Results 211 to 220 of about 349,112 (272)

The Challenging P‐Alkylation of Aromatic Phosphorus Heterocycles and Follow‐Up Reactions

open access: yesChemistryEurope, EarlyView.
P‐alkylation of λ3σ2‐phosphinines is hindered by weak nucleophilicity and scarce synthetic access, previously requiring multistep routes or extreme electrophiles. A direct ambient‐condition method is reported using 3,5‐bis(trimethylsilyl)‐phosphinine/B(C6F5)3 with esters or iso(thio)cyanates to generate stable 1‐R‐phosphininium salts.
Samantha Frank   +6 more
wiley   +1 more source

Synthesis and Isolation of Bismuth Scorpionate Complexes: Toward Bond Activation via Bismuth‐Ligand Cooperation

open access: yesChemistry – A European Journal, EarlyView.
ABSTRACT Over the past twenty years, main group chemistry has significantly expanded its scope to include reactivities once considered the exclusive domain of transition metals. Among the emerging concepts, element‐ligand cooperation has proven to be a powerful strategy for enabling bond activation reactions but remains relatively unexplored for ...
Lennart Hensle, Viktoria H. Gessner
wiley   +1 more source

Boron Neutron Capture Therapy at a Crossroads: Translational Gap and Emerging Delivery Agents

open access: yesChemistry – A European Journal, EarlyView.
This review surveys recent advances in boron delivery agents for BNCT, emphasizing the shift from classical small molecules to multifunctional nanocarriers and theranostic systems. By integrating targeting, imaging, and therapy, next‐generation boron compounds aim to bridge the gap between (bio)chemical innovation and clinical translation.
Christoph Selg, Evamarie Hey‐Hawkins
wiley   +1 more source

Tumor-specific antibody cocktail treatment suppresses colorectal tumor growth in mice. [PDF]

open access: yesCancer Immunol Immunother
Shukla GS   +7 more
europepmc   +1 more source

On the Role of Linker Fluorination in the Adsorption‐Induced Structural Response of CeIV‐Based Metal‐Organic Frameworks

open access: yesChemistry – A European Journal, EarlyView.
The effect of the degree of fluorination of the organic linker on the adsorption behavior of MIL‐140A(Ce) is systematically investigated with a combination of experimental techniques. Cooperative adsorption is switched off in less fluorinated frameworks, as a result of reduced steric hindrance around the adsorption sites.
Francesca Nerli   +11 more
wiley   +1 more source

From Research to Action: Communicating Science Effectively for Real‐World Impact

open access: yes
The Bulletin of the Ecological Society of America, EarlyView.
Luis Y. Santiago‐Rosario   +6 more
wiley   +1 more source

Bayesian inverse ensemble forecasting for COVID‐19

open access: yesCanadian Journal of Statistics, EarlyView.
Abstract Variations in strains of COVID‐19 have a significant impact on the rate of surges and on the accuracy of forecasts of the epidemic dynamics. The primary goal for this article is to quantify the effects of varying strains of COVID‐19 on ensemble forecasts of individual “surges.” By modelling the disease dynamics with an SIR model, we solve the ...
Kimberly Kroetch, Don Estep
wiley   +1 more source

Evolution of the water cluster in pore condensation

open access: yesDroplet, EarlyView.
In pore condensation, lower contact angles reduce molecular displacement (60%) and potential energy (10%), enhancing vapor capture tenfold. Pores restrict water molecule mobility, promoting condensation. On hydrophobic surfaces (124∘$^\circ$), pores stabilize embryos, ensuring uniform condensation within pores, boosting nucleation efficiency.
Boxuan Cui   +4 more
wiley   +1 more source

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