Results 41 to 50 of about 564,955 (175)

A Dual Co‐Reactant Accelerator Based On Nanoreactor‐Encapsulated CeO2 Nanozymes to Drive Potentiated Luminol Cathodic Electrochemiluminescence for Ultrasensitive Immunoassay

open access: yesRare Metals, Volume 45, Issue 5, May 2026.
ABSTRACT The precise quantification of cytokines is crucial for monitoring disease onset and progression. Herein, we developed a synergistic signal amplification approach by utilizing nanoreactor‐encapsulated CeO2 nanozymes, which were in situ electrodeposited within the mesoporous silica nanochannel film (SNF) grown on indium tin oxide (ITO ...
Yu Cui   +4 more
wiley   +1 more source

Synergistic Activation of the Inert (001) Facet in Janus ZnIn2S4 Through Co 3d and P 3p Orbital Hybridization for Superior Photocatalytic Hydrogen Evolution

open access: yesRare Metals, Volume 45, Issue 5, May 2026.
ABSTRACT The Janus structure of ZnIn2S4 (ZIS) endows it with an intrinsic built‐in electric field that effectively drives photogenerated charge separation. However, this very structure also renders the predominant (001) facet (In–S termination) catalytically inert due to its low electron density and high energy barrier for the hydrogen evolution ...
Qingao Zhou   +8 more
wiley   +1 more source

基于铁盐催化的固态硼氢化钠制氢研究

open access: yes, 2012
以非贵金属铁盐为催化剂,考察不同浓度的Fe_2(SO_4)_3溶液、初始反应温度和不同进液速率下的固态NaBH4水解产氢性能。实验表明:相同浓度下,Fe_2(SO_4)_3的催化产氢性能高于Fe(NO_3)_2和FeC1_3。在Fe_2(SO_4)_3溶液浓度为1.5mol/L时产氢速率出现最大值,提高Fe_2(SO_4)_3浓度,可提高平均产氢速率;在20~48℃范围内,随反应温度的升高,产氢转化率略有上升,最终均能达到90 ...
郭常青, 方朝君, 闫常峰
core   +1 more source

Oxygen‐Vacancy‐Engineered Ni‐Fe Layered Double Hydroxides Enables Ultralow‐Overpotential Hydrogen Evolution Reaction and Durable Overall Water Splitting

open access: yesRare Metals, Volume 45, Issue 5, May 2026.
ABSTRACT Layered double hydroxides (LDHs) are attractive non‐noble catalysts for overall water splitting (OWS), yet their hydrogen evolution reaction (HER) activity is often limited by suboptimal *H adsorption and a paucity of accessible sites. Herein, we introduce an oxygen‐vacancy (Ov) engineering strategy to construct ultrathin Ni‐Fe LDH nanosheets ...
Qi Liu   +8 more
wiley   +1 more source

Dual‐Engineered Electrocatalyst: Work‐Function‐Driven Electronic Reconfiguration and Self‐Sacrifice Nanorod‐Templated Nanoflowers of Ni3S2/MoS2 Heterojunctions for High‐Performance Hydrogen Evolution

open access: yesRare Metals, Volume 45, Issue 5, May 2026.
ABSTRACT Water electrolysis is a promising method for green hydrogen production, but slow hydrogen evolution reaction (HER) kinetics require efficient catalysts. In this study, we develop a Ni3S2/MoS2 heterostructure electrocatalyst using a work‐function‐driven electronic modulation strategy combined with a self‐sacrificial template approach.
Xinxin Zhao   +11 more
wiley   +1 more source

高性能氢气传感器的研制

open access: yes, 2011
高性能氢气传感器的研制待填
关亚风
core  

Elastic Framework Driven Mg2+ Autocapture and Autocatalysis: Mechanistic Origin of Fast Hydrogen Release in 2LiBH4–MgH2

open access: yesRare Metals, Volume 45, Issue 5, May 2026.
ABSTRACT The protracted incubation time has long been the Achilles' heel of the promising 2LiBH4–MgH2 hydrogen storage system. Instead of the usual route‐creating heterogeneous nucleation sites to hasten MgB2 formation, we shortened both de‐ and re‐hydrogenation incubation periods by steering the Mg transformation itself.
Kai Jia   +6 more
wiley   +1 more source

高性能中空纤维氮氢膜分离器

open access: yes, 1993
高性能中空纤维氮氢膜分离器待填
待填写
core  

Electrospinning Synthesized Cd0.3Zn0.7S@PVDF/PAN Piezoelectric Nanofiber Membrane for Efficient Photocatalytic Hydrogen Evolution

open access: yesRare Metals, Volume 45, Issue 4, April 2026.
ABSTRACT Photocatalytic hydrogen evolution technology is a crucial approach to achieve efficient solar energy conversion and green hydrogen production. However, traditional semiconductor photocatalysts often face issues such as weak visible‐light response, high photogenerated charge carrier recombination, and poor structural stability, severely ...
Longtao Guo   +8 more
wiley   +1 more source

催化剂掺杂改进轻质高容量氢化物储氢性能的研究

open access: yes, 2014
本文首次利用K2TiF6对LiAlH4进行掺杂改性, 使其脱氢性能得到了较大的提高。1.5 mol% K2TiF6 掺杂的LiAlH4起始脱氢温度降低到了65 oC,在90 oC 恒温脱氢,60 min和300 min内分别脱氢4.4 wt%和6.0 wt%。 LiAlH4两步脱氢活化能分别降低 38 kJ/mol和42.2 kJ/mol。 利用球磨后的LiAlH4-K2TiF6 样品作为共掺杂物加入到MgH2中用以改进其储氢性能。掺杂制备的10MgH2+LiAlH4 ...
李志宝
core  

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