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Artificial interphase engineering to stabilize aqueous zinc metal anodes

Nanoscale, 2021
In this mini-review, the state-of-the-art knowledge on the rational artificial interphase engineering of zinc metal anodes for high performance aqueous zinc ion batteries are presented.
Zichao Yan, Wenli Xin, Zhiqiang Zhu
openaire   +2 more sources

Inorganic Hybrid Interfacial Layer for a Stable Zinc Metal Anode

ACS Applied Materials & Interfaces, 2023
In aqueous zinc-ion batteries (AZIBs), the zinc metal anode faces serious problems such as dendrite growth, interface corrosion, and byproduct accumulation, which hinder the commercialization process of AZIBs. Herein, an inorganic hybrid interfacial layer ZnF2/ZnSe (ZnFS) including the insulating interfacial phase (ZnF2) and conductive interfacial ...
Zhenhua Hou   +3 more
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A Lean‐Zinc and Zincophilic Anode for Highly Reversible Zinc Metal Batteries

Advanced Functional Materials, 2023
AbstractLean‐zinc anode is a promising configuration that can eliminate the trade‐off of energy density and cycle lifetime of zinc metal (Zn0) batteries. However, there are rare investigations of lean‐Zn anode designs and it remains a grand change to sustain high zinc reversibility under lean zinc conditions.
Chao Li   +9 more
openaire   +1 more source

Optimizing Porous Metal–Organic Layers for Stable Zinc Anodes

ACS Applied Materials & Interfaces, 2023
Aqueous zinc-ion batteries (ZIBs) have been considered as alternative stationary energy storage systems, but the dendrite and corrosion issues of Zn anodes hinder their practical applications. Here we report a series of two-dimensional (2D) metal-organic frameworks (MOFs) with Zr12 clusters, which act as artificial solid electrolyte interphase (SEI ...
Liling Lei   +8 more
openaire   +2 more sources

The role of glass fiber separators on the cycling of zinc metal anodes

Journal of Membrane Science, 2023
Aqueous zinc-ion batteries (AZIBs) have shown promising suitability for grid-scale energy storage due to their affordability, intrinsic safety, and environmental-friendliness. However, the commercialization of AZIBs has been hindered by the dissolution of the cathode and instabilities of the Zn metal anode.
Evan J. Hansen   +4 more
openaire   +1 more source

Highly reversible zinc metal anode for aqueous batteries

Nature Materials, 2018
Metallic zinc (Zn) has been regarded as an ideal anode material for aqueous batteries because of its high theoretical capacity (820 mA h g-1), low potential (-0.762 V versus the standard hydrogen electrode), high abundance, low toxicity and intrinsic safety.
Fei Wang   +9 more
openaire   +2 more sources

Oriented Zinc Metal Anode Based on Directional Recognition and Assembly

Small, 2023
AbstractThe practical application of aqueous zinc batteries are highly limited by unsatisfied Zn anodes for the unavoidable dendrite growth and side reactions. Crystal orientation engineering is an effective way to overcome these inherent drawbacks.
Shimeng Zhang   +3 more
openaire   +2 more sources

Aluminum and Zinc Metal Anode Batteries

2021
Aluminum and zinc metal are expected to be anode active materials with high volumetric capacity for future secondary batteries. Theoretical volumetric capacities for Al and Zn are 5854 and 8046 mAh cm−3, respectively. These metal anodes are usually handled in the Lewis acid-base type ionic liquid (IL) electrolytes with Al or Zn salts, e.g., AlCl3–1 ...
openaire   +1 more source

Sustainable Phytic Acid–Zinc Anticorrosion Interface for Highly Reversible Zinc Metal Anodes

ACS Applied Materials & Interfaces, 2022
Although aqueous zinc-ion batteries (AZIBs) promise high capacity, low cost, and environmental friendliness, the Zn metal anode suffers from limited reversibility and unsatisfied lifespan arising from severe dendritic growth and inevitable interfacial corrosion.
Ying Zhang   +6 more
openaire   +2 more sources

Engineering interfaces of zinc metal anode for stable batteries

Chemical Engineering Journal
Jinchao Cao, Guojie Li, Aoxuan Wang
exaly   +2 more sources

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