Atualmente, há uma grande demanda pelo polibutadieno com alto teor de unidades 1,4-cis, devido às suas excelentes propriedades físicas, tais como alta resistência à abrasão, baixo desenvolvimento de calor, baixa resistência ao rolamento, maior ...
Denise S. S. Nunes +2 more
doaj +1 more source
Organic Nanoparticles as Fragmentable Support for Ziegler-Natta Catalysts
A fragmentable support material for Ziegler-Natta catalysts is presented based on micrometer-sized aggregates of polystyrene nanoparticles. Hydroxyl anchoring groups are introduced by copolymerization of hydroxymethylstyrene in emulsion process to ...
Sven Nietzel +16 more
core +1 more source
Quality control for Ziegler-Natta catalysis via spectroscopic fingerprinting [PDF]
Commercial olefin polymerization catalysts are typically produced at a manufacturing site before transport to production facilities for storage and eventual use.
Vantomme, Aurélien +5 more
core
Foi utilizado o sistema catalítico tipo Ziegler-Natta modificado, constituído por TiCl4/I2/Al(i-Bu)3 para a síntese de polibutadieno com alto teor de unidades 1,4-cis.
Neusa M. T. Pires +2 more
doaj +1 more source
Stereospecific Living Ziegler−Natta Polymerization of 1-Hexene
Stereospecific Living Ziegler−Natta Polymerization of 1 ...
Kumudini C. Jayaratne (2443618) +1 more
core +1 more source
MgO/MgCl_2/TiCl_4 Core-Shell Catalyst for Establishing Structure-Performance Relationship in Ziegler-Natta Olefin Polymerization [PDF]
Recently we successfully established the first structure-performance relationships between the catalyst surface area and propylene polymerization activity using novel MgO/MgC_l2/TiCl_4 core-shell catalysts with non-porous and non-fragmentable features ...
Taniike, Toshiaki +3 more
core +1 more source
Development of Ziegler-Natta catalysts for the synthesis of polyolefins
reservedLo scopo di questa tesi è la visione dello sviluppo di catalizzatori Ziegler-Natta per la sintesi di olefine. Vedremo cos'è un catalizzatore e nello specifico uno di tipo Ziegler-Natta, considerando i suoi componenti, gli effetti che hanno, l ...
MARCELLAN, GIOVANNI
core
Evaluation of the Reactivity of Methanol and Hydrogen Sulfide Residues with the Ziegler-Natta Catalyst during Polypropylene Synthesis and Its Effects on Polymer Properties. [PDF]
Hernández-Fernández J +2 more
europepmc +1 more source
DIENES POLYMERISATION WITH METATHESIS AND ZIEGLER-NATTA HOMOGENEOUS CATALYSTS
IN THIS THESIS THE POLYMERISATION OF DIENES WITH ZIEGLER-NATTA AND METATHESIS CATALYSTS IS DESCRIBED AND THE RELATION BETWEEN THE TWO TYPES OF POLYMERISATION IS EXAMINED.
Μπόκαρης, Ευθύμιος
core +1 more source
Genesis of MgCl2-based Ziegler-Natta Catalysts as Probed with Operando Spectroscopy [PDF]
Ziegler‐Natta catalysts for olefin polymerization are intrinsically complex multi‐component systems. The genesis of the active sites involves several simultaneous and sequential steps, making the individual steps and interconnections difficult to be ...
Jongkind, Maarten K. +21 more
core +1 more source

