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Smart Self‐Healing Anode/Electrolyte Interphases for Stabilizing Zn Anode

Advanced Materials
AbstractThe rational design of Zn anode/electrolyte interphases (AEIs) is an effective strategy for regulating the Zn2+ stripping/plating process, as well as suppressing the interfacial side reactions. However, the formation of defects during the cycling process is still inevitable, and the exacerbation of defects would lead to the failure of the ...
Haifeng Bian   +8 more
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Engineering hosts for Zn anodes in aqueous Zn-ion batteries

Energy & Environmental Science
This review systematically summarizes the host-design strategies for Zn anodes regarding substrate and interface fabrication, aiming to provide a prospective guideline for developing high-performance Zn anodes.
Yunhai Zhu   +6 more
openaire   +1 more source

Anodic Behaviour of Electrodeposited Zn-Sn Alloys

Transactions of the IMF, 1998
SummaryThe paper discusses the anodic behaviour of the electrodeposited alloys Zn-15%Sn in comparison with pure Zn coatings in 0.5M Na2SO4 and 5% NaCI. A passive state in 0.5M Na2SO4 medium was registered for the alloy while in 5% NaCI the typical passive state was not observed.
V. Ivanova   +3 more
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Achieving high-durability aqueous Zn-ion batteries enabled by reanimating inactive Zn on Zn anodes

Journal of Colloid and Interface Science
The heavy by-products generated on Zn anode surface decrease the active surface of Zn anodes and thus induce uneven Zn deposition, seriously reducing the service life of aqueous Zn-ion batteries (AZIBs). Herein, we propose an elimination strategy enabled by the coordination chemistry to dissolve the main by-products (Zn4SO4(OH)6·xH2O).
Yuanze Yu   +6 more
openaire   +2 more sources

Guiding uniform Zn deposition with a multifunctional additive for highly utilized Zn anodes

Nanoscale
As a multifunctional additive for 2 M ZnSO4 electrolyte, l-leucine with abundant carboxyl and amino groups, exhibits strong interactions with Zn-ion to disrupt its solvation structure, inhibiting the occurrence of side reactions and promoting uniform Zn electrodeposition.
Xi Li   +7 more
openaire   +2 more sources

Solvation Reconfiguration and Controllable Zn(101) Deposition Enable Stable Zn Anodes

Advanced Functional Materials
Abstract Deposition of Zn 2+ along the (002) crystal plane often leads to uneven deposition and dendrites, which increases the risk of short circuits and shortens battery lifespan.
Hanqi Zhao   +4 more
openaire   +1 more source

Maltose Additive Enables Compacted Deposition of Zn Ions for Stabilizing the Zn Anode

ACS Applied Materials & Interfaces
Aqueous zinc-ion batteries (AZIBs) have emerged as one of the most promising energy storage technologies due to their high safety and cost-effectiveness. However, several challenges associated with the Zn metal anode, such as dendrite growth, corrosion, and hydrogen evolution reaction (HER), have hindered further applications of AZIBs. Herein, maltose (
Huan Liu   +9 more
openaire   +2 more sources

Multifunctional Separator for Zn Metal Anode Protection

ECS Meeting Abstracts
Lithium-ion batteries (LIBs) have issues such as the high cost of raw materials due to the use of rare metals such as Li and Co in the electrode and the risk of fire due to the use of organic electrolytes.[1] Zn-ion batteries (ZIBs) based on aqueous electrolytes are inexpensive (~US$2 kg-1) and safe for practical use.[2] In addition, the high ...
Wei Yu   +3 more
openaire   +1 more source

A triflate porous layer stabilizing Zn anodes for high-performance Zn-ion batteries

Chemical Communications
A triflate porous layer is constructed on Zn anodes, which stabilizes the surface pH and contributes to a ZnF2-containing interphase during cycling. This interphase significantly enhances the reversibility and reaction kinetics of the Zn anodes.
Ruijun Rao   +9 more
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Sulfurized Composite Interphase Enables a Highly Reversible Zn Anode

Angewandte Chemie International Edition
AbstractThe stability and reversibility of Zn anode can be greatly improved by in situ construction of solid electrolyte interphase (SEI) on Zn surface via a low‐cost design strategy of ZnSO4 electrolyte. However, the role of hydrogen bond acceptor ‐SO3 accompanying ZnS formation during SEI reconstruction is overlooked.
Lu Wu   +12 more
openaire   +2 more sources

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