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导电聚合物改性金属氧化物光催化剂的研究进展

open access: yesGongye shui chuli, 2023
光催化技术降解污染物在环境修复和催化领域具有显著优势,针对传统金属氧化物存在禁带宽度大和电子-空穴对复合率高等缺点,导电聚合物改性成为提高金属氧化物光催化活性的一种有效方式。在导电聚合物/金属氧化物光催化剂的分类、制备方法和表征方式等基础上,综述了导电聚合物/金属氧化物的光催化机理及应用。导电聚合物/金属氧化物光催化活性的增强机制为导电聚合物的光敏化作用、导电聚合物和金属氧化物的协同作用。最后,阐明了导电聚合物/金属氧化物光催化剂研究面临的挑战,包括金属氧化物的能带调控、导电聚合物 ...
杨传玺   +8 more
doaj  

电化学氧化-电渗析联合处理丙烯腈四效蒸发凝液

open access: yesGongye shui chuli, 2022
采用“电化学氧化-电渗析”联合处理丙烯腈四效蒸发凝液,既解决了电化学氧化出水盐含量高,不利于后续生化处理的难题,又节约了运行成本。结果表明,三维电化学氧化效果明显优于二维电化学氧化,多种有机污染物被大幅去除,三维电化学氧化出水中总氮(TN)和总有机碳(TOC)质量浓度分别降至125.8、335.2 mg/L,比二维电化学氧化分别降低了18.36%、26.31%,运行能耗也降低了14.4%;采用电渗析处理氧化出水,脱盐率接近100%,且浓水回用对污染物的去除率影响较小,最终出水B/C提升至0.43 ...
王文虎, 赵姗姗, 王伟, 阎光绪
doaj  

掺杂氧化锑对氧化锌电阻片性能的影响

open access: yesDianci bileiqi, 2020
通过改变氧化锑的含量,分析不同含量对氧化锌电阻片电位梯度、泄漏电流等性能的影响。氧化锑在烧结过程中与氧化锌可以形成尖晶石相,可以抑制氧化锌晶粒尺寸的大小,进而调整电阻片电位梯度。在传统五元配方体系中,通过改变氧化锑的增加,电阻片收缩率逐渐增大,致密度逐渐增加;掺杂适量的氧化锑可以提高电位梯度,降低泄漏电流;掺杂过量的氧化锑会降低电位梯度。
刘亚芸, 厍海波, 杨军, 刘明新
doaj  

Synergistic Enhancement of Toluene Catalytic Oxidation via Pt‐Induced Oxygen Vacancies and Heterojunction Built‐In Electric Field

open access: yesRare Metals, Volume 45, Issue 6, June 2026.
ABSTRACT Improving catalytic activity for volatile organic compounds (VOCs) oxidation and enhancing water‐tolerance stability remain challenging in practical applications. Herein, a composite catalyst integrating Pt/CoOx‐NiOx mesoporous nanorods (MNRs) with a phenyltriethoxysilane (PhTES)‐modified surface was fabricated via a facile route for toluene ...
Jiaqin He   +13 more
wiley   +1 more source

Atomically Thin Sn:GaN‐GaN Homojunction for High‐Sensitivity β‐Ray Detection

open access: yesRare Metals, Volume 45, Issue 6, June 2026.
ABSTRACT Gallium nitride (GaN), a third‐generation wide‐bandgap semiconductor renowned for its superior radiation tolerance, holds promise for advanced β‐ray detection. Herein, a scalable liquid metal‐assisted in situ synthesis method is presented to fabricate Sn‐doped GaN homojunctions via gallium oxide printing followed by ammonolysis, enabling ...
Weiqing Liu   +8 more
wiley   +1 more source

Oxygen Doping and Crystal–Amorphous Multiphase Coupling Synergistically Improve the Wear Resistance of NiTiCu Alloy

open access: yesRare Metals, Volume 45, Issue 6, June 2026.
ABSTRACT NiTi shape memory alloys (SMAs) show excellent performance in vibration damping and corrosion resistance. However, due to low hardness and lack of self‐lubrication, they suffer severe friction and wear during service. Although various strategies including doping and heterostructure design have been proposed, the effects are unsatisfactory.
Huwen Ma   +13 more
wiley   +1 more source

Advances in BiOCl‐Based Photocatalysts: From Synthesis, Structural Tailoring to Solar Energy Conversion

open access: yesRare Metals, Volume 45, Issue 6, June 2026.
ABSTRACT Semiconductor photocatalysis represents a pivotal frontier in the quest for sustainable energy and environmental remediation. Among the diverse catalytic materials, Bismuth Oxychloride (BiOCl) has emerged as a particularly promising candidate due to its unique layered structure, featuring [Bi2O2]2+ layers intertwined with halogen ions, which ...
Liu Han   +5 more
wiley   +1 more source

Emerging MBenes for Energy Technologies

open access: yesRare Metals, Volume 45, Issue 6, June 2026.
ABSTRACT The escalating global demand for sustainable energy is driving the search for transformative materials that transcend the limitations of conventional systems. Two‐dimensional (2D) transition metal borides (MBenes) have recently emerged as a compelling class, distinguished by unique electronic structures, tunable surface chemistry, and ...
Yingrui Ding   +5 more
wiley   +1 more source

联合电催化氧化处理难降解有机废水研究进展

open access: yesGongye shui chuli, 2009
介绍了难降解有机废水的各种联合电催化氧化处理技术,主要包括:光电催化氧化技术、超声-电催化氧化技术、臭氧电催化氧化技术、电催化-生物反应技术、膜过滤电催化氧化技术。讨论了联合电催化氧化技术各自的特点、优势与不足。分析表明,联合电催化氧化技术在废水处理上具有协同作用。通过电催化材料和工艺技术的研究,有可能实现电催化氧化技术的产业化。
张腾云, 范洪波, 廖世军
doaj  

Pre‐Established Zincophilic Na2SiO3 Decorated Array‐Like Channels to Regulate the Zn2+ Flux and Interfacial Corrosion for Dendrite‐Free Zinc Anode

open access: yesRare Metals, Volume 45, Issue 6, June 2026.
ABSTRACT Aqueous zinc‐ion batteries (AZIBs) have attracted increasing attention in energy storage owing to their high energy density, low redox potential, and cost‐effectiveness. Nevertheless, uncontrolled dendrite accumulation, gas generation, and severe side‐reaction problems hinder the cycling lifespan, which prevents their commercial applications ...
Xiangzhong Kong   +8 more
wiley   +1 more source

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