Results 151 to 160 of about 333,648 (309)

In Situ UV–Vis–NIR Absorption Spectroscopy and Catalysis

open access: yesChemical Reviews
This review highlights in situ UV-vis-NIR range absorption spectroscopy in catalysis. A variety of experimental techniques identifying reaction mechanisms, kinetics, and structural properties are discussed. Stopped flow techniques, use of laser pulses, and use of experimental perturbations are demonstrated for in situ studies of enzymatic, homogeneous,
Max L. Bols   +9 more
openaire   +4 more sources

Modulating Iridium Electronic Structure With High‐Valent Metal Doping for Efficient and Durable Acidic Oxygen Evolution Reaction

open access: yesAdvanced Functional Materials, EarlyView.
We synthesized a novel IrCuOx/MnO2 heterostructure co‐doped with high‐valent W and Mo atoms, achieving exceptional acidic stability and high mass activity. Owing to the synergistic effects of structural and electronic modulation, cooperative charge redistribution occurs across both the interface and the lattice.
Minseo Kim   +17 more
wiley   +1 more source

Receptor‐Free Identification of Toxic Gases Enabled by Hygroscopic Aqueous Salt Films

open access: yesAdvanced Functional Materials, EarlyView.
Water as a gas sensor coating sounds impossible—until it stops evaporating. Here, hygroscopic salt solutions (LiCl, LiBr, H3PO4) form non‐drying aqueous films on CNT chemiresistors under ambient air. Gases partition into these liquid layers, sometimes transforming into water, and generate salt‐specific resistance fingerprints across a four‐channel ...
Seongwoo Lee   +5 more
wiley   +1 more source

Halide‐Dependent Photoluminescence and Heavy‐Atom Effects in Low‐Melting Organic–Inorganic Manganese Halides

open access: yesAdvanced Functional Materials, EarlyView.
Two pyridinium‐based ionic liquid templated hybrid manganese halides, (C4Py)2[MnCl4] and (C4Py)2[MnBr4], display similar bulk structures but show significantly different photoluminescence behaviors due to the bromine heavy‐atom effect. Their stable local Mn environments remain intact even in the molten state, allowing applications such as luminescence ...
Biswajit Bhattacharyya   +22 more
wiley   +1 more source

Auger electron spectroscopy, secondary ion mass spectroscopy and optical characterization of a-C-H and BN films [PDF]

open access: yes
The amorphous dielectrics a-C:H and BN were deposited on III-V semiconductors. Optical band gaps as high as 3 eV were measured for a-C:H generated by C4H10 plasmas; a comparison was made with bad gaps obtained from films prepared by CH4 glow discharges ...
Alterovitz, S. A.   +2 more
core   +1 more source

Electrolyte Design Strategies for Static Shuttle‐Free and Long‐Life Aqueous Zinc‐Iodine Batteries

open access: yesAdvanced Functional Materials, EarlyView.
This review systematically summarizes recent advances in electrolyte design for static aqueous Zn‐I2 batteries, highlighting solvation regulation and interfacial engineering strategies to control reaction kinetics, suppress iodine shuttling, enhance energy density, and stabilize multi‐electron iodine redox chemistry for durable, high‐performance energy
Qianqin Zhou   +3 more
wiley   +1 more source

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