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Lotus Effect Inspired Hydrophobic Strategy for Stable Zn Metal Anodes
Advanced Materials, 2023AbstractZn‐ion batteries (ZIBs) have long suffered from the unstable Zn metal anode, which faces numerous challenges concerning dendrite growth, corrosion, and hydrogen evolution reaction. The absence of H2O adsorption control techniques has become a bottleneck for the further development of ZIBs.
Lishun Han +9 more
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Interfacial Reconstruction for Regulating Zn2+ Deposition toward Ultrastable Zn Metal Anodes
ACS Applied Materials & Interfaces, 2023Rechargeable aqueous zinc-ion batteries (AZIBs) are attracting much attention as high-density energy storage systems owing to their fascinating features with low cost, high safety, and simple manufacturing process. However, the commercialization of Zn anodes is hindered by uncontrollable dendrite growth and water-induced side reactions.
Chengwu Yang +6 more
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Nano-semiconductor material stabilized Zn metal anode for long-life aqueous Zn-ion batteries
Journal of Colloid and Interface Science, 2023The advantages of aqueous Zn-ion batteries lie in the affordability and environmental friendliness. Nonetheless, the use of aqueous Zn-ion batteries is severely hindered by key issues such dendrite formation and side reactions in Zn metal anodes. It is able to works well so as to create a stable interface layer, which controls the development of ...
Yang, Chen +5 more
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Multifunctional Separator for Zn Metal Anode Protection
ECS Meeting AbstractsLithium-ion batteries (LIBs) have issues such as the high cost of raw materials due to the use of rare metals such as Li and Co in the electrode and the risk of fire due to the use of organic electrolytes.[1] Zn-ion batteries (ZIBs) based on aqueous electrolytes are inexpensive (~US$2 kg-1) and safe for practical use.[2] In addition, the high ...
Wei Yu +3 more
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Electrical‐Conductive/Insulating Bi‐Functional Layers for Stable Zn Metal Anode
Chemistry – A European Journal, 2022AbstractZinc‐ion batteries are regarded as an extremely promising candidate for large‐scale energy storage equipment due to the inexpensive ingredients and high safety. However, dendrite growth and side reactions occur in the Zn anode, which lead to exceedingly low coulombic efficiency (CE) and poor cycling stability.
Lang Wang +5 more
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ZnO Nanoparticle Assisted Liquid Metal for Dendrite‐Free Zn Metal Anodes
SmallAbstractDendrite growth and interfacial side reactions on Zn anode seriously affect the safety and service life of Zn ions batteries. Interface engineering is an effective way to solve these problems. Here, a liquid metal‐ZnO composite coating with high ionic conductivity is creatively designed, which not only reduces the Zn2+ diffusion barrier but ...
Li‐Jun Tang +6 more
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Efficient Zn Metal Anode Enabled by O,N-Codoped Carbon Microflowers
Nano Letters, 2022Zinc metal anodes show great promise for cheap and safe energy storage devices. However, it remains challenging to regulate highly efficient Zn plating/stripping under a high depth of discharge (DOD). Guided by density functional theory calculation, we here synthesized an oxygen- and nitrogen-codoped carbon superstructure as an efficient host for high ...
Zhixiao Xu +5 more
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Electrostatic Shielding Engineering for Stable Zn Metal Anodes
Advanced Energy MaterialsAbstractAqueous Zn‐ion batteries (AZIBs) are promising energy storage systems due to their low cost, excellent safety, and environmental friendliness. However, challenges like uncontrollable dendrite growth and side reactions during battery operation limit their commercialization.
Zhangxing He +12 more
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Tailoring the Electrode Interface Microenvironment to Stabilize Zn Metal Anode
SmallAbstractZn metal is the most attractive anode material for aqueous batteries, yet it encounters challenges from dendrites. Here, based on lanthanum trifluoromethanesulfonate (La(OTf)3)‐based electrolyte, the idea of tailoring the electrode interface microenvironment (ion concentration, solid electrolyte interphase (SEI) and electric field) is proposed ...
Weiping Hou +7 more
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Synergistic Anion–Cation Chemistry Enables Highly Stable Zn Metal Anodes
Journal of the American Chemical SocietyEngineering aqueous electrolytes with an ionic liquid (IL) for the zinc (Zn) metal anode has been reported to enhance the electrochemical performances of the Zn metal batteries (ZMBs). Despite these advancements, the effects of IL and the mechanisms involving their anions and cations have been scarcely investigated.
Yanqun Lv +14 more
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