近年来,我国多台采用表面式换热器铝制散热器(SCAL)型间冷系统的火电机组出现铝制散热器腐蚀泄漏问题。通过对十余台同类型机组的实地调研与系统分析,揭示了纯铝材料的腐蚀机理:Cl-会破坏纯铝表面的钝化膜保护层,并与铝腐蚀产物Al(OH)3发生次生反应生成OH-,导致间冷循环水pH异常升高,而这种碱性环境又会加速钝化膜的溶解进程,从而进一步加剧铝基体的腐蚀。同时,SO42-会加速碳钢的腐蚀并生成腐蚀产物Fe3O4,纯铝表面的钝化膜在碱性环境中大面积溶解后 ...
郝洪铎 +4 more
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Antibacterial property, corrosion and discoloration resistance of pure copper containing Zn or Ni. [PDF]
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