Results 51 to 60 of about 4,978 (205)

Half-titanocene 5-t-butyl-2-(1-(arylimino)methyl)quinolin-8-olate chlorides: Synthesis, characterization and ethylene (co-) polymerization behavior [PDF]

, 2013
A series of half-titanocene chloride complexes bearing 5-t-butyl-2-(1-(arylimino)methyl)quinolin-8-olate ligands (L), CpTiLCl₂, has been synthesized in acceptable yields by the stoichiometric reaction of CpTiCl₃ with the respective potassium 5-t-butyl-2-(
Chen, Langqiu, Redshaw, Carl, Sun, Wen-Hua, Wang, Lin, Yan, Qing, Yang, Wenhong   +5 more
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Effects of SUpport preparation on the perfonnance of the catalysts Ziegler-Natta based in TiCI4/MgCI2

Revista Técnica de la Facultad de Ingeniería, 2011
The properties of supported Ziegler-Natta catalysts depend mostly on the preparation of the support. Four kinds of Ziegler-Natta catalysts consisting of TIC4 supported on MgCh were prepared, differting mainly by the method used to prepare the support ...
F. Medina, M. Hidalgo, R Sanchéz, T. Rajmankina, A. Parada   +4 more
doaj  

Discovery and development of metallocene-based polyolefins with special properties [PDF]

Polyolefins Journal, 2015
Beside Ziegler-Natta and Phillips catalysts the development of methylaluminoxane (MAO) as cocatalyst in combination with metallocenes or other transition metal complexes for the polymerization of olefins has widely increased the possibilities in ...
Walter Kaminsky, Mercia Fernandes
doaj   +1 more source

50th Anniversary Perspective: Living Polymerization—Emphasizing the Molecule in Macromolecules [PDF]

, 2017
The ideal of living polymerization has defined research in polymer chemistry over the past 50 years. In this Perspective, we present the case that this concept has enabled the treatment of polymers as organic molecules, rather than impure mixtures of ...
Grubbs, Robert B., Grubbs, Robert H.
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A Silicon-Bridged Bis(substituted Cp) Yttrium Complex [PDF]

, 1992
rac-Bis(tetrahydrofuran)lithium [bis(2-trimethylsilyl-4-tert-butyl-η^5-cyclopentadienyl)dimethylsilane] dichloroyttrate, [Li(C_4H_80)_2][Y(C_(26)H_(48)-Si_3)Cl_2], M_r= 755.87, triclinic, Pl, ɑ = 13.110 (8), b = 17.163 (15), c = 20.623 (14) Å, ɑ= 104.02 (
Bercaw, John E., Coughlin, E. Bryan, Marsh, Richard E., Schaefer, William P.   +3 more
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Understanding the activity and stability of Lewis acid-modified Ziegler–Natta catalysts for the sustainable production of polypropylene

Journal of Taibah University for Science
Cleaner polymer production involves minimizing environmental impact by using efficient catalysts and eco-friendly synthesis methods. Identifying active and stable catalysts is essential.
Rafik Rajjak Shaikh, Yodsamol Sainu, Supareak Praserthdam, Piyasan Praserthdam   +3 more
doaj   +1 more source

UHMWPE/HDPE in-reactor blends, prepared by in situ polymerization: synthetic aspects and characterization [PDF]

, 2017
This work covers the synthesis and characterization of in-reactor Ultra-High Molecular Weight Polyethylene/ High Density Polyethylene, UHMWPE/HDPE, blends by in situ polymerization in a single reactor, through dual catalyst immobilization. These blends
Cerrada, M. L., Cramail, H., Ferreira, A. E., Lorenzo, V., Lourenco, J. P., Pérez, Ernesto, Ressia, J., Ribeiro, M. R., Vallés, E.   +8 more
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Structure of a Permethylcyclopentadienyl-μ-tetramethylcyclopentadienylmethylene Scandium Dimer [PDF]

, 1992
Bis(η^5-pentamethylcyclopentadienyl)-bis[μ-2,3,4,5-tetramethyl-1-methylene-ScC^1:Sc'(η^5)-cyclopentadienyl]-discandium(III), [Sc_2(C_(10)H_(15))_2-(C_(10)H_(14)_2], M_r = 628.90, triclinic, Pl, ɑ = 8.641 (5), b= 9.478 (2), c = 12.338 (5) Å, ɑ = 75.58 (3),
Bercaw, John E., Hajela, Sharad, Schaefer, William P.   +2 more
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Structure-property relations of heterophasic ethylene-propylene copolymers based on a single-site catalyst

eXPRESS Polymer Letters, 2017
The target of the present study was to investigate the structure-property relationships of heterophasic ethylenepropylene (EP) copolymers based on a single-site (metallocene) catalyst (SSC) supported with an emulsion technology developed by Borealis. The
M. Aarnio-Winterhof, P. Doshev, J. Seppala, M. Gahleitner   +3 more
doaj   +1 more source

Technology Strategies in the Knowldge Economy. The Licensing Activity of Himont [PDF]

The exchange of technologies and technological knowledge - through joint-ventures, partnerships, licensing, cross-licensing, R&D contracts - and the upsurge of markets for technology are main features of the "knowledge-based" economy.
Fabrizio Cesaroni
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