Results 161 to 170 of about 180,400 (354)

Coordinative‐Guest‐Triggered Dimensional Crossover in a Metal–Organic Framework With Rigid Metal–Oxo Rods

open access: yesChemistry – A European Journal, EarlyView.
We report a reversible structural phase transition in a metal–organic framework (MOF) triggered by the exchange of coordinative guest molecules. This MOF consists of rigid 1D Pb–O rods as building units, forming a 3D framework with 1D pores. Guest exchange induces pronounced changes in both the Pb–O rod structure and the dimensionality of the framework.
Keisuke Ishikawa, Kazuya Otsubo
wiley   +1 more source

TOPICAL REVIEW Advances in principal factors influencing carbon dioxide adsorption on zeolites

open access: yesScience and Technology of Advanced Materials, 2008
We report the advances in the principal structural and experimental factors that might influence the carbon dioxide (CO2) adsorption on natural and synthetic zeolites.
Danielle Bonenfant et al
doaj  

Durene conversion in a methanol‐to‐jet process: Exploring conversion at 150–350°C over different acid catalysts

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract Acid catalyzed conversion of durene by isomerization, disproportionation, and transalkylation is of interest to the development of a methanol‐to‐jet process to reduce the amount of durene in the kerosene. It was of interest to determine whether durene conversion could be performed at a temperature lower than 350°C.
Aida G. Velasco Ortiz   +2 more
wiley   +1 more source

Revisiting the synthesis of dimethyl carbonate from methanol and carbon dioxide

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract The process for producing dimethyl carbonate (DMC) from carbon dioxide (CO2) and methanol is explored in this article. It provides an overview of the thermodynamics involved in DMC synthesis, discussing the challenges and potential solutions. The article highlights the reported use of catalysts and dehydrating agents to improve DMC yield and ...
Diego Alexander Santos Araque   +3 more
wiley   +1 more source

Catalytic ozonation for the removal of anthropogenic organic contaminants in water

open access: yes
The ZSM-5 zeolites with varying silica to alumina ratios and with both hydrogen and sodium counter ions (Z1000H:SiO2/Al2O3 = 1000, Z900Na:SiO2/Al2O3 = 900, Z25H:SiO2/Al2O3 = 25 and Z25Na:SiO2/Al2O3 = 25) and γ-alumina have been selected as catalysts. The
Ikhlaq, Amir
core  

Innovative electrospun geopolymer/zeolite/PVA composite membranes

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Proposed scheme of gas adsorption mechanisms on electrospun geopolymer/zeolite/PVA composite membranes. Abstract Innovative electrospun poly(vinyl alcohol) (PVA)–geopolymer–zeolite 13X composite membranes were successfully fabricated and systematically characterized.
Mariana Schneider   +7 more
wiley   +1 more source

Carbon monoxide adsorption on NaY zeolite and impregnated with 5% niobium: Characteristics and fixed‐bed study

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Schematic of the CO adsorption process in a fixed‐bed column containing pure NaY zeolite and Nb‐modified NaY (NaY–5%Nb). On the left, breakthrough curves and temperature profiles highlight the dynamic performance and thermal effects during CO adsorption.
Elson Oliveira   +3 more
wiley   +1 more source

Characterization of aluminosilicate zeolites by UV Raman spectroscopy

open access: yes, 2001
A series of aluminosilicate zeolites are characterized by UV Raman spectroscopy for the first time, and UV Raman spectra of various zeolites give strong and clear bands with high resolution, while conventional Raman spectra of these zeolites are ...
Xiong, G, Yu, Y, Xiao, FS, Li, C
core  

Extended batch adsorber analogue model (e‐BAAM) for rapid evaluation of CO2 capture pressure swing adsorption cycles

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract This work presents a simplified extended‐batch adsorber analogue model (e‐BAAM) to quantify key performance metrics such as purity, recovery, and energy trends for various pressure swing adsorption (PSA) process cycles for CO2$$ {\mathrm{CO}}_2 $$ capture.
Gwyneth Liske, Arvind Rajendran
wiley   +1 more source

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