Results 31 to 40 of about 2,339 (147)

Patenting activity in manufacturing organoclays for nanocomposite applications [PDF]

open access: yes, 2009
peer reviewedFor the last two decades, intensive research has been focused on developing reinforced polymers with incorporation of nanometric fillers. Amongst the different types of nanofillers, those based on layered silicates (commonly known as clays),
Alexandre, Michaël   +3 more
core   +1 more source

One-pot oximation–Beckmann rearrangement of ketones and aldehydes to amides of industrial interest: Acetanilide, caprolactam and acetaminophen [PDF]

open access: yes, 1924
High yielding one-pot oximation–Beckmann rearrangement of ketones to amides in ktrifluoroacetic acid has been conducted on several ketones and aldehydes. The substrate reactivity showed to depend on both oximation and Beckmann rearrangement reaction rate.
Arico', Fabio   +5 more
core   +2 more sources

Selective, Oxygen‐Tunable, and Metal‐Free Functionalization of Polyethylene Through Dual‐Mode Nitrosation and Carbonylation

open access: yesAngewandte Chemie, Volume 138, Issue 2, 9 January 2026.
A metal‐free nitrosation process enables direct C–H functionalization of polyethylene (PE) with high selectivity, producing either oxime‐ or carbonyl‐functionalized polymers. Using t‐BuONO under visible light or thermal conditions, the process operates in both lab‐scale and industrial settings.
Lucile Cluzeau   +4 more
wiley   +2 more sources

N,N'-(Hexane-1,6-diyl)bis(4-methyl-N-(oxiran-2-ylmethyl)benzenesulfonamide): Synthesis via cyclodextrin mediated N-alkylation in aqueous solution and further Prilezhaev epoxidation

open access: yesBeilstein Journal of Organic Chemistry, 2013
N-alkylation of N,N'-(hexane-1,6-diyl)bis(4-methylbenzenesulfonamide) with allyl bromide and subsequent Prilezhaev reaction with m-chloroperbenzoic acid to give N,N'-(hexane-1,6-diyl)bis(4-methyl-N-(oxiran-2-ylmethyl)benzenesulfonamide) is described ...
Julian Fischer   +2 more
doaj   +1 more source

Estimativa da incerteza de medição: estudo de caso no ensaio de migração de ε-caprolactama com determinação por CG-DIC

open access: yesQuímica Nova, 2012
The estimation of measurement uncertainty of an analytical result is an important tool to be applied for compliance to ISO IEC 17025. Through the available guides it is possible to establish procedures and criteria for the estimation of measurement ...
Fabio Silvestre Bazilio   +3 more
doaj   +1 more source

Synthesis and Thermal Properties of Curing Materials by Thermosetting Epoxy Resins with ε-Caprolactam [PDF]

open access: yes, 2017
ε-カプロラクタム(CL)と様々なタイプのエポキシ樹脂類、ビフェニル型(YX-4000、NC-3000)、ノボラック樹脂型(N500P-1、EPPN-502H)、グリシジルアミン型(EP630)との熱硬化反応を検討した。仕込み比、CL/エポキシ樹脂類 = 10/2~10/20の範囲で、ジアザビシクロウンデセン(DBU)存在下、80~170℃、2時間の範囲で加熱したところ、EPPN-502H以外のすべてのエポキシ樹脂類において、対応する架橋硬化物が定量的に得られた。さらに得られた硬化物のガラス転移温度 ...
Buya Kentaro   +3 more
core   +2 more sources

Chemoselective hydrogenation of arenes by PVP supported Rh nanoparticles [PDF]

open access: yes, 2016
Polyvinylpyrrolidone-stabilized Rh nanoparticles (RhNPs/PVP) of ca. 2.2 nm in size were prepared by the hydrogenation of the organometallic complex [Rh(η3-C3H5)3] in the presence of PVP and evaluated as a catalyst in the hydrogenation of a series of ...
Garcia-Suarez, Eduardo J.   +4 more
core   +3 more sources

Moisture adsorption and desorption behavior of raw materials for the t-rtm process [PDF]

open access: yes, 2021
The use of fiber reinforced plastics (FRPs) has significant potential to reduce the weight of components. As regards the sustainability of these components, thermoplastic matrices offer more potential for recycling than thermoset ones.
Henning, Frank   +5 more
core   +2 more sources

Harmonisation framework for health based evaluation of indoor emissions from construction products in the European Union using the EU-LCI concept [PDF]

open access: yes, 2013
This report describes a harmonised procedure for establishing a list of compounds and their associated LCI (Lowest Concentration of Interest) values for the evaluation of emissions from construction products taking into account existing procedures used ...
ANNYS Erwin   +23 more
core   +1 more source

Applying additive-modifiers in dewaxing raffinate process [PDF]

open access: yes, 2016
Dewaxing petroleum oil raffinates is carried out by low-temperature rectification in sovents acetone – toluene. To intensify the process as an additive-modifier we used ε -caprolactam.
Al-Razuki, A. A.   +3 more
core  

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