Node Modification of Metal‐Organic Frameworks for Catalytic Applications
Post‐synthetic modification of metal‐organic framework (MOF) nodes with metal or organic species produces advanced materials that serve as efficient catalysts, promoting more sustainable chemical transformations. Abstract Metal‐organic frameworks (MOFs) have been a breakthrough in different fields of chemistry, not only due to the extensive ...
Mario Martos, Isidro M. Pastor
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The molybdenum(0)-carbonyl-triazole complexes [Mo(CO)3(L)3] [L = 1,2,3-triazole (1,2,3-trz) or 1,2,4-triazole (1,2,4-trz)] have been prepared and examined as precursors to molybdenum(VI) oxide catalysts for the epoxidation of cis-cyclooctene. Reaction of
Lucie S. Nogueira+7 more
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Recent advances in the synthesis of triazole derivatives [PDF]
Triazole ring system has attracted a continuously growing interest of synthetic organic chemists and those dealing with the medicinal compounds due to its versatile potential to interact with biological systems.
Ahmad, Matloob+6 more
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3-Pyridin-2-yl-1H-1,2,4-triazol-5-amine [PDF]
In the title compound, C7H7N5, the non-H atoms are almost coplanar (r.m.s. deviation = 0.050 Å), with the N atom of pyridine ring oriented to the N—N(H) side of the 1,2,4-triazole ring.
Anna V. Dolzhenko+11 more
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A field‐induced slow magnetic relaxation was observed in an ionic pentacoordinated Cu(II) complex with 4‐amino‐3,5‐di‐2‐pyridyl‐4H‐1,2,4‐triazole and azido ligands. The analysis of the relaxation behaviour supports the origin of the slow magnetic relaxation in intramolecular low‐energy vibration modes participating in the one‐phonon direct and two ...
Svitlana Vitushkina+5 more
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5-[(E)-Methoxy(phenyl)methylidene]-1,3,4-triphenyl-4,5-dihydro-1H-1,2,4-triazole
In the title compound, C28H23N3O, the 1,2,4-triazole ring deviates slightly from planarity adopting a N3TC2 conformation which is distorted towards an EC2 conformation. The plane around the ethylene unit makes a dihedral angle of 17.32 (11)&
Biplab Maji+3 more
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The Synthesis of Fully Boe-Protected Insulin Derivatives by Use of Boc-Azide - 1,1,3,3-Tetramethylguanidine - 1,2,4-Triazole as an Effective Acylating System. - A Simple and Sensitive Fluorescence Test for Determining the Degree of N-Substitution [PDF]
Acylation of desoctapeptide-(1323-3°) -insulin pentamethyl ester (II), insulin arid insulin \u27hexamethyl ester was carried out with Boc-azide in dimethylformamide in the presence of 1,1,3,3-tetramethylguanidine as a base and 1,2,4-triazole as an ...
B. Ladešić+5 more
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Synthesis and structural characterization of a disulphide-bridged tetranuclear palladium(II) complex derived from 3,5-diacetyl 1,2,4-triazole bis(4-ethylthiosemicarbazone) [PDF]
NOTICE: this is the author’s version of a work that was accepted for publication in Inorganic Chemistry Communications. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality ...
Matesanz, Ana I.+2 more
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The tomato transcription factor SlMYB78 controls a key metabolic gene cluster including ENHANCED PSEUDOMONAS SUSCEPTIBILTY 1, encoding a key enzyme that produces disease‐fighting compounds (phenolamides) and immune signals (salicylic acid). During domestication, tomatoes lost a superior variant (SlEPS1HapB), weakening disease resistance; restoring this
Peng Cao+14 more
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Synthesis and physicochemical properties 4-((R))amino)-5-methyl-4H-1,2,4-triazole-3-thiols
Purposeful synthesis of derivatives of 1,2,4-triazole is one of the most important branches of modern pharmaceutical science Modern pharmaceutical market of domestic medicines requires constant updates of existing range.
T. V. Kravchenko+2 more
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