Results 101 to 110 of about 29,030 (208)

Chemical Switching Between B2N and B2C Homoaromaticity

Angewandte Chemie, EarlyView.
We report the synthesis of homoaromatic 1‐aza‐2,4‐diazadiboretane with a bicyclic four‐membered NB2C motif and demonstrate experimentally and theoretically that the homoaromatic delocalization can also be chemically shifted from the B2N to the B2C moiety by deprotonation of the ring carbon atom.
Tim Wiesmeier, Philipp Grewelinger, Carsten Präsang, Bernd Morgenstern, Diego M. Andrada, David Scheschkewitz   +5 more
wiley   +2 more sources

Evaluation of therapeutic effects of D‐limonene following orchiopexy in the rat model of cryptorchidism

Animal Models and Experimental Medicine, EarlyView.
D‐limonene supplementation enhances testicular recovery following orchiopexy in a rat model of bilateral cryptorchidism. Treatment with D‐limonene reduces oxidative stress (↓MDA, ↑SOD, ↑GPx, ↑TAC), downregulates pro‐apoptotic proteins (↓TNF‐α, ↓BAX, ↓Caspase‐3), and upregulates anti‐apoptotic Bcl‐2 expression.
Arman Norouzi‐Ghalehbala, Mohammadjavad Rezaei‐Varmaziar, Majid Taati, Ali Soleimanzadeh, Abbas Raisi, Farshid Davoodi, Amir Ali Shahbazfar   +6 more
wiley   +1 more source

Caging Polyhalide Anions in Polycyclodextrin for Long‐Lasting Aqueous Zinc‐Iodine Batteries

Angewandte Chemie, EarlyView.
We demonstrated poly(β‐cyclodextrin) gel as an ideal host material that effectively contains and releases polyhalide anions in aqueous zinc‐iodine batteries. Such a unique host‐guest chemistry prevents the shuttle effect of polyhalides. The corresponding batteries can operate via both 2e and 4e storage, attaining 60,000 cycles with more than 99% and 85%
Shangxu Jiang, Zhipeng Pei, Yanlin Shi, Kai Zhang, Justin M. Chalker, Sara J. Fraser‐Miller, Michelle L. Coote, Zhongfan Jia   +7 more
wiley   +2 more sources

Agostic Hydridoborate Complexes as Masked Coinage‐Metal Hydrides: Hydride Migration Between Boron and Gold Unlocks CO2 Reactivity

Angewandte Chemie, EarlyView.
Hydride addition to coinage‐metal diphosphine–borane complexes gives unprecedented Cu(I), Ag(I), and Au(I) hydridoborates featuring agostic σ(B–H)→M interactions. While, Cu and Ag derivatives are inert toward CO2, the Au analogue reversibly fixes CO2 and catalyzes its hydroboration as well as formic acid dehydrogenation through a cooperative B─H─Au ...
Balakrishna Peddi, Sonia Mallet‐Ladeira, Karinne Miqueu, Ghenwa Bouhadir, Didier Bourissou   +4 more
wiley   +2 more sources

Epitaxial Oxide Interfaces Create Poison‐Resistant CuO Sites for Environmental Catalysis

Angewandte Chemie, EarlyView.
An epitaxially stabilized CuO overlayer on Ti1−xInxO2 creates electron‐poor, high‐symmetry Cu–O sites that activate interfacial lattice‐oxygen redox. This interface promotes NOx reduction through an Eley–Rideal pathway, diverts sulfate formation, and sustains CH3SH deep oxidation via a Mars–van Krevelen cycle, offering a route to poison‐resistant ...
Lupeng Han, Yanqing Li, Yongjie Shen, Huijun Yu, Evangelina Pensa, Xuehui Yang, Yanqi Chen, Xiaonan Hu, Xiyang Wang, Song Li, Gaowu Qin, Wenqiang Qu, Ming Xie, Emiliano Cortés, Dengsong Zhang   +14 more
wiley   +2 more sources

Reliability and performance modeling of an M[X]/G(a,b)/1 retrial queue with re-service and Balking behavior under working vacation policy. [PDF]

PLoS One
S S, S N.
europepmc   +1 more source

Legionnaires Disease Associated with a Private-Use Hot Tub in a Vacation Rental Property - New York, October 2024-April 2025. [PDF]

MMWR Morb Mortal Wkly Rep
Morse M, Zartarian M, Savage B, O'Connor P, Nicholas D, Jones H, Gil C, Wroblewski D, Chmura S, Biswas N, Bocketti C, Willard G, Blumerman S, Hattenrath T, Gowie D, Mingle L, Lauper U.   +16 more
europepmc   +1 more source

Paid Time Off Pressure in Emergency Medicine: Vacation Conflict Risk in the Context of Group Size, and Shift Coverage. [PDF]

J Emerg Med
Sebro R.
europepmc   +1 more source

The impact of school life and holidays on sleep and physical activity patterns in junior high school students: a small-sample longitudinal study using wearable devices. [PDF]

Front Public Health
Chen Y, Xu K, Zhao Y, Gu Z, Zhang S, Chen G, Dai J.   +6 more
europepmc   +1 more source

Local Construction Employment and Binge Drinking Among US Adults in Their Early 30s: Insights From a Path Analysis. [PDF]

Am J Ind Med
Oh S, Freisthler B, Hawkins D.
europepmc   +1 more source