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Artificial interphase engineering to stabilize aqueous zinc metal anodes
Nanoscale, 2021In this mini-review, the state-of-the-art knowledge on the rational artificial interphase engineering of zinc metal anodes for high performance aqueous zinc ion batteries are presented.
Zichao Yan, Wenli Xin, Zhiqiang Zhu
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Inorganic Hybrid Interfacial Layer for a Stable Zinc Metal Anode
ACS Applied Materials & Interfaces, 2023In aqueous zinc-ion batteries (AZIBs), the zinc metal anode faces serious problems such as dendrite growth, interface corrosion, and byproduct accumulation, which hinder the commercialization process of AZIBs. Herein, an inorganic hybrid interfacial layer ZnF2/ZnSe (ZnFS) including the insulating interfacial phase (ZnF2) and conductive interfacial ...
Zhenhua Hou +3 more
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A Lean‐Zinc and Zincophilic Anode for Highly Reversible Zinc Metal Batteries
Advanced Functional Materials, 2023AbstractLean‐zinc anode is a promising configuration that can eliminate the trade‐off of energy density and cycle lifetime of zinc metal (Zn0) batteries. However, there are rare investigations of lean‐Zn anode designs and it remains a grand change to sustain high zinc reversibility under lean zinc conditions.
Chao Li +9 more
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Optimizing Porous Metal–Organic Layers for Stable Zinc Anodes
ACS Applied Materials & Interfaces, 2023Aqueous zinc-ion batteries (ZIBs) have been considered as alternative stationary energy storage systems, but the dendrite and corrosion issues of Zn anodes hinder their practical applications. Here we report a series of two-dimensional (2D) metal-organic frameworks (MOFs) with Zr12 clusters, which act as artificial solid electrolyte interphase (SEI ...
Liling Lei +8 more
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The role of glass fiber separators on the cycling of zinc metal anodes
Journal of Membrane Science, 2023Aqueous zinc-ion batteries (AZIBs) have shown promising suitability for grid-scale energy storage due to their affordability, intrinsic safety, and environmental-friendliness. However, the commercialization of AZIBs has been hindered by the dissolution of the cathode and instabilities of the Zn metal anode.
Evan J. Hansen +4 more
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Highly reversible zinc metal anode for aqueous batteries
Nature Materials, 2018Metallic zinc (Zn) has been regarded as an ideal anode material for aqueous batteries because of its high theoretical capacity (820 mA h g-1), low potential (-0.762 V versus the standard hydrogen electrode), high abundance, low toxicity and intrinsic safety.
Fei Wang +9 more
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Oriented Zinc Metal Anode Based on Directional Recognition and Assembly
Small, 2023AbstractThe practical application of aqueous zinc batteries are highly limited by unsatisfied Zn anodes for the unavoidable dendrite growth and side reactions. Crystal orientation engineering is an effective way to overcome these inherent drawbacks.
Shimeng Zhang +3 more
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Aluminum and Zinc Metal Anode Batteries
2021Aluminum and zinc metal are expected to be anode active materials with high volumetric capacity for future secondary batteries. Theoretical volumetric capacities for Al and Zn are 5854 and 8046 mAh cm−3, respectively. These metal anodes are usually handled in the Lewis acid-base type ionic liquid (IL) electrolytes with Al or Zn salts, e.g., AlCl3–1 ...
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Sustainable Phytic Acid–Zinc Anticorrosion Interface for Highly Reversible Zinc Metal Anodes
ACS Applied Materials & Interfaces, 2022Although aqueous zinc-ion batteries (AZIBs) promise high capacity, low cost, and environmental friendliness, the Zn metal anode suffers from limited reversibility and unsatisfied lifespan arising from severe dendritic growth and inevitable interfacial corrosion.
Ying Zhang +6 more
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Engineering interfaces of zinc metal anode for stable batteries
Chemical Engineering JournalJinchao Cao, Guojie Li, Aoxuan Wang
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