Results 81 to 90 of about 7,732,983 (244)

Unexpected Tellurohalogenation of Terminal N‐Alkynyl (Alkenyl) Derivatives of 4‐Functionalized Pyrazoles

open access: yesChemistryOpen
The efficient synthesis of terminal N‐alkenyl and N‐alkynyl derivatives of pyrazole‐4‐carboxylic acids and their methyl esters as substrates for studying electrophilic heterocyclization has been reported.
Marianna V. Povidaichyk   +3 more
doaj   +1 more source

Sequential decarboxylative azide–alkyne cycloaddition and dehydrogenative coupling reactions: one-pot synthesis of polycyclic fused triazoles

open access: yesBeilstein Journal of Organic Chemistry, 2014
Herein, we describe a one-pot protocol for the synthesis of a novel series of polycyclic triazole derivatives. Transition metal-catalyzed decarboxylative CuAAC and dehydrogenative cross coupling reactions are combined in a single flask and achieved good ...
Kuppusamy Bharathimohan   +3 more
doaj   +1 more source

Microstructure‑Dependent Phase Transformations Under High‑Pressure Laser Heating in Additively Manufactured AlCrFe2Ni2

open access: yesAdvanced Engineering Materials, EarlyView.
Additively manufactured AlCrFe2Ni2 with contrasting BCC/B2‐dominant and lamellar FCC + BCC/B2 microstructures exhibits the same pressure‐induced BCC/B2 → HCP transformation. Under laser heating at high pressure, HCP is destabilized, and a cubic BCC/B2 + FCC assemblage is recovered, while the lower‐scan‐speed microstructure transforms at a lower ...
Raimundas Sereika   +5 more
wiley   +1 more source

Influence of annealing on X-ray diffraction of natural alexandrite [PDF]

open access: yes, 2002
In this work we present results of X-ray diffraction using powder method, on natural alexandrite samples from Minas Gerais State (Brazil), as a function of a sequence of annealing. From these measurements we determine lattice parameters before (a = 9.405
Ruggiero, L. D., Li, M. S., Scalvi, RMF
core   +1 more source

Usage of Quantum Chemical Methods to Understand the Formation of Concomitant Polymorphs of Acetyl 2‑(N‑(2-Fluorophenyl)imino)coumarin-3-carboxamide

open access: yesACS Omega, 2021
Svitlana V. Shishkina   +4 more
doaj   +1 more source

Assessment of microarchitecture and crystal structure of hydroxyapatite in osteoporosis

open access: yesUniversa Medicina, 2016
Osteoporosis is characterized by lower bone mineral density (BMD) and microarchitectural degeneration, which tends to increase bone fragility and fracture risk.
Zairin Noor   +4 more
doaj   +1 more source

Impact of Hydrogen Incorporation on Electronic and Magnetic Structure of X2CrNi18‐9 Stainless Steel

open access: yesAdvanced Engineering Materials, EarlyView.
Hydrogen uptake in austenitic stainless steel alters both its electronic and magnetic structure. Seebeck measurements reveal hydrogen‐induced shifts in the electronic density of states, while neutron scattering uncovers nanoscale inhomogeneities that grow upon hydrogen incorporation, with the most pronounced effect observed in the PBF as‐built state ...
Torben Tappe   +9 more
wiley   +1 more source

Characterization by X ray diffraction of mechanically alloyed tripotassium sodium sulfate

open access: yesMaterials Research, 2006
Nanocrystalline powder of tripotassium sodium sulfate (K3Na(SO4)2 - KNS) was successfully obtained by mechanical alloying a mixture of potassium sulfate (K2SO4) and sodium sulfate (Na2SO4) with a proportion of 3:1 in a planetary mill.
Marcus Aurélio Ribeiro Miranda   +4 more
doaj   +1 more source

Microstructural Evolution and In Situ Formation of TiB and TiC in Ti─5Al─2.5Sn Alloy Processed by Powder Metallurgy

open access: yesAdvanced Engineering Materials, EarlyView.
Accelerated in situ formation of TiB and TiC in Ti–5Al–2.5Sn–B4C is driven by transient liquid phase formation, which enhances particle reactions and microstructural evolution. This process increases hardness and establishes a coupled relationship between sintering temperature and reinforcement content, strongly influencing porosity in the resulting ...
Fernando. Y. Kojima, Juliano. Soyama
wiley   +1 more source

Microstructural, Mechanical, and Textural Evolution of Dissimilar Combination of Laser‐Welded Maraging Steel and 4340 Steel

open access: yesAdvanced Engineering Materials, EarlyView.
The present work reports the microstructural, mechanical, and texture evolution of a dissimilar combination laser‐welded maraging steel with 4340 steel. This is important for aerospace applications. The demand for dissimilar welding is growing rapidly with the requirement of efficient and durable joints.
Bharat Behl   +3 more
wiley   +1 more source

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