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Surface-Engineered Zn-Based Alloys Anodes for Aqueous Zn Batteries

ECS Meeting Abstracts, 2023
Safety and durability concerns caused by surface and interface instabilities of high-surface-activity energy materials are challenging modern electrochemical energy conversion and storage systems. In this presentation, I will present our most recent representative works on the surface engineering of functional materials for aqueous batteries.
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Tuning Zn‐Ion Solvation Chemistry with Chelating Ligands toward Stable Aqueous Zn Anodes

Advanced Materials, 2022
AbstractChanging the solvation sheath of hydrated Zn ions is an effective strategy to stabilize Zn anodes to obtain a practical aqueous Zn‐ion battery. However, key points related to the rational design remain unclear including how the properties of the solvent molecules intrinsically regulate the solvated structure of the Zn ions.
Rongwei Meng   +9 more
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Surface and Interface Engineering of Zn Anodes in Aqueous Rechargeable Zn‐Ion Batteries

Small, 2022
AbstractRechargeable zinc‐ion batteries (ZIBs) have shown great potential as an alternative to lithium‐ion batteries. The ZIBs utilize Zn metal as the anode, which possesses many advantages such as low cost, high safety, eco‐friendliness, and high capacity.
Jiaxian Zheng   +8 more
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Strategies for Optimizing the Zn Anode/Electrolyte Interfaces Toward Stable Zn‐Based Batteries

Small Methods, 2023
AbstractAqueous rechargeable Zn‐ion batteries (ARZIBs) have attracted extensive attention because of the advantages of high energy density, high safety, and low cost. However, the commercialization of ARZIBs is still challenging, mainly because of the low efficiency of Zn anodes. Several undesirable reactions (e.g., Zn dendrite and byproduct formation)
Jiechang Gao   +3 more
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Luminescence properties of anodically etched porous Zn

Applied Surface Science, 2000
Anodization of Zn in HF/ethanol and NaOH solution yields porous structure, which luminesces in the visible region. It is observed that the luminescence properties of these samples have been found quite different. The p-Zn prepared in NaOH displays two luminescence peaks near 420 and 520 nm. On the contrary, the p-Zn prepared in HF displays luminescence
Sung-Sik Chang   +3 more
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Smart Self‐Healing Anode/Electrolyte Interphases for Stabilizing Zn Anode

Advanced Materials
AbstractThe rational design of Zn anode/electrolyte interphases (AEIs) is an effective strategy for regulating the Zn2+ stripping/plating process, as well as suppressing the interfacial side reactions. However, the formation of defects during the cycling process is still inevitable, and the exacerbation of defects would lead to the failure of the ...
Haifeng Bian   +8 more
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Engineering hosts for Zn anodes in aqueous Zn-ion batteries

Energy & Environmental Science
This review systematically summarizes the host-design strategies for Zn anodes regarding substrate and interface fabrication, aiming to provide a prospective guideline for developing high-performance Zn anodes.
Yunhai Zhu   +6 more
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Anodic Behaviour of Electrodeposited Zn-Sn Alloys

Transactions of the IMF, 1998
SummaryThe paper discusses the anodic behaviour of the electrodeposited alloys Zn-15%Sn in comparison with pure Zn coatings in 0.5M Na2SO4 and 5% NaCI. A passive state in 0.5M Na2SO4 medium was registered for the alloy while in 5% NaCI the typical passive state was not observed.
V. Ivanova   +3 more
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Achieving high-durability aqueous Zn-ion batteries enabled by reanimating inactive Zn on Zn anodes

Journal of Colloid and Interface Science
The heavy by-products generated on Zn anode surface decrease the active surface of Zn anodes and thus induce uneven Zn deposition, seriously reducing the service life of aqueous Zn-ion batteries (AZIBs). Herein, we propose an elimination strategy enabled by the coordination chemistry to dissolve the main by-products (Zn4SO4(OH)6·xH2O).
Yuanze Yu   +6 more
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Guiding uniform Zn deposition with a multifunctional additive for highly utilized Zn anodes

Nanoscale
As a multifunctional additive for 2 M ZnSO4 electrolyte, l-leucine with abundant carboxyl and amino groups, exhibits strong interactions with Zn-ion to disrupt its solvation structure, inhibiting the occurrence of side reactions and promoting uniform Zn electrodeposition.
Xi Li   +7 more
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