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Electrodeposited Zinc-Based Films as Anodes for Aqueous Zinc Batteries
ACS Applied Materials & Interfaces, 2020In the past thirty years, there has been significant development in the search for alternative energy sources such as secondary battery systems. Zinc (fourth-most mined material) has attracted much attention due to its abundance, low-cost, and recyclability. More-over, as Zinc-based batteries can be manufactured with aqueous-based electrolytes, this
Matthew Fayette +4 more
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Journal of Applied Chemistry, 1958
AbstractLaboratory and full‐scale trials of zinc anodes have shown that the presence of small amounts of aluminium (0.5–1.0%) gives improved performance and that addition also of 0.25–0.5% of silicon is more effective. The detrimental effect of iron is overcome by these additions.
J. T. Crennell, W. C. G. Wheeler
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AbstractLaboratory and full‐scale trials of zinc anodes have shown that the presence of small amounts of aluminium (0.5–1.0%) gives improved performance and that addition also of 0.25–0.5% of silicon is more effective. The detrimental effect of iron is overcome by these additions.
J. T. Crennell, W. C. G. Wheeler
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Hydrated Solvation Suppression of Zinc Ions for Highly Reversible Zinc Anodes
Chemical Engineering Journal, 2023Low-cost and high-safety aqueous zinc batteries are promising for large-scale energy storage applications. However, the actual performance of aqueous zinc batteries is hampered by the irreversibility of the zinc metal anode originating from the dendrite growth and side reactions, which are associated closely with the hydrated solvation sheath of Zn2 ...
Qinping Jian +4 more
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Anodic Oxidation of Zinc Phosphide
Japanese Journal of Applied Physics, 1986Initial stages of a native oxidation on Zn3P2 by anodization have been investigated for the first time using 3% tartaric acid/propylene glycol electrolyte. A constant-current anodization is found to be superior to a constant-voltage anodization because of the rapid growth of the initial stage in the constant-voltage mode in view of controlling thin ...
Toshikazu Suda +2 more
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Zinc Powder Anodes for Rechargeable Aqueous Zinc-Based Batteries
Nano LettersAqueous rechargeable zinc-based batteries hold great promise for energy storage applications, with most research utilizing zinc foils as the anode. Conversely, the high tunability of zinc powder (Zn-P) makes it an ideal choice for zinc-based batteries, seamlessly integrating with current battery production technologies.
Qing Li, Nan Li, Chunyi Zhi
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The anodic behaviour of zinc in saturated solution of zinc sulphate
Electrochimica Acta, 1972Abstract Using 65 Zn and 35 S marked zinc sulphate, we have shown with a zinc rotating disk electrode, that in saturated solution of zinc sulphate, after formation of a pore-free salt layer, the anodic reaction consists in the direct reaction of the metal with sulphate ion into solid salt.
K. Schwabe, H.-B. Lück
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Hydrophobic Organic‐Electrolyte‐Protected Zinc Anodes for Aqueous Zinc Batteries
Angewandte Chemie International Edition, 2020AbstractAqueous Zn batteries are promising energy‐storage devices. However, their lifespan is limited by irreversible Zn anodes owing to water decomposition and Zn dendrite growth. Here, we separate aqueous electrolyte from Zn anode by coating a thin MOF layer on anode and filling the pores of MOF with hydrophobic Zn(TFSI)2‐tris(2,2,2‐trifluoroethyl ...
Longsheng Cao +4 more
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Surface Engineering on Zinc Anode for Aqueous Zinc Metal Batteries
ChemSusChemAbstractRechargeable aqueous zinc metal batteries (AZMBs) are considered as a potential alternative to lithium‐ion batteries due to their low cost, high safety, and environmental friendliness. However, the Zn anodes in AZMBs face severe challenges, such as dendrite growth, metal corrosion, and hydrogen evolution, all of which are closely related to the
Huili Peng +5 more
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An anode-free zinc-ion battery
C&EN Global Enterprise, 2021For rechargeable batteries, zinc chemistry presents a low-cost and potentially safer option than lithium and sodium.
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Zinc Anodes for Cathodic Protection
Anti-Corrosion Methods and Materials, 1957Historically, zinc was first used to provide cathodic protection to the copper‐sheathed hulls of warships a century and a quarter ago. The practice continued with steel‐hulled ships and ‘zincs’ were fitted to most naval vessels. The sacrificial action was not great and electrical contact to the hull was often poor.
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