Results 161 to 170 of about 3,662 (277)

Lewis‐Acid Engineering with Neodymium Promoters as Synergistic Nd‐Ni Dual Sites for Enhanced Urea Oxidation

open access: yesAdvanced Science, EarlyView.
The integration of rare‐metal neodymium centers to engineer Lewis acid sites with nickel centers is proposed as highly efficient UOR catalysts. ABSTRACT The sluggish kinetics of the urea oxidation reaction (UOR) are strongly associated with the high energy barriers required for the C‐N cleavage and N‐N coupling steps.
Mingfan Li   +8 more
wiley   +1 more source

Fully Textured Monolithic Sb2S3/Silicon Tandem for Unbiased and Stable Solar‐Driven Water Splitting Paired with Iodide Oxidation Reaction

open access: yesAdvanced Science, EarlyView.
Monolithically integrated Sb2S3 on industry‐compatible textured silicon for tandem photoelectrochemical hydrogen evolution coupled with iodide oxidation. ABSTRACT Solar‐driven photoelectrochemical (PEC) production of chemical fuels such as hydrogen is a viable solution to address climate neutrality objectives.
Jihong Min   +13 more
wiley   +1 more source

K+‐Triggered Defect Engineering and Proton‐Coupled Storage in V2O5·nH2O for Advanced Zn‐Ion Thin‐Film and Microbatteries

open access: yesAdvanced Science, EarlyView.
K+ pre‐intercalation in V2O5·nH2O induces interlayer contraction, oxygen‐vacancy formation, and mixed‐valence states, activating defect‐mediated proton‐dominated transport. This enables cooperative H+/Zn2+ storage with enhanced kinetics and stability. The resulting Zn‐based thin‐film and microbatteries deliver high areal energy and capacity, offering a
Jingli Luo   +14 more
wiley   +1 more source

Tailoring K+ Dosage in K+/Zn2+ Mixed Electrolytes via Lattice Expansion Regulation of Zinc Hexacyanoferrate for High‐performance Zinc Ion Batteries

open access: yesAdvanced Science, EarlyView.
The study proposes a fitting curve as a reference to quantify the optimal K+ ratio in K+/Zn2+ mixed electrolyte, thus achieving stable and high‐capacity aqueous zinc ion batteries at each current density. ABSTRACT Incorporating K+ into Zn‐based electrolytes can enhance the performance of aqueous zinc ion batteries, while the lack of a clear rule for ...
Yewei Li   +7 more
wiley   +1 more source

Beyond d‐Band Catalysis: A Critical Review and Descriptor Framework for Rare‐Earth Engineering in Lithium–Sulfur Batteries

open access: yesAdvanced Science, EarlyView.
Rare‐earth catalysts regulate lithium–sulfur battery chemistry through f‐orbital–mediated interactions, enabling simultaneous polysulfide adsorption and catalytic conversion on conductive carbon hosts. This synergistic control suppresses the shuttle effect, accelerates redox kinetics, and guides stable Li2S nucleation, providing a mechanistic framework
Fan Wang   +5 more
wiley   +1 more source

Operando Raman Spectroscopy Reveals Backpressure‐Controlled Dynamics in Diluted CO2 Electrolysis

open access: yesAdvanced Science, EarlyView.
High backpressure operation governs the CO2 reduction reaction (eCO2RR) kinetics and selectivity, as well as the CO2 and water dynamics, as revealed through operando Raman spectroelectrochemical measurement. Operating eCO2RR near diffusion‐limited conditions provides a platform for investigating the competition between eCO2RR and the hydrogen evolution
Muhammad Adib Abdillah Mahbub   +7 more
wiley   +1 more source

Highly Reversible Zinc Anode Enabled by a Thiourea‐Derived Protective Layer for Alkaline Zinc Batteries

open access: yesAdvanced Science, EarlyView.
A ZnS/carbon nitride (ZnS/CN) protective coating is constructed on Zn anodes via ultrasonic spray coating, enabling uniform and stable Zn stripping/plating, suppressing dendrite formation, and mitigating parasitic side reactions, resulting in a prolonged cycling lifespan and high reversibility of the Zn anode in alkaline Zn–air batteries. ABSTRACT Zinc‐
Noam Navon   +7 more
wiley   +1 more source

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