Results 101 to 110 of about 21,524 (265)

Kooperative Redox‐Katalyse der N2O‐Zersetzung mittels auf Co3O4 geträgerten RhOx‐ und CeOx‐Spezies mit kurzreichweitiger Wechselwirkung

open access: yesAngewandte Chemie, EarlyView.
A short‐range Rh‐O‐Co‐O‐Ce interfacial moiety drives low‐temperature N2O decomposition via a cooperative redox cycle. Operando modulated‐excitation XAS with phase‐sensitive detection (ME‐XAS+PSD) tracks rapid, reversible Rh oxidation coupled to Co reduction. Combined kinetics and DFT rationalize the activity trends and identify the Rh‐O‐Co interface as
Daniel C. Cano‐Blanco   +7 more
wiley   +1 more source

Optimal control for solutions to Sobolev stochastic equations

open access: yesElectronic Journal of Differential Equations, 2021
Evgeniy Bychkov   +2 more
doaj  

On the First Passage of the Integrated Wiener Process

open access: yesThe Annals of Mathematical Statistics, 1971
The rate of first passage of the integrated Wiener process to $x > 0$ is determined in terms of the "$\frac{1}{2}$-winding time" distribution of H. P. McKean, Jr. The probability that the integrated Wiener process is currently at its maximum is approximated.
openaire   +3 more sources

Taming a Blue Gas—Structure and Chemistry of Hexafluorothioacetone

open access: yesAngewandte Chemie International Edition, EarlyView.
Hexafluorothioacetone (1), a blue gas at r.t., was synthesized by flash vacuum pyrolysis of its cyclic dimer at 660°C. We discuss fundamental properties of elusive 1, including single‐crystal structure and nuclear magnetic resonance spectroscopy, despite its tendency to dimerize even at –74°C.
Hennes Günther   +3 more
wiley   +1 more source

Existence of square-mean almost periodic mild solutions to some nonautonomous stochastic second-order differential equations

open access: yesElectronic Journal of Differential Equations, 2010
In this paper we use the well-known Schauder fixed point principle to obtain the existence of square-mean almost periodic solutions to some classes of nonautonomous second order stochastic differential equations on a Hilbert space.
Paul H. Bezandry, Toka Diagana
doaj  

Molecular Dioxygen‐Mediated Passivation of Electron Traps in n‐Type Organic Charge‐Transfer Complexes

open access: yesAngewandte Chemie International Edition, EarlyView.
O2 enhances charge‐transfer in n‐type organic donor–acceptor charge‐transfer complexes (CTCs) via physisorption‐mediated trap passivation. By suppressing recombination and promoting long‐lived delocalized charge carriers, O2 improves electron transport and conductivity without doping.
Kirill K. Gubanov   +16 more
wiley   +1 more source

New optical stochastic solutions for the Schrödinger equation with multiplicative Wiener process/random variable coefficients using two different methods

open access: yesOpen Physics
In this article, we take into consideration the stochastic Schrödinger equation (SSE) perturbed in the Itô sense by the multiplicative Wiener process. We employ an appropriate transformation to turn the SSE into another Schrödinger equation with random ...
Mohammed Wael W., Al-Askar Farah M.
doaj   +1 more source

Anomeric Amide Enabled Divergent Synthesis of Unsymmetrical Ureas, Carbamates, Thioesters, and Amides From Aldehydes

open access: yesAngewandte Chemie International Edition, EarlyView.
An anomeric amide‐enabled divergent aldehyde functionalization sequence provides one‐pot access to unsymmetrical ureas, carbamates, thiocarbamates, thioesters, and amides. Key to this transformation is the formation of N‐Boc‐hydroxamate intermediates, which serve as platforms for orthogonal activation via Lossen‐type rearrangements, single‐electron ...
Jasper L. Tyler   +6 more
wiley   +1 more source

Pan‐Frying Conditions Affect the Tocopherol Intake From Edible Oils: Results From Temperature Measurements and the Standardized Heating of an Edible Oil

open access: yesJournal of the American Oil Chemists' Society, EarlyView.
High temperatures in a short time on electric stoves in private homes. Fast loss of tocochromanols using standardized conditions and a miniature heating apparatus. ABSTRACT Tocochromanols (vitamin E compounds) are essential ingredients in human nutrition. Their consumption via edible oils is considered the main source of dietary intake.
Alicia Harter   +2 more
wiley   +1 more source

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