Results 21 to 30 of about 361,068 (169)
ABSTRACT Efficient catalytic materials are vital for addressing the polysulfide shuttle and sluggish redox kinetics in lithium–sulfur batteries. Herein, we report a facile sugar‐blowing method to prepare porous carbon‐supported FeCoNiCuPt high‐entropy alloy (HEA) nanospheres with abundant lattice defects in a single crystalline phase.
Guixiang Zhong +8 more
wiley +1 more source
ABSTRACT The Janus structure of ZnIn2S4 (ZIS) endows it with an intrinsic built‐in electric field that effectively drives photogenerated charge separation. However, this very structure also renders the predominant (001) facet (In–S termination) catalytically inert due to its low electron density and high energy barrier for the hydrogen evolution ...
Qingao Zhou +8 more
wiley +1 more source
ABSTRACT Layered double hydroxides (LDHs) are attractive non‐noble catalysts for overall water splitting (OWS), yet their hydrogen evolution reaction (HER) activity is often limited by suboptimal *H adsorption and a paucity of accessible sites. Herein, we introduce an oxygen‐vacancy (Ov) engineering strategy to construct ultrathin Ni‐Fe LDH nanosheets ...
Qi Liu +8 more
wiley +1 more source
以光核桃核壳为原料,采用氯化锌化学活化法制备了活性炭(ZCAC)。利用SEM、FT-IR、氮气吸附-脱附、Zeta电位等对制备的ZCAC进行了表征,并考察了其对水中Cr(Ⅵ)的吸附效果及吸附机理。结果表明,制备的ZCAC的比表面积为1 460.0 m2/g,总孔容为0.733 cm3/g,平均孔径为2.59 nm,等电点为4.4。ZCAC对Cr(Ⅵ)的最大吸附量为128.65 mg/g,其对Cr(Ⅵ)的吸附为单层、化学、吸热、自发的反应。
阚金涛 +5 more
doaj
研究了咪唑啉胍盐在盐酸介质中对不锈钢的缓蚀性能,并探讨其吸附行为。结果表明,咪唑啉胍盐具有良好的缓蚀性能,缓蚀率随着缓蚀剂浓度的增加而增大。电化学实验结果表明,咪唑啉胍盐是混合型缓蚀剂,等效电路中存在电容和电感。咪唑啉胍盐在不锈钢表面的吸附符合Langmuir吸附等温方程,既包含了物理吸附又包含化学吸附。
张惠欣 +4 more
doaj
用水热法制得磁性复合材料用于对二甲基胂酸的吸附研究。首先通过XRD、BET、VSM和SEM对合成材料进行分析;考察投加量、pH等因素对磁性复合材料吸附二甲基胂酸效果的影响,并结合吸附等温线和吸附动力学研究其吸附性能和吸附机理;通过FT-IR和Zeta电位探讨了磁性材料吸附二甲基胂酸的机理。XRD分析表明磁性复合材料纯度高、晶型好;SEM图显示磁铁矿为单分散球团附着在膨润土和硅藻土表面,孔隙结构丰富;磁性硅藻土和磁性膨润土比表面积分别48.63、65.17 m2/g ...
马晓燕 +5 more
doaj
ABSTRACT Aqueous zinc‐ion batteries are plagued by anode challenges such as dendrite growth and corrosion, which stem from intrinsic surface heterogeneity. Although constructing a homogeneous interfacial layer is a promising strategy, conventional electrolyte additives often suffer from incomplete or unstable coverage.
Ke Huang +6 more
wiley +1 more source
以带结构正电荷的镁铝层状双金属氢氧化物(Mg-Al-LDH)溶胶为吸附剂系统研究了不同因素对磷吸附去除性能的影响,结果表明:其吸附动力学和吸附等温线分别符合准二级、Elovich速率方程和Langmuir方程,理论饱和吸附量可达55.99~60.90 mg/g。吸附过程的ΔG0为-28.78~-20.67 kJ/mol,吸附机理以静电吸引和化学吸附为主导。无机和有机阴离子会抑制磷在吸附剂上的吸附。200 mg/L的Mg-Al-LDH可以吸附90%以上的溶解性反应磷和84%的总磷 ...
谢发之 +5 more
doaj
ABSTRACT Environmental pollution across water, air, and soil systems poses escalating threats to human health and ecosystem stability, driven by heavy metals, persistent organic pollutants, particulate matter (PM), bioaerosols, and toxic gases. Conventional remediation technologies often suffer from limited selectivity, insufficient efficiency, and the
Junjie Qi +6 more
wiley +1 more source
ABSTRACT Water electrolysis is a promising method for green hydrogen production, but slow hydrogen evolution reaction (HER) kinetics require efficient catalysts. In this study, we develop a Ni3S2/MoS2 heterostructure electrocatalyst using a work‐function‐driven electronic modulation strategy combined with a self‐sacrificial template approach.
Xinxin Zhao +11 more
wiley +1 more source

