Results 171 to 180 of about 3,198,692 (262)

Azidophosphonamido Rhodium(I) and Iridium(I) Complexes: Synthesis, Properties, and Linkage Isomerism

open access: yesChemistry – A European Journal, EarlyView.
A family of azidophosphonamido ligands and their corresponding rhodium(I) and iridium(I) complexes were synthesized. The rich reaction chemistry of these species revealed unusual linkage isomerization processes and bonding motifs. M = Rh, Ir; Mes = 2,4,6‐Me3C6H2. ABSTRACT A series of azidophosphonamido rhodium(I) and iridium(I) complexes ([iPr2P(N3R)NR]
Emily L. Trew   +3 more
wiley   +1 more source

A time series based dynamic prediction model for loess mudstone landslides. [PDF]

open access: yesSci Rep
Tang C   +7 more
europepmc   +1 more source

Modulation of Epigenetic Control by Advanced Molecular Tweezers

open access: yesChemistry – A European Journal, EarlyView.
Tailored dimeric molecular tweezers recognize the DNA‐binding part of Histone H4 and interrupt the essential histone‐DNA interaction. ABSTRACT This work addresses the question if supramolecular systems can be tailored to interfere with posttranslational modifications (PTM) and epigenetics.
My‐Hue‐Le   +9 more
wiley   +1 more source

Scaling Up Molecular Electron Spin Qubits Around a Core‐Shell Quantum Dot

open access: yesChemistry – A European Journal, EarlyView.
Making assemblies of molecular nanomagnet (MNM) qubits is an essential step toward scalable quantum devices. Here, SH‐functionalized {Cr7Ni} antiferromagnetic rings with ability as MNM qubits were successfully grafted to the surface of fluorescent CdSe/ZnS quantum dots (QD).
Simon G. McAdams   +8 more
wiley   +1 more source

Development of a Mechanically Regenerating Desublimator for Freeze‐Drying Systems in the Food Industry

open access: yesChemie Ingenieur Technik, EarlyView.
Thermal defrosting limits desublimator efficiency in freeze‐drying. This review and case study compares thermal versus mechanical regeneration, links frost properties and external heat transfer to energy demand, and summarizes pilot‐scale scraping results enabling single‐unit, continuous lyophilization.
Moritz Krummenacher   +3 more
wiley   +1 more source

Coupled heat and mass transfer in reactive parallel‐plate flow: A perturbative Graetz model with modal symmetry and Arrhenius kinetics

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
A perturbative Graetz model describes coupled heat and mass transfer in reactive Couette–Poiseuille flow between parallel plates. Viscous dissipation and heat of reaction produce a small temperature rise, which enhances Arrhenius reaction rates and modestly accelerates axial species conversion in the small‐Brinkman‐number regime.
Leonardo Damián Soria Rodríguez   +1 more
wiley   +1 more source

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