Results 131 to 140 of about 11,563 (263)

Interfacial Ru–O–W Orbital Coupling Enables Lattice Oxygen Stabilization for Enhanced Acidic OER

Carbon Energy, EarlyView.
A RuO2/WO3 electrocatalyst with strong interfacial Ru–O–W bonds exhibits optimized Ru–O interactions, enhancing intrinsic activity and stability for acidic OER. The WO3 support modulates the electronic structure of RuO2 and promotes oxo‐intermediate deprotonation, delivering a low overpotential of 203 mV at 10 mA cm−2 and sustained operation beyond 200 
Tongzhou Wang, Shoujian Duan, Junyu Pan, Jihong Li, Li Shao, Lei Shi, Yuhan Sun, Jingming Ran, Huaiyu Shao, Yida Deng   +9 more
wiley   +1 more source

Modulating Electronic Structure of Atomic Iron Catalyst by Metallic Cobalt Cooperation for Boosting Oxygen Reduction/Evolution Reactions in Rechargeable and Flexible Zinc‐Air Battery

Carbon Energy, EarlyView.
Porous Co,Fe@NCNF‐900 catalyst has been innovatively synthesized as enhanced bifunctional catalysts by modulating the electronic structure of the atomic Fe catalyst through metallic Co cooperation. DFT analysis indicates that metallic Co as an electron donor can induce electron redistribution of the atomic Fe catalyst, thereby reducing the rate ...
Shuangshuang Ren, Pengfei Zhang, Xinxin Tang, Jian Tang, Jing Zhang, Liang Chen, Hegen Zheng, Zhengkai Tu, Yiyu Chen, Zhongmin Wan, Siew Hwa Chan   +10 more
wiley   +1 more source

CO2‐Driven Synthesis of Holey Edge‐Carboxylated Graphene for Tunable Electronic Interactions in Cu–CeO2‐Catalyzed Water‐Gas Shift Reaction

Carbon Energy, EarlyView.
Holey‐structured, edge‐carboxylated graphene with a controlled specific surface area was synthesized using an environmentally friendly, CO2‐activated, KOH‐free ball‐milling process. ABSTRACT Graphene, notable for its high specific surface area, is ideal for catalyst support but faces challenges under harsh thermal catalytic conditions.
Seon‐Yong Ahn, I‐Jeong Jeon, Won‐Jun Jang, In‐Yup Jeon, Jae‐Oh Shim, Hyun‐Seog Roh   +5 more
wiley   +1 more source

Low‐Temperature Initiation Enhances HCN and NH3 Formation From Methane and NO Over Pt/Al2O3

Chemistry – A European Journal, EarlyView.
Hydrogen cyanide (HCN) was formed from CH4 and NO over Pt/Al2O3 at low temperatures. Increasing NO concentration and optimizing reaction‐start conditions significantly enhanced HCN yield. In situ FTIR and DXAFS measurements revealed that dynamically balancing Pt‑CO and Pt‑CN surface species, particularly their desorption under temperature‑swing ...
Emika Yamashita, Kyoko K. Bando, Toshitaka Kubo, Atsushi Takagaki   +3 more
wiley   +1 more source

Precise Control of Water Adsorption Behavior in Solid Solutions of Amorphous Coordination Polymers

Chemistry – A European Journal, EarlyView.
Amorphous coordination polymers (Am‐CPs) showed a strict modulation of water uptake behavior via a solid solution approach. The desirable water uptake characteristics were corroborated by the type and local coordination geometry of the central metals, as revealed by a combination of L2,3‐ and K‐edge X‐ray absorption fine structure (XAFS) techniques ...
Haruka Yoshino, Kohei Yamagami, Yuki Imamura, Hirona Yamagishi, Sayuri Shimoda, Benjamin Le Ouay, Ryo Ohtani, Hitoshi Miyasaka, Masaaki Ohba   +8 more
wiley   +1 more source

A Thermally Robust Luminescent Antimony Halide for Real‐Time Detection of Volatile Iodine at Elevated Temperatures

EcoEnergy, EarlyView.
Zero‐dimensional antimony halides drive efficient iodine capture through electron transfer and display rapid fluorescence quenching at 75°C (348 K), establishing the first luminescent sensor for real‐time I2 detection at elevated temperatures. ABSTRACT Real‐time monitoring of volatile molecular iodine (I2), a hazardous radioactive byproduct of nuclear ...
Ying Jiang, Yumin Wang, Fu Peng, Junren Wang, Shangge Zhang, Linwei He, Guangyuan Chen, Jianrong Zeng, Fangling Jiang, Lin Zhu, Kai Li, Long Chen, Shuao Wang, Yaxing Wang   +13 more
wiley   +1 more source

Mechanisms and Advanced Characterizations for Urea Electrosynthesis

EcoEnergy, EarlyView.
In this review, various mechanisms and the advanced characterizations involved in urea electrosynthesis are summarized. Furthermore, the outlook on the future potential, the challenges, and scope of these techniques for developing the urea electrosynthesis route are discussed, paving the way for the green synthesis of urea and other important chemicals.
Chu Zhang, Liwei Guo, Shuangli Li, Zihan Chen, Chunshuang Yan, Chade Lv   +5 more
wiley   +1 more source

Water‐Activated Proton Transfer Mediated by Subnanoscale CeO2‐Cu2O Interfaces for Near‐Unity CH4 Selectivity in Photothermal CO2 Reduction

EcoEnergy, EarlyView.
Subnanoscale CeO2‐Cu2O particles can efficiently catalyze the hydrogenation of the key intermediate *CO to CH4 at an impressive rate of 2818 μmol g−1 h−1 in photothermal CO2 reduction. ABSTRACT Water‐mediated photothermal CO2 reduction to CH4 is promising for renewable energy storage and carbon neutrality, but its selectivity and efficiency are limited
Siyang Nie, Liang Wu, Qingda Liu, Xun Wang   +3 more
wiley   +1 more source

Design of High‐Performance MnCo1.5Cu0.5O4 Spinel Contact Material with Optimized Electrical Conductivity and Thermal Stability for Solid Oxide Electrolysis Cells by Cu Doping

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Cu‐doped spinel MnCo1.5Cu0.5O4 exhibits excellent conductivity and stability as SOC contact material. After 1000‐h aging at 850 °C, the contact layer maintains a 10 mΩ cm2 ASR value, and a single‐cell stack achieves a H2O/CO2 co‐electrolysis power density of 0.52 W cm−2.
Haozhen Li, Shuai Yuan, Xingtong Mao, Hao Shi, Hengyong Tu, Chao Ma, Lei Zhu, Zhen Huang   +7 more
wiley   +1 more source

CeO2/Co3O4 p‐n Heterojunction as a Photo‐Responsive Bifunctional Electrocatalyst for Efficient Zinc‐Air Batteries

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A photo‐responsive bifunctional electrocatalyst with CeO2/Co3O4 p‐n heterojunction has been designed and exhibited excellent photo‐enhanced ORR/OER performance and Zn‐air batteries performance. The introduction of semiconductor materials as bifunctional oxygen reduction/evolution reaction (ORR/OER) electrodes has been proved as an efficient way to ...
Yuling Liu, Taotao Zeng, Chenyu Zhang, Zhanglong He, Mingqing Zuo, Hao He, Zeyan Zhou, Lei Han   +7 more
wiley   +1 more source