Results 21 to 30 of about 3,351 (147)
采用浸渍法、一般离子交换和络合离子交换制备Zn/HZSM-5催化剂,用于甲烷和丙烷混合气的无氧芳构化研究,其中络合离子交换法制备的催化剂活性最好.在反应温度823 K,空速600 h-1,甲烷/丙烷摩尔比为5:1的条件下,丙烷转化率和芳烃选择性分别达99.93%和80.29%.Zn/HZSM-5上经CH4-C3H8芳构化反应后,表面存在至少两种类型的积碳,分别对应于CHx活性中间体,类石墨碳或石墨碳,前者可用高温H2消除,后者要在O2气氛下才能被消除 ...
XUANDong(宣东) +3 more
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ABSTRACT Low conductivity, slow ion‐diffusion, and limited reactive sites are common problems in electrocatalysts and electrode materials. In this study, a complex NiTe–CoTe heterojunction with abundant Te vacancies embedded in N, P, and F co‐doped hollow carbon nanorods (NiTe1−x–CoTe1−x/NPFC) was fabricated via a simple ionic liquid‐assisted ...
Mingjie Yi +7 more
wiley +1 more source
ABSTRACT The development of high‐performance and stable electrocatalysts for oxygen reduction reaction (ORR), oxygen evolution reaction (OER), and hydrogen evolution reaction (HER) plays a critical role in advancing clean energy technologies, including metal‐air batteries and hydrogen production through overall water splitting.
Chen‐Yu Cai +4 more
wiley +1 more source
ABSTRACT Efficient and durable bifunctional electrocatalysts are vital for scalable water electrolysis. Here, we realize cobalt‐vacancy (Covac) engineering in CoFeP supported on N,P‐codoped carbon nanocages (Co1‐vacFeP/NPC) through a simple route comprising a CoFe Prussian blue analog precursor, phosphidation–pyrolysis, tannic‐acid etching, and a ...
Yuan‐Liang Yuan +6 more
wiley +1 more source
ABSTRACT The development of efficient and stable bifunctional catalysts remains a key challenge for green hydrogen production via electrochemical water splitting. In this study, a bimetallic Mo/Fe‐doped CoP2 nanoleaf array anchored on carbon cloth (Mo, Fe‐CoP2@CC) was synthesized from zeolitic imidazolate framework‐L (ZIF‐L) via an ion‐exchange and low‐
Xiangqun Zeng +6 more
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ABSTRACT Recently, cobalt/nitrogen co‐doped materials have emerged as heterogeneous catalysts to activate peroxymonosulfate (PMS) and have been applied to advanced oxidation processes for environmental remediation. However, their recyclability and reusability remain major barriers to practical application.
Wen‐Kai Zhu +11 more
wiley +1 more source
主要分析不同森林植被下有机碳的分解动态和土壤碳库各组分大小、周转时间。结果表明:土壤样品培养90天,CO2累计释放量表层大致为1723~5065mg/kg、下层大致为178~642mg/kg。分解速率总的趋势是前期快,后期慢,表层明显大于下层。大小顺序为:冷杉林〉针阔混交林和阔叶林〉针叶林。在不同植被下的表层和下层土壤中,活性碳占总有机碳的0.54%~1.67%,0.45%~5.48%.平均驻留时间为11~56天、60~88天;缓效性碳占总有机碳的23.0%~63.3%,33.2%~72.2 ...
邵月红 +3 more
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Plasma‐Boosted Bi2Mn4O10 Electrocatalysis Enables Real‐Time On‐Board Monitoring of CO2 in Exhaust
ABSTRACT Real‐time monitoring of CO2 concentration in automobile exhaust is critical for effective carbon emission reduction. However, the inherently inert nature of CO2 poses a significant challenge for achieving accurate and efficient detection in the exhaust automobile environment.
Aining Jiang +6 more
wiley +1 more source
ABSTRACT Biomass‐derived quinones are promising green and sustainable cathode materials for sodium‐ion batteries (SIBs), yet their practical application is hindered by poor cycling stability due to dissolution in conventional electrolytes. Herein, we demonstrate that sodiumation is an effective strategy to enhance both rate capability and cycling ...
Xinyue Zhu +4 more
wiley +1 more source
为了解土壤有机碳组分在植被恢复过程中的变化规律,选取了红壤区本底条件基本一致、不同恢复年限的马尾松林为研究对象,以未治理的侵蚀裸地(CK1)和恢复后的次生林(CK2)为对照,采用物理化学分组法,将土壤有机碳分为由溶解性有机碳(DOC)和颗粒有机碳(POM)组成的活性碳库、物理保护态的团聚体与粉粒和黏粒组合成的缓效性碳库以及化学结构稳定的惰性碳库。结果表明:在植被恢复过程中(0~30年)活性碳库储量及其分配比例在植被恢复7~10年显著提高(P<0.05),并在植被恢复27~30年保持较稳定水平 ...
邓 翠 +6 more
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