Results 91 to 100 of about 13,485 (259)

Emerging Materials and Future Strategies for Solid Oxide Electrochemical Cells

Advanced Energy Materials, EarlyView.
Solid oxide electrochemical cells operate under strongly coupled electrochemical and thermodynamic conditions, where performance is constrained by interactions among crystal structure, defect chemistry, and interfacial evolution. This review, based on a structure‐defect‐property‐durability framework, reveals the roles of lattice symmetry and defect ...
Qiuchun Lu, Yufei Zhang, Han Zhao, Pooi See Lee, Daniel H.C. Chua   +4 more
wiley   +1 more source

Ultrathin Membrane With Ion‐Specific Gating Enables Interfacial Decoupling of Conductivity–Selectivity for Aqueous Flow Batteries

Angewandte Chemie, EarlyView.
An interfacial ion‐specific gating strategy shifts membrane design from ion diffusion within ion‐exchange channels to ion partitioning at the membrane–electrolyte interface, thereby decoupling selectivity from conductivity. The strategy underscores the pivotal yet underexplored role of the membrane–electrolyte interface, providing a broadly applicable ...
Di Mu, Yu Xiong, Feiran Wang, Jiafeng Lei, Fei Ai, Jun Fan, Yi‐Chun Lu   +6 more
wiley   +2 more sources

Deciphering Intricacies in Directional CO2 Conversion From Electrolysis to CO2 Batteries

Advanced Energy Materials, EarlyView.
This review will delve into the inherent connections and distinctions of CO2‐directed conversion in ECO2RR and CO2 batteries, in terms of product types, catalyst selection, catalytic mechanisms, and electrochemical performances, while proposing a benchmarking framework for the evaluation of CO2 batteries and innovative CO2 battery configurations for ...
Changfan Xu, Huaping Zhao, Lizhuang Chen, Weidong Shi, Guosheng Shao, Yong Lei   +5 more
wiley   +1 more source

Flavin Catalysts in Organic Synthesis

Angewandte Chemie, EarlyView.
Flavins and their congeners are potent catalysts for organic synthesis inspired by enzymatic transformations. In addition to catalysis in the flavin ground state via covalent intermediates, the excited singlet and triplet states unlock applications including photooxidation, photoreduction, and energy transfer via sensitization.
Jan Freudenberg, Golo Storch
wiley   +2 more sources

Reduction Processes in Thin-Film Vanadium Oxides for Application in Optoelectronic Devices

Nanomaterials
This article describes a study on the synthesis and annealing processes of thin-film coatings of vanadium oxide on flat, parallel substrates made of quartz glass, sapphire, and silicon, as well as optical fibers using an organometallic precursor ...
Dmitriy P. Sudas, Vasily O. Yapaskurt, Valery A. Luzanov, Galina G. Yakushcheva, Kirill Kuznetsov, Petr I. Kuznetsov   +5 more
doaj   +1 more source

Streamlined V3.5+ Electrolyte Production by Leveraging Chemical and Catalytic Reductions

Advanced Energy Materials, EarlyView.
A tuned catalytic process for V3.5+ electrolyte production is shown to streamline the conventional chemical‐to‐catalytic sequence by extending catalysis into the rate‐determining reduction regime. This study shows that initiating catalysis in this regime shortens the overall production time by 67% based on rigorous thermodynamic and kinetic analysis of
Kyunghwa Seok, Minseong Kang, Hee‐Tak Kim   +2 more
wiley   +1 more source

Electrocatalytic Urea Waste Valorization via Water Electrolysis: Transition‐Metal Phosphides for Sustainable Hydrogen Production

Advanced Energy Materials, EarlyView.
This article provides a comprehensive analysis of transition metal phosphides (TMP) as electrocatalysts for urea‐assisted water electrolysis, highlighting the critical role of phosphorus engineering in modulating electronic structure, optimizing active sites, and enhancing catalytic durability.
Shivalingayya Gaddimath, Varsha Kashanner, Soumya Kulkarni, Vishal Sorathiya, Anitha Bamani, Rajveer Singh Rajaura, Mahaveer Kurkuri, Shambhulinga Aralekallu, Yogendra Kumar Mishra   +8 more
wiley   +1 more source

Water, Alcohols, Amines, and Amides as Formal Hydrogen‐Atom‐Transfer Reagents Through Activation With Redox‐Active Lewis Acids

Angewandte Chemie, EarlyView.
Protic molecules containing strong O─H or N─H bonds typically resist hydrogen‐atom abstraction because of the high reactivity of the resulting heteroatom‐centered radicals. However, association of the protic molecules with redox‐active Lewis acids can provide powerful hydrogen‐atom donors or proton‐coupled‐electron‐transfer reagents.
Petra Vojáčková, Armido Studer
wiley   +2 more sources

Synergistic Optimization of Cathode Composite Architecture and Stack Pressure for High‐Performance All‐Solid‐State Chloride‐Ion Batteries

Advanced Energy Materials, EarlyView.
Composite cathode engineering and stack pressure co‐optimization enable a high‐performance all‐solid‐state chloride‐ion battery based on a VOCl/CsSn₀.₉In₀.₀₆₇Cl3/In architecture, delivering 169 mAh g−1 with 500‐cycle durability. Electrode‐resolved impedance tracking via distribution of relaxation times revealed progressive interphase and charge ...
Soutam Panja, Anantha Padmanabhan Gopikuttan, Manuel Mundszinger, Amr Radwan, Hong Chen, Johannes Biskupek, Oliver Clemens, Maximilian Fichtner   +7 more
wiley   +1 more source

A High‐Voltage Membrane‐Free Li–Organic Hybrid Flow Battery Using Eutectic Lithium Chemistry

Angewandte Chemie, EarlyView.
A high‐voltage (3.6 V) membrane‐free Li–organic hybrid flow battery is enabled by a deep‐eutectic lithium electrolyte composed of trifluoroacetamide (TFAD) and LiPF6, paired with a dichloromethane (DCM) catholyte containing phenothiazine (PTZ). The TFAD/LiPF6 eutectic provides fast Li+ transport and stable Li‐metal cycling, while the immiscible TFAD ...
Xiao Wang, Bindu Dahal, Yuhang Tang, Jack J. McGrath, Rabin Siwakoti, Feng Wang, Jun Cheng, Jianbing “Jimmy” Jiang   +7 more
wiley   +2 more sources