Results 121 to 130 of about 13,458 (252)

Probing Metal Tip‐Induced Bond Weakening of a Reactive Alkyne Center Aligned via a Rigid Triphenylmethane‐Based Tripod on Au(111) by TERS and DFT

Journal of Raman Spectroscopy, EarlyView.
We investigate tip‐induced bond weakening of a single alkyne center immobilized and aligned upright on Au(111) using a rigid triphenylmethane‐based tripod. By varying the tip–molecule distance, we observe shifts in the ≡C–H and –C≡C– vibrational bands via ultrahigh vacuum low‐temperature tip‐enhanced Raman scattering (TERS).
Gang Li, Simon Mennicken, Lu‐Yao Zhu, Sadaf Ehtesabi, Till Reichenauer, Stephan Kupfer, Daniel Schäfer, Saber Mehrparvar, Gebhard Haberhauer, Yao Zhang, Stefanie Gräfe, Sebastian Schlücker, Zhen‐Chao Dong   +12 more
wiley   +1 more source

Recent Advances in Conductive Rubber Composites: Progress, Challenges, and Emerging Opportunities

Macromolecular Rapid Communications, EarlyView.
This study reviews the recent advances in conductive rubber composites, focusing on key aspects such as material selection, conductive mechanisms, interfacial engineering, processing methods, vulcanization strategies, and practical applications. It also discusses current challenges and highlights emerging directions that are shaping the development of ...
Lu Yin, Ali Vahidifar, Steven Yu, Boxin Zhao   +3 more
wiley   +1 more source

Novel Sulfur‐Rich Polymers from Inverse Vulcanization as Functional Building Blocks for Photonics

Macromolecular Rapid Communications, EarlyView.
Isopropenyl aromatic comonomers, in particular novel 2,7‐diisopropenylfluorene and 2,8‐diisopropenyldibenzothiophene, synthesized by sustainable, facile, single‐step SMCCR from available brominated substrates are exploited in the Inverse Vulcanization process to obtain functional Sulfur‐rich macromolecular materials.
Raimondo Insogna, Fabiano Martorelli, Daniela Di Fonzo, Martina Martusciello, Roberto Utzeri, Angelo Angelini, Davide Comoretto, Paola Stagnaro   +7 more
wiley   +1 more source

Incorporation of Nitrogen into Organics Produced by Fischer-Tropsch Type Chemistry [PDF]

Laboratory simulations have demonstrated that hydrothermal systems have the potential to produce a range of organic compounds through Fischer-Tropsch type (FTT) chemistry.
Berger, E. L., Burton, A. S., Lee, C., McCollom, T.   +3 more
core   +1 more source

Branched‐Chain Amino and Keto Acids Reduce Hepatocyte Lipid Droplet Size and Number via Distinct Proteomic Pathways

PROTEOMICS, EarlyView.
ABSTRACT Branched‐chain amino acids (BCAA) and their corresponding keto acids (BCKA) have been associated with changes in hepatic lipid metabolism and the resulting alterations in intracellular triglyceride concentrations. In this study, we utilized a previously established hepatocyte model to investigate the impact of BCAA and BCKA supplementation on ...
Jayasimha R. Daddam, Mounica Sura, Edward Kolodziej, Maria Gojcaj, Zheng Zhou   +4 more
wiley   +1 more source

Second Symposium on Chemical Evolution and the Origin of Life [PDF]

Recent findings by NASA Exobiology investigators are reported. Scientific papers are presented in the following areas: cosmic evolution of biogenic compounds, prebiotic evolution (planetary and molecular), early evolution of life (biological and ...
Devincenzi, D. L., model.
core   +1 more source

Super‐capacitive carbon materials with large micropores and rich mesopores synthesized using N, S co‐doped carbon dots as self‐templates

Responsive Materials, EarlyView.
Nitrogen‐sulfur co‐doped carbon dots are employed as self‐templates to fabricate hierarchical porous carbon material with a concentrated micropore size distribution of 1.1–1.6 nm and a high mesopore volume ratio up to 47.2%, which shows good capacity and excellent responsive ability as electrodes in electrochemical supercapacitors.
Xi‐Rong Zhang, Hao‐Wen Sun, Ling Xiao, Zhao‐Fan Wu, Huan‐Ming Xiong   +4 more
wiley   +1 more source

Gender-Specific Differences between the Concentrations of Nonvolatile (R)/(S)-3-Methyl-3-Sulfanylhexan-1-Ol and (R)/(S)-3-Hydroxy-3-Methyl-Hexanoic Acid Odor Precursors in Axillary Secretions [PDF]

, 2017
The volatile fatty acid, (R)/(S)-3-hydroxy-3-methylhexanoic acid ((R)/(S)-HMHA), and the human specific volatile thiol, (R)/(S)-3-methyl-3-sulfanylhexan-1-ol ((R)/(S)-MSH), were recently identified as major components of human sweat malodor.
Beccucci, Sabine, Borchard, Gerrit, Niclass, Yvan, Raviot-Derrien, Sophie, Starkenmann, Christian, Troccaz, Myriam, Vuilleumier, Christine   +6 more
core  

Dimethyl‐, Diethyl‐, and Propylene Carbonates: An Emerging Class of Green Solvents for Organic Synthesis

The Chemical Record, EarlyView.
This review highlights recent advances in the use of organic carbonates, dimethyl carbonate (DMC), diethyl carbonate (DEC), and propylene carbonate (PC), as solvents in organic synthesis. Based on over seventy studies from the past 6 years, it shows their application in different organic reaction types, emphasizing their role in safer and more ...
Gabriela T. Quadros, Livia C. L. Valente, Thiago Barcellos, Daniela Hartwig, Laura Abenante, Eder J. Lenardão   +5 more
wiley   +1 more source

Organic and Inorganic Pollutants, Oxidative Stress Biomarkers, and Electrophoretic Protein Profiles in an Endangered Thresher Shark (Alopias vulpinus) From Southeastern Brazil: A Case Study

Environmental Toxicology, EarlyView.
ABSTRACT A comprehensive screening of different environmental contaminants (total metals, thermostable metal fractions associated with detoxification, and persistent organic pollutants) was conducted in an endangered common thresher shark (Alopias vulpinus ) individual incidentally captured in southeastern Brazil.
Sidney Fernandes Sales Junior, Amanda Pontes Lopes, Heloíse Martins de Souza, Regina Fonseca, Enrico Mendes Saggioro, Francielli Monteiro Casanova, Kamila Cezar Gramlich, Tatiana Dillenburg Saint'Pierre, Carlos German Massone, Renato Carreira, Rachel Ann Hauser‐Davis   +10 more
wiley   +1 more source