Results 111 to 120 of about 2,075 (218)

Theoretical Study of the Copolymerization of Ethylene and Propylene by a Heterogeneous Ziegler−Natta Catalyst

open access: yes, 2016
The copolymerization of ethylene and propylene by a heterogeneous Ti/MgCl2 Ziegler−Natta catalyst is studied with density functional theory calculations.
Tom Ziegler (1535809)   +1 more
core   +1 more source

Polymerization Properties of a Heterogeneous Ziegler−Natta Catalyst Modified by a Base:  A Theoretical Study

open access: yes, 2016
The effects of an external base (tetrahydrofuran, THF) on the ethylene polymerization properties of the TiCl4/MgCl2 heterogeneous Ziegler−Natta catalyst are examined using density functional methods.
Tom Ziegler (1535809)   +1 more
core   +1 more source

Ziegler-Natta catalyst alteration

open access: yes, 2017
Ziegler-Natta (ZN) catalysts are among the most important catalysts for the industrial production of plastics. The main components of ZN catalysts are TiCl4 in combination with an organic aluminum component as a cocatalyst, whereas a wide range of additional components exists which influence the catalyst behavior.
openaire   +1 more source

Supported Ziegler-Natta catalysts

open access: yesPolimery, 1984
JOLANTA PACHA, MARIA NOWAKOWSKA
openaire   +1 more source

Polimerização 1,4-cis de butadieno com sistemas catalíticos Ziegler-Natta à base de neodímio

open access: yesQuímica Nova, 2004
Nowadays the catalyst systems based on neodymium are the ones most used in the high cis polybutadiene production. These systems contain a neodymium compound (catalyst), an alkylaluminium compound (cocatalyst) and a halogen compound (halogenating agent ...
Mello Ivana L.   +5 more
doaj  

High activity Ziegler-Natta catalyst made from Mg powder

open access: yes, 2006
A series of novel high activity Ziegler-Natta catalysts were manufactured with spherical magnesium powder as the raw material. The morphology and properties of the catalysts and the prepolymer thereof were analyzed and characterized by scanning electron ...
Jin, C, Liu, F, Li, S, Wei, G, San, X
core  

Synthesis of Polar-functionalized Isotactic Polypropylenes Using Commercial Heterogeneous Ziegler–Natta Catalyst

open access: yes
The efficient synthesis of polar-functionalized polypropylenes with high molecular weight and high stereoregularity represents a challenging task. This challenge becomes even more daunting when pursuing an industrially preferred heterogeneous process ...
Yu Wang (12152)   +3 more
core   +1 more source

Quantitative Screening of Ziegler-Natta: Catalyst Regioselectivity

open access: yes, 2015
High Throughput Experimentation (HTE) has gained importance in the screening of olefin polymerization catalysts. In particular, its recent integration with ‘fast’ 13C NMR spectrometers represents a most powerful tool for mechanistic investigations ...
CIPULLO, ROBERTA
core  

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