Results 131 to 140 of about 2,731 (183)
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Zirconium−Phosphonate Monolayers with Embedded Disulfide Bonds
Langmuir, 2003Disulfides are chemically and electrochemically reactive functional groups that could be useful for ultra-high-resolution patterning of self-assembled monolayer films (SAMs) by atomic force microscopic (AFM) anodization. Zirconium−organophosphonate monolayers that contain embedded disulfide bonds were prepared by sequential deposition of Zr4+ and H2PO3-
Xuejun Wang, Marya Lieberman
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Catalyst design of two-dimensional zirconium phosphonates
Journal of Molecular Catalysis, 1992Abstract Zirconium phosphates or phosphonates, whose compounds have the general formula Zr(O3PR)2, can be obtained in crystalline forms with various layered structures. The preparation and characterization of two-dimensional zirconium phosphonate derivatives have been investigated.
Kohichi Segawa +2 more
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Chapter 2. Zirconium Phosphonates
2011This contribution presents a survey of the various aspects of the chemistry of Zr phosphonates, throughout 30 years of activity of the Laboratory of Inorganic Chemistry of Perugia on this topic. These inorganic–organic compounds are characterized by a very low solubility and chemical robustness, and their structure and reactivity can be easily ...
Riccardo Vivani +2 more
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Zirconium(IV) Phosphonate–Phosphates as Efficient Ion-Exchange Materials
Inorganic Chemistry, 2016Layered metal phosphonate-phosphate hybrid materials are known to be ion-exchange materials. Hybrids with zirconium metal centers were synthesized at varying phosphonate-phosphate ratios in order to explore the function and charge preference. The zirconium hybrid materials were found to have a range of applicable uses with preference for highly charged
Rita, Silbernagel +2 more
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Mesoporous Zirconium Phenylenesiliconate‐phosphonate Hybrids with Ordered Lamellar Nanostructures
Chemistry – A European Journal, 2015AbstractNovel ordered lamellar mesostructure pZrPS‐2 was hydrothermally prepared by using zirconium propoxide and 4‐(EtO)2OPC6H4Si(OEt)3 (pPPS‐E), which was hydrolyzed to organic building units substituted with both siliconate and phosphonate groups, in the presence of CnTAB and TMAOH.
Kazuyuki, Maeda +5 more
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Intercalates of zirconium phosphates and phosphonates
1991Abstract Tetravalent metals such as Zr, Ti, Sn, Ce, Th, etc. can be bound to oxygens belonging to XO4 and/or RXO3 groups (X = pentavalent element; R =inorganic or organic group such as -H, -OH, -CH3, -C6H5, etc.) and from such a combination many fibrous, layered, and three-dimensional structures can be obtained.
Giulio Alberti, Umberto Costantino
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α-Zirconium phosphonates: versatile supports for N-heterocyclic carbenes
Chemical Communications, 2009alpha-Zirconium phosphonates derivatised with N-heterocyclic carbenes provide a versatile platform for organocatalysis and metal-catalysed transformations, including the ring-opening polymerisation of cyclic esters, and olefin metathesis and hydroformylations by surface-bound ruthenium, rhodium and iridium complexes.
Chessa, Simona +3 more
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Solid State Ionics, 1996
Five γ-layered zirconium phosphonates containing sulfophenyl, sulfobenzyl, as well as mono- and di-fluorinated sulfobenzyl groups in the interlayer region, have been prepared by topotactic exchange starting from γ-zirconium phosphate in the hydrogen form.
G. Alberti +4 more
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Five γ-layered zirconium phosphonates containing sulfophenyl, sulfobenzyl, as well as mono- and di-fluorinated sulfobenzyl groups in the interlayer region, have been prepared by topotactic exchange starting from γ-zirconium phosphate in the hydrogen form.
G. Alberti +4 more
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Bifunctional Mesoporous Zirconium Phosphonates for Delivery of Nucleic Acids
Inorganic Chemistry, 2013The bifunctional mesoporous zirconium phosphonates (ZrBFs) were synthesized through surfactant-assisted co-condensation of ZrCl(4) with two different phosphonic acids, both 1-phosphomethylproline (H(3)PMP) and 1,4-bis(phosphomethyl)piperazine (BPMP), in a one-pot procedure.
Yan, Tang, Yubao, Ren, Xin, Shi
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Asymmetric Aldol Reaction Using Zirconium Phosphonate Supported l-Proline
Synfacts, 2014Zirconium phosphonates supported L-proline (ZrPB-Pro) was prepared from functionalized L-proline PB-Pro, methyl and phenylphosphonic acid, and ZrOCl2. ZrPB-Pro catalyzed the direct asymmetric aldol addition reaction to give the adducts with good to excellent stereoselectivity.
Angeloni M. +3 more
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