Results 221 to 230 of about 28,098 (306)

Shedding Light on Synthetic Autocatalysis: From Conventional Closed‐Shell Chemistries to Overlooked Open‐Shell Occurrences

open access: yesChemistry – A European Journal, EarlyView.
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley   +1 more source

Distinct Ligand‐ and Metal‐Centered Phosphorescence in a Terbium Carbazolyl Complex

open access: yesChemistry – A European Journal, EarlyView.
Terbium and lanthanum carbazolide complexes show two distinct modes of luminescence: Strongly temperature‐dependent narrow‐line terbium emission could be induced. In addition, both the terbium and the lanthanum complexes show broad‐line interligand emission processes with excited states of microsecond life‐time.
Xiaofei Sun   +9 more
wiley   +1 more source

Large zoom ratio and adaptive aberration correction microscope using 4DPSF-aware Physical Degradation-guided Network. [PDF]

open access: yesLight Sci Appl
Yu DX   +9 more
europepmc   +1 more source

Highly Potent Fluorogenic Ligands for Triplex DNA: 5‐Substituted 2‐(Naphthalen‐2‐yl)‐4H‐Chromen‐4‐Ones

open access: yesChemistry – A European Journal, EarlyView.
5‐Substituted 2‐(naphthalen‐2‐yl)‐4H‐chromen‐4‐ones are reported as a novel class of highly potent and selective triplex DNA ligands. These ligands induce triplex formation at submicromolar concentrations and inhibit enzymatic activity via ligand‐mediated triplex formation.
Nghia Tran   +4 more
wiley   +1 more source

The Asymmetric Self‐Replicative Alkylation of N‐Arylaldimines Using Organolithium Reagents

open access: yesChemistry – A European Journal, EarlyView.
Here, we report a new asymmetric autoinductive reaction; the addition of nBuLi to N‐arylaldimines to form chiral lithium amides. The reaction proceeds with full conversion and complete transfer of chirality, representing the first example of an asymmetric autoinductive reaction with organolithium reagents.
Anka Hagelschuer   +2 more
wiley   +1 more source

Substituent‐Dependent Structural Trends in Thermal Condensation of Silanetriols and Disiloxanetetraols

open access: yesChemistry – A European Journal, EarlyView.
We report a catalyst‐ and solvent‐free thermal condensation route to oligosilsesquioxanes from arylsilanetriols and disiloxanetetraols. Phenyl and 1‐naphthyl systems form ladder‐like structures, while 2‐naphthyl systems yields layered architectures.
Jan‐Falk Kannengießer   +4 more
wiley   +1 more source

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