Results 21 to 30 of about 833,376 (282)

Unexpected Charge Effects Strengthen π–Stacking Pancake Bonding [PDF]

open access: yesJACS Au, 2021
Zhong-hua Cui   +3 more
doaj   +2 more sources

Ordered π-conjugated polymer backbone in amorphous blend for high efficiency nonfullerene organic photovoltaics

open access: yesCommunications Materials, 2023
In π-conjugated polymers, the amorphous region absent from π–π stacking order typically limits polymer functions compared to the crystalline region with high π–π stacking order.
Masahiko Saito   +8 more
doaj   +1 more source

Enhanced π-π Stacking between Dipole-Bearing Single Molecules Revealed by Conductance Measurement.

open access: yesJournal of the American Chemical Society, 2023
Dipoles are widely involved in π-π interactions and are central to many chemical and biological functions, but their influence on the strength of π-π interactions remains unclear.
Chengyang Zhang   +9 more
semanticscholar   +1 more source

Complementary, Cooperative Ditopic Halogen Bonding and Electron Donor-Acceptor π-π Complexation in the Formation of Cocrystals

open access: yesMolecules, 2022
This study expands and combines concepts from two of our earlier studies. One study reported the complementary halogen bonding and π-π charge transfer complexation observed between isomeric electron rich 4-N,N-dimethylaminophenylethynylpyridines and the ...
Erin D. Speetzen   +3 more
doaj   +1 more source

Differences in thermal expansion and motion ability for herringbone and face-to-face π-stacked solids

open access: yesIUCrJ, 2022
A series of aromatic organic molecules functionalized with different halogen atoms (I/ Br), motion-capable groups (olefin, azo or imine) and molecular length were designed and synthesized.
Xiaodan Ding   +3 more
doaj   +1 more source

Synthesis, Structure, and Photophysical Properties of Yellow-Green and Blue Photoluminescent Dinuclear and Octanuclear Copper(I) Iodide Complexes with a Disilanylene-Bridged Bispyridine Ligand

open access: yesMolecules, 2021
The synthesis, structural, and photophysical investigations of CuI complexes with a disilanylene-bridged bispyridine ligand 1 are herein presented. Dinuclear (2) and ladder-like (3) octanuclear copper(I) complexes were straightforwardly prepared by ...
Toyotaka Nakae   +4 more
doaj   +1 more source

The Grapefruit Effect: Interaction between Cytochrome P450 and Coumarin Food Components, Bergamottin, Fraxidin and Osthole. X-ray Crystal Structure and DFT Studies

open access: yesMolecules, 2020
Coumarins are plant-derived secondary metabolites. The crystal structure of three coumarins—bergamottin, osthole and fraxidin—are described and we analyze intermolecular interactions and their role in crystal formation.
Miriam Rossi   +7 more
doaj   +1 more source

Strength of π-Stacking, from Neutral to Cation: Precision Measurement of Binding Energies in an Isolated π-Stacked Dimer [PDF]

open access: yes, 2018
π-Stacking interactions are ubiquitious across chemistry and biochemistry, impacting areas from organic materials and photovoltaics to biochemistry and DNA.
Cai, Jin-Zhe   +5 more
core   +4 more sources

Conformational modulation of sequence recognition in synthetic macromolecules [PDF]

open access: yes, 2011
The different triplet sequences in high molecular weight aromatic copolyimides comprising pyromellitimide units ("I") flanked by either ether-ketone ("K") or ether-sulfone residues ("S") show different binding strengths for pyrene-based tweezer-molecules.
Cardin, Christine   +6 more
core   +1 more source

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