +1 more source

Studies in the usnic acid series. II. The condensation of (+)-usnic acid with hydroxylamine

Canadian Journal of Chemistry, 1976
The results of the reaction of usnic acid (1) with hydroxylamine are presented. Four products, two isomeric isoxazoles (2 and 4), a novel oxazocine structure (3), and Δ2,11-enaminousnic acid (5) were isolated and characterized. These data clarify the earlier published results in this area.
James P. Kutney   +2 more
openaire   +1 more source

Studies in the usnic acid series. V. The base catalyzed usnic acid – isousnic acid rearrangement. Part III. (—)-Usnic acid isomethoxide monoacetate

Canadian Journal of Chemistry, 1977
Further studies on the base catalyzed usnic acid – isousnic acid rearrangement process clarify the situation concerning (−)-usnic acid isomethoxide monoacetate (7). This substance is now shown to be a mixture of the two possible C4a epimers. These and previous data allow a mechanism to be proposed for this interesting rearrangement.
James P. Kutney, Ignacio H. Sanchez
openaire   +1 more source

A colorimetric method for the estimation of usnic acid

Analytical Biochemistry, 1968
Abstract A simple method has been developed for the estimation of usnic acid by an adaptation of the qualitative test described by Asahina and Shibata (1) with appropriate modifications under regulated conditions. Some factors affecting the formation of color have been studied.
N P, Jayasankar, G H, Towers
openaire   +2 more sources

Enzyme immunoassay of usnic acid in lichens

Applied Biochemistry and Microbiology, 2013
An enzyme immunoassay for usnic acid in lichens was developed, the sensitivity of which was 0.1 microg/g of air-dried material (0.00001%). Polyclonal rabbit antibodies against bovine serum albumin conjugated to (+)-usnic acid under the conditions of formaldehyde condensation made it possible to determine the analyzed substance in solutions at ...
A A, Burkin   +2 more
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Chemical modification of usnic acid: III.* Reaction of (+)-usnic acid with substituted phenylhydrazines

Russian Journal of Organic Chemistry, 2009
Reactions of (+)-usnic acid with a number of substituted (halo, alkyl, alkoxy, nitro) phenylhydrazines led to the formation of the corresponding benzofuro[3,2-f]indazole derivatives or hydrazones at the acetyl group on C2, depending on the initial hydrazine.
O. A. Luzina   +3 more
openaire   +1 more source

In vitro risk assessment of usnic acid

Toxicology and Industrial Health, 2013
Lichens are symbiotic organisms composed of fungi and algae and are very common in Turkey. Lichen secondary metabolites are mainly phenolic compounds produced by fungal partner of lichen symbiosis. Usnic acid (UA) is one of the most common lichen metabolites, and it was reported that to be effective for a wide range of pharmacological purposes ...
Aydin, Elanur   +3 more
openaire   +4 more sources

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