Results 101 to 110 of about 37,161 (255)

Volume in the Extensive Thermodynamics of Black Holes

Since black holes lack a straightforward notion of geometrical volume due to their event horizon structure and coordinate dependence, various approaches have been proposed to introduce a meaningful geometric and thermodynamic volume. In this work we investigate the stability conditions of AdS black holes with and without volume.
Somogyfoki, Réka, Ván, Péter
openaire   +2 more sources

Toward Fast Proton Shuttling in Acidic Oxygen Evolution Reaction

Advanced Functional Materials, EarlyView.
This review establishes proton transfer dynamics as a descriptor governing acidic OER activity, moving beyond the kinetic constraints derived from the proton coupled electron transfer. We discuss how deprotonation governs classical mechanisms, including adsorbate evolution mechanism (AEM), lattice oxygen mechanism (LOM) and oxide path mechanism (OPM ...
Ashish Gaur, Jaeyeong Kim, Sungwook Mhin, HyukSu Han   +3 more
wiley   +1 more source

Engineering MnNiPx Cathode via Dual Role of Mn: Simultaneous Enhancement of Activity and Intermittent Operation Durability

Advanced Functional Materials, EarlyView.
Engineering MnNiPx cathodes through the dual role of Mn simultaneously improves hydrogen evolution reaction activity and intermittent‐operation durability. Mn preferentially oxidizes to protect Ni–P sites from irreversible oxidation, while metallic Mn incorporation enhances the HER kinetics of Ni–P active layer.
Ik‐Sun Kim, Jungwoo Choi, Sechan Lee, Jung Eun Park, Changsoo Lee, Jongsu Seo, Ji Hee Kwon, Gisu Doo, Hyeonjung Park, Dongju Lee, Won‐Chul Cho, Changhee Kim, Nosang Vincent Myung, Sang Soo Han, Byeong‐Seon An, MinJoong Kim, Hyun‐Seok Cho   +16 more
wiley   +1 more source

Support‐Controlled Reaction Pathways via Dynamic Sulfur‐Mediated Interfaces for Selective Urea Electrolysis

Advanced Functional Materials, EarlyView.
Sulfur‐doped graphitized carbon nanofibers act as adaptive catalyst–support platforms, enabling dynamic sulfur‐mediated reconstruction and strong metal–support interactions. This unique behavior enhances catalyst stability and controls reaction pathways, achieving highly selective urea oxidation (∼92% N2) coupled with efficient hydrogen evolution ...
Melanie Guillén‐Soler, Lucía Vizcaíno‐Anaya, Ahmad Tayyebi, José Manuel Vila‐Fungueiriño, María del Carmen Giménez‐López   +4 more
wiley   +1 more source

Nano‐Scale Characterization of Impurities Segregation in Solid Oxide Electrolysis Cells

Advanced Functional Materials, EarlyView.
Cathodic polarization induces impurity segregation in Ni, forming an amorphous Na─Al─Si─O amorphous phase at grain boundaries. Under ultralow oxygen partial pressure, multiple elements dissolve, migrate, and reoxidize within the metal. A patterned model system provides direct nanoscale evidence, clarifying the mechanism of polarization‐driven impurity ...
Zhongtao Ma, Qingjie Wang, Bowen Li, Vasileios Bilalis, Søren Bredmose Simonsen, Ming Chen   +5 more
wiley   +1 more source

Redirecting Nano‐Silicon Agglomeration: Dual‐Carbon Design Triggers Self‐Adaptive Nanoporous Si Sponge for Enhanced Lithium Storage

Advanced Functional Materials, EarlyView.
This study addresses silicon anode degradation using an engineered nSi/Gr/C dual‐carbon matrix. By restricting SEI infiltration, the architecture redirects silicon agglomeration into a beneficial structural self‐adaptive activation. During cycling, silicon nanoparticles self‐organize into a resilient nanoporous sponge. This dynamic network accommodates
Wei Zhang, Yuxia Zhong, Wen Ren, Lei Zhang, Yexin Pan, Mitch Guijun Li, Gary J. Cheng, Ruohan Yu   +7 more
wiley   +1 more source

Amended FRW universe: thermodynamics and heat engine

European Physical Journal C: Particles and Fields
Thermodynamics of non-flat Amended Friedmann–Robertson–Walker (AFRW) universe with cosmological constant as thermodynamic pressure is studied. The unified first law of thermodynamics, the Clausius relation and the gravity equations yield entropy on the ...
Jhumpa Bhadra, Ujjal Debnath, Anirudh Pradhan   +2 more
doaj   +1 more source

Glucose Deprivation‐Driven Concurrent Induction of Apoptosis/Disulfidptosis/Ferroptosis by Tumor Targeting Nanoassemblies in Triple‐Negative Breast Cancer Therapy

Advanced Functional Materials, EarlyView.
Innovative hybrid nanoassemblies installed with ferrocene, D‐α‐tocopherol succinate, and phloretin exploit the metabolic vulnerability of triple‐negative breast cancer under glucose starvation. By blocking glucose uptake, this single nanoplatform simultaneously orchestrates apoptosis, disulfidptosis, and ferroptosis to achieve synergistic and ...
Song Yi Lee, ChaeRim Hwang, Seong Eun Kim, Mrinmoy Karmakar, Seo Jin Jung, Hyeonseok Jang, Hae‐In Kim, Heejung Yang, Junmin Lee, Dae‐Duk Kim, Hyun‐Jong Cho   +10 more
wiley   +1 more source

Predictive Thermodynamics for Isochoric (Constant-Volume) Cryopreservation Systems

The Journal of Physical Chemistry B
Cryopreservation is the preservation and storage of biomaterials using low temperatures. There are several approaches to cryopreservation, and these often include the use of cryoprotectants, which are solutes used to lower the freezing point of water.
Julia H. Grenke, Janet A. W. Elliott
openaire   +2 more sources

Controlling Proton Migration in Oxide Heterostructures by Interfacial Chemical Potential Mismatch

Advanced Functional Materials, EarlyView.
Interfacial reconstruction of the proton chemical potential enables control of proton migration in oxide heterostructures. In TiO2/VO2 heterostructures, we found that increasing the TiO2 capping layer thickness by only several nanometers modulates the thermal stability of protons inserted into VO2.
Sota Fuji, Lingling Xie, Ryotaro Aso, Takuya Majima, Takeshi Watanabe, Yuichi Shimakawa, Daisuke Kan   +6 more
wiley   +1 more source