Results 211 to 220 of about 3,642,808 (303)

Eco‐Friendly Synthesis of Cobalt Phthalocyanine for High‐Efficiency CO2${\rm CO}_{2}$ Electroreduction

open access: yesChemistry – A European Journal, EarlyView.
A sustainable synthesis of cobalt phthalocyanine (CoPc) using low‐impact solvents yields high‐performance electrocatalysts with reduced waste (E‐factor 18.6). When integrated into gas diffusion electrodes, CoPc achieves up to 12% Faradays efficiency for CO2‐to‐methanol and 65% CO2‐to‐CO conversion, aligning with state‐of‐the‐art materials and enabling ...
Gloria Zanotti   +10 more
wiley   +1 more source

State‐of‐the‐Art and Synthetic Challenges for Hydrosilane Production

open access: yesChemistry – A European Journal, EarlyView.
The synthesis of hydrosilanes is currently energy intensive and their recycling is not considered. However, these compounds are important in many industrial fields but also for the valorization of oxygenated waste, towards a circular economy. This review compares the available synthetic routes and highlights the remaining challenges for the production ...
Gabriel Durin   +3 more
wiley   +1 more source

Cationic Sulfonium‐Based Tripodal Ligand and Its Rh(I) Complexes

open access: yesChemistry – A European Journal, EarlyView.
We report a cationic EP3‐type tripodal ligand based on an aromatic sulfonium cation (E = S+) along with a series of its Rh(I) complexes. Structural, spectroscopic, electrochemical, and computational analyses of these complexes compared to isostructural analogs (E = Si− or P) reveal pronounced electron density depletion at Rh in the sulfonium congener ...
Nitsan Barel   +5 more
wiley   +1 more source

Proton‐Exchanged Montmorillonite With Interlayer Accessibility as a Solid Acid Catalyst for the Upcycling of Polyoxymethylene

open access: yesChemistry – A European Journal, EarlyView.
The first microwave‐assistance‐free heterogeneous catalytic upcycling of polyoxymethylene (POM) into valuable cyclic acetals is achieved with a reusable proton‐exchanged montmorillonite (H‐Mont) catalyst. Combining interlayer accessibility with strong acidity, H‐Mont enables efficient, regenerable, and versatile transformations with potentially biomass‐
José F. Noboa   +3 more
wiley   +1 more source

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