Unsaturated Coordination Oxygen in Zn─V─O Vacancy Clusters Enables Superb Zinc Storage Capability
Zn3(VO4)2 with Zn─V─O vacancy clusters was synthesized and innovatively applied as cathode material in aqueous Zn‐ion batteries. In‐situ XRD, HRTEM and ab initio molecular dynamics simulations unveil the double reaction mechanism of zinc ions. Adsorption of zinc ions on unsaturated coordination O and H+ on O in ‐VO4 contributes to the main capacity. It
Yulong Chi +8 more
wiley +1 more source
Biomimetic Localized Gel Electrolyte for Practical Zinc Anode. [PDF]
Zhu Y +12 more
europepmc +1 more source
This study reports the first application of a W‐oxo bis(dithiolene) complex, (Et4N)2[WO(S2C2(C6H5)2)2], as a novel anode material for lithium‐ion batteries. This complex stores Li+ ions via multivalent W‐centered redox processes involving its oxo (WO) and dithiolene (S) sites.
Honggyu Seong +5 more
wiley +1 more source
Electrolyte Additive-Assembled Interconnecting Molecules-Zinc Anode Interface for Zinc-Ion Hybrid Supercapacitors. [PDF]
Li Y +5 more
europepmc +1 more source
Heterointerface‑Enabled Electrocatalysis for Efficient Energy Conversion
Functionally distinct A/B materials can be integrated at the nanoscale to create customized heterointerfaces with tunable band alignment and charge redistribution, providing fast electron and ion transport channels as well as cooperative dual active sites.
Liuru Fang +3 more
wiley +1 more source
Molecular Damping Effect of Trace Additives Enhances Zinc Anode Stability Under High Depth of Discharge. [PDF]
Li Y +8 more
europepmc +1 more source
A multifunctional mercaptosuccinic acid enables an ultrathin organic–inorganic SEI (Zn‐S‐RCOOH) that synergistically regulates interfacial water and accelerates Zn2+ transport. The optimized hydrogen‐bond environment and ZnS‐guided deposition suppress dendrites, corrosion, and by‐product formation, delivering ultrastable Zn cycling and high‐performance
Huaichong Sun +11 more
wiley +1 more source
A weak acid-responsive porous polyelectrolyte membrane enables the high efficiency of a zinc anode interface. [PDF]
Li W +10 more
europepmc +1 more source
Tailored Catalytic Microenvironments Enable Efficient Electrochemical Ammonia Production
This study shows that Co2+ substitution in inverse spinel FeFeCoO4 constructs an integrated catalytic microenvironment for efficient nitrate‐to‐ammonia reduction. Jahn–Teller distortion activates Fe sites for *H generation, while hard–soft acid–base regulated dual‐metal sites optimize proton‐coupled electron transfer and intermediate adsorption ...
Qi Zhang +8 more
wiley +1 more source
Integration of zinc anode and cement: unlocking scalable energy storage. [PDF]
Liu Z +10 more
europepmc +1 more source

