A strategy for the Pt/TiO2‐photocatalyzed β‐scission of nonactivated 3° alcohols in the absence of external oxidants and additives was developed. A wide variety of C‐centered radicals were generated and subsequently engaged in C─C bond‐forming reactions.
Shu Sakurai +3 more
wiley +1 more source
Nasal negative pressure oscillatory therapy versus oscillatory positive expiratory pressure for airway clearance in patients with acute exacerbations of bronchiectasis (NNPO-BE): a multicentre, randomised, crossover non-inferiority trial protocol. [PDF]
Wang S +10 more
europepmc +1 more source
Magnetic field induced crossover in weakly localized regimes and scaling of the conductivity
R.H. Oppermann
openalex +2 more sources
On the Reaction Mechanism of Nitrate Radical and DMPO in Non‐aqueous Photocatalytic Media
This work identifies 2‐oxo‐5,5‐dimethyl‐1‐pyrroline 1‐oxyl (DMPOX), formed via the selective oxidation of 5,5‐dimethyl‐1‐pyrroline N‐oxide (DMPO) by nitrate radicals (NO3•) in nonaqueous media, as a distinctive EPR fingerprint of NO3•. The DFT‐supported mechanism clarifies its formation pathway and highlights DMPOX detection as a robust tool for ...
Alessandro Gottuso +4 more
wiley +1 more source
Particular Water Organization in Homogeneous Water Mixtures of Amphiphilic Polystyrene-<i>block</i>-poly(methoxydiethylene glycol acrylate) Diblock Copolymer with Thermoresponsive Behavior. [PDF]
Kripotou S +5 more
europepmc +1 more source
“Reversible I2 Uptake Induces Record‐High Spin‐Crossover Hysteresis in a Fe(II) Hofmann‐Type MOF”
Reversible iodine uptake in a flexible Fe(II) Hofmann‐type MOF [Fe(pz)Pd(CN)4] induces record‐wide SCO hysteresis. Gas‐phase I2 acts as internal chemical pressure, stabilizing both high‐spin and LS states without altering the framework, providing a general strategy for tunable bistability in coordination networks.
Mario Pacheco +3 more
wiley +1 more source
Machine learning analysis of oral solid dosage formulation solubility variations by adjusting pressure and temperature. [PDF]
Lahiq AA, Alshehri AA, Alsharif ST.
europepmc +1 more source
Effects of bed baths with weak wiping pressure using cotton and disposable towels on the skin barrier function of the lower limbs in older patients with heart disease: A quasi- experimental (crossover) study [PDF]
Inaho Shishido, Rika Yano
openalex +1 more source
Key improvements obtained by incorporating nanoparticles into a lab‐scale SAGD process configuration. The bar plots show enhanced oil recovery, reduced viscosity, and increased asphaltene adsorption in nanoparticle‐assisted scenarios compared with conventional SAGD.
Luis Prada +6 more
wiley +1 more source
Rethinking adjunctive dobutamine in septic shock: time to individualize, not generalize. [PDF]
Lee SH.
europepmc +1 more source

