Results 211 to 220 of about 159,585 (324)

β‐Scission of Tertiary Alcohols on a Platinum‐Loaded Titanium Dioxide Photocatalyst for C─C Bond‐Forming Reactions

open access: yesChemistry – A European Journal, EarlyView.
A strategy for the Pt/TiO2‐photocatalyzed β‐scission of nonactivated 3° alcohols in the absence of external oxidants and additives was developed. A wide variety of C‐centered radicals were generated and subsequently engaged in C─C bond‐forming reactions.
Shu Sakurai   +3 more
wiley   +1 more source

On the Reaction Mechanism of Nitrate Radical and DMPO in Non‐aqueous Photocatalytic Media

open access: yesChemistry – A European Journal, EarlyView.
This work identifies 2‐oxo‐5,5‐dimethyl‐1‐pyrroline 1‐oxyl (DMPOX), formed via the selective oxidation of 5,5‐dimethyl‐1‐pyrroline N‐oxide (DMPO) by nitrate radicals (NO3•) in nonaqueous media, as a distinctive EPR fingerprint of NO3•. The DFT‐supported mechanism clarifies its formation pathway and highlights DMPOX detection as a robust tool for ...
Alessandro Gottuso   +4 more
wiley   +1 more source

“Reversible I2 Uptake Induces Record‐High Spin‐Crossover Hysteresis in a Fe(II) Hofmann‐Type MOF”

open access: yesChemistry – A European Journal, EarlyView.
Reversible iodine uptake in a flexible Fe(II) Hofmann‐type MOF [Fe(pz)Pd(CN)4] induces record‐wide SCO hysteresis. Gas‐phase I2 acts as internal chemical pressure, stabilizing both high‐spin and LS states without altering the framework, providing a general strategy for tunable bistability in coordination networks.
Mario Pacheco   +3 more
wiley   +1 more source

In‐situ asphaltene capture with iron oxide nanoparticles in steam‐assisted gravity drainage (SAGD) for improved recovery and partial upgrading of bitumen

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Key improvements obtained by incorporating nanoparticles into a lab‐scale SAGD process configuration. The bar plots show enhanced oil recovery, reduced viscosity, and increased asphaltene adsorption in nanoparticle‐assisted scenarios compared with conventional SAGD.
Luis Prada   +6 more
wiley   +1 more source

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