Overcoming the crystallization and designability issues in the ultrastable zirconium phosphonate framework system [PDF]
Zirconium phosphonate based metal-organic frameworks often exhibit superior chemical stabilities, but typically exist as poorly crystalline or amorphous materials.
Tao Zheng +17 more
doaj +5 more sources
Zirconium (IV) layered phosphonate-phosphate as catalysts for the valorization of glycerol [PDF]
The valorization of glycerol, a large-volume byproduct of biodiesel production, remains a key challenge for the biorefinery sector. Among the available strategies, its acetalization with acetone offers a sustainable route to produce solketal, a valuable ...
Nahal Ghanemnia +14 more
doaj +8 more sources
Phosphonate-substituted zirconium oxo clusters [PDF]
The phosphonate-substituted zirconium oxo clusters Zr6O2(OBu)12(O3PPh)4 and Zr7O2(OiPr)12(O3PCH2CH2CH2Br)6, with octahedrally coordinated Zr atoms, were synthesized by reaction of zirconium alkoxides with phosphonic acid bis(trimethylsilyl) esters. The basic structural motif are Zr3O(µ2-OR)3(OR)3 units which are connected in different ways.
Ulrich Schubert +2 more
exaly +5 more sources
Zirconium Phosphonate Sorbent Materials-Synthesis, Characterization, and Application for Copper Removal from Acidic Wastewater. [PDF]
Copper removal from wastewater is a major challenge in the treatment of both hydrometallurgical copper recycling effluents and mining wastewater. The use of sorbents is considered the most efficient and environmentally friendly method for this purpose ...
Marszałek M +3 more
europepmc +4 more sources
Immobilization of Alendronate on Zirconium Phosphate Nanoplatelets [PDF]
Different amounts of sodium-alendronate (ALN) were loaded into layered zirconium phosphates of alpha and gamma type (αZP and γZP) by means of topotactic exchange reactions of phosphate with ALN.
Anna Donnadio +8 more
doaj +2 more sources
The Sol–Gel Process, a Green Method Used to Obtain Hybrid Materials Containing Phosphorus and Zirconium [PDF]
The sol–gel process is a green method used in the last few decades to synthesize new organic–inorganic phosphorus-containing hybrid materials. The sol–gel synthesis is a green method because it takes place in mild conditions, mostly by using water or ...
Petru Merghes +4 more
doaj +2 more sources
Preparation of novel zirconium phosphonates for adsorption of lutetium
Separation and recovery of 177Lu from radioactive medicine waste is concerned due to its potential application in radiopharmaceuticals. In this paper, two zirconium phosphonate materials (Zr-AMTP-1 and Zr-AMTP-2) were prepared by water-bath and ...
Wanjun Mu +5 more
doaj +2 more sources
The present study aims to develop a layered zirconium phosphate/phosphonate (LZP) powder to control the release of therapeutic inorganic ions. Organically modified LZPs were successfully prepared with various contents of phenyl groups via a reflux method
Jin Nakamura +4 more
doaj +2 more sources
XPS investigation of DNA binding to zirconium-phosphonate surfaces
The surface coverage of phosphorylated oligonucleotides immobilized on a zirconium-phosphonate surface was analyzed using X-ray photoelectron spectroscopy (XPS). By quantifying the intensity of the N 1s signal originating from the oligonucleotide and the Zr 3d peak from the metal-phosphonate surface, the surface coverage of the oligonucleotide could be
Marc Petit +2 more
exaly +5 more sources
A comparative study of adsorption properties of zirconium (IV) phosphonates for removal of 90Sr
With as goal of improving on traditional α-ZrP, four zirconium phosphonate materials were prepared as potential adsorbents for the removal of 90Sr from nuclear wastewater.
Wanjun Mu, Baihua Chen, Xingliang Li
doaj +1 more source

