本发明是一种催化湿式氧化处理高含酚废水的方法。催化剂以Pt、Pd、Rh、Ru中的一种及几种为活性组分,以La、Ce、Pr、Nd中的一种及几种为辅助组分,每一种元素的占催化剂总重量的0.2~4%;担载于TiO2~ZrO2载体;在60~180℃下,烘干2~18小时后,再在300~800℃下,进行焙烧2~18小时;应用条件为:反应温度:220-280℃,压力:4.0~8.0MPa,气/水(体):50~300,空速:0.5~6.0小时-1。本发明提高了反应效率,COD去除率达99%,BOD5/CODcr由0 ...
张晶晶 +5 more
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