Results 231 to 240 of about 79,478 (310)

Acid Resistant and Highly Silver Selective Membranes Based on Charged Nanoporous 2D‐Materials

open access: yesSmall, EarlyView.
In this work, new membranes based on charged & nanoporous nanosheets with unprecedented selectivity to silver versus a wide range of other metallic ions are reported. Furthermore, a demonstrated and lead specific intralamellar lead pathway is demonstrated. A potential applicability for ubiquitous silver in WEEE is validated.
Sarah M. Chevrier   +6 more
wiley   +1 more source

Microporous Self‐Assembled Pd(II) Tetrahedral Cages for Rapid and Reversible Multi‐Phase Sequestration of Iodine and Methyl Iodide

open access: yesSmall, EarlyView.
This work reports a family of microporous, self‐assembled tetrahedral coordination cages that efficiently capture iodine, polyiodides, and methyl iodide from vapor, aqueous, and organic media. The cages display exceptional uptake capacities, rapid kinetics, and high selectivity, enabling the first dynamic vapor‐phase iodine capture by coordination ...
Raghunath Singha   +5 more
wiley   +1 more source

Cryogenic TDS Platform for Quantitative Hydrogen Isotope (H2/D2/HD) Separation via Quantum Sieving in Porous Materials

open access: yesSmall, EarlyView.
The AC‐TDS enables precise hydrogen isotope analysis over a wide temperature range (15–900 K), allowing both physisorption and chemisorption processes to be investigated under gas exposure conditions. Through calibration, this system achieves reliable quantitative desorption analysis, including direct quantification of H2, D2, and HD under mixed ...
Minji Jung   +3 more
wiley   +1 more source

Reactor-based approach for achieving high-silica zeolites: a fed-batch strategy.

open access: yesJ Mater Chem A Mater
Javdani A   +8 more
europepmc   +1 more source

Zeolite

open access: yesJournal of Synthetic Organic Chemistry, Japan, 1982
openaire   +1 more source

Functional Chain Engineering in MOFs: Balancing Pore Size and Affinity for Noble Gas Separation

open access: yesSmall, EarlyView.
A series of mixed‐ligand metal‐organic frameworks (ML‐xC8) were synthesized by systematically incorporating C8 alkoxy substituents (C8BDC) into the IRMOF‐1 framework. As the C8BDC content increased, the pore size progressively decreased. ML‐80C8 (80% C8BDC) provided the optimal pore environment for selective Xe adsorption, exhibiting a markedly ...
Kyu‐Min Ryoum   +4 more
wiley   +1 more source

Brønsted acid sites in zeolites activate ozone to generate reactive oxygen species for CO oxidation. [PDF]

open access: yesNat Commun
Li L   +10 more
europepmc   +1 more source

Mechanistic Insight into H2S‐Induced Fluorescence Quenching in a Robust Metal–Organic Framework

open access: yesSmall, EarlyView.
An ultramicroporous Zn‐based metal‐organic framework, MFM‐520, enables reversible hydrogen sulfide adsorption and selective fluorescence sensing. Confinement of H2S within the pores perturbs ligand‐centered excited states through weak host‐guest interactions, enhancing non‐radiative decay pathways.
Valeria B. López‐Cervantes   +12 more
wiley   +1 more source

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