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Substituted 1,3,5-Triazine Hexacarboxylates as Potential Linkers for MOFs. [PDF]
Molecules, 2019 Klinkebiel A, Beyer O, Lüning U.
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Journal of Heterocyclic Chemistry, 1987
AbstractA convenient route is reported for the synthesis of substituted 1,3,4‐thiadiazolo[3,2‐a]‐1,3,5‐triazine‐5,7‐diones and isoxazolo[2,3‐a]‐1,3,5‐triazines. Condensation of the appropriately substituted 2‐amino‐1,3,4‐thiadiazole and 3‐aminoisoxazole with phenoxycarbonyl isocyanate provides the desired target compounds in fair yield.
Mohamed M. El‐Kerdawy +3 more
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AbstractA convenient route is reported for the synthesis of substituted 1,3,4‐thiadiazolo[3,2‐a]‐1,3,5‐triazine‐5,7‐diones and isoxazolo[2,3‐a]‐1,3,5‐triazines. Condensation of the appropriately substituted 2‐amino‐1,3,4‐thiadiazole and 3‐aminoisoxazole with phenoxycarbonyl isocyanate provides the desired target compounds in fair yield.
Mohamed M. El‐Kerdawy +3 more
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2008
[290-87-9] C3H3N3 (MW 81.09) InChI = 1S/C3H3N3/c1-4-2-6-3-5-1/h1-3H InChIKey = JIHQDMXYYFUGFV-UHFFFAOYSA-N (C1 electrophile; formylating agent;2 methylenating and aminomethylenating agent;3 in combination with cyclic amines, dehydro-Mannich bases4, 5 are formed) Alternate Name: s-triazine. Physical Data: mp 80–82 °
GIACOMELLI, G, PORCHEDDU, ANDREA, A.
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[290-87-9] C3H3N3 (MW 81.09) InChI = 1S/C3H3N3/c1-4-2-6-3-5-1/h1-3H InChIKey = JIHQDMXYYFUGFV-UHFFFAOYSA-N (C1 electrophile; formylating agent;2 methylenating and aminomethylenating agent;3 in combination with cyclic amines, dehydro-Mannich bases4, 5 are formed) Alternate Name: s-triazine. Physical Data: mp 80–82 °
GIACOMELLI, G, PORCHEDDU, ANDREA, A.
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ChemInform, 1987
AbstractThe 2‐aminothiadiazoles (I) are coupled with cyanamide to give the guanidines (II).
M. M. EL‐KERDAWY +3 more
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AbstractThe 2‐aminothiadiazoles (I) are coupled with cyanamide to give the guanidines (II).
M. M. EL‐KERDAWY +3 more
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1,3,5-Triazines. Part X. Complexes of 2,4,6-trisdimethylamino-1,3,5-triazine
J. Chem. Soc. A, 1969Exocyclic dimethylamino-groups produce a drift of electrons towards the 1,3,5-triazing ring. 2,4,6-Trisdimethylamino-1,3,5-triazine behaves as an electron-donor towards protons, boron trifluoride, and aromatic π-electron-acceptors. A range of complexes of trisdimethylaminotriazine has been characterised.
S. K. Das +3 more
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Journal of Heterocyclic Chemistry, 1976
AbstractThe synthesis of variously substituted bis‐triazinylhydrazines and their subsequent oxidation preferably with chlorine in a two‐phase system to azo‐1,3,5‐triazines starting from cyanuric chloride is reported. Reaction of ethoxycarbonylhydrazine with cyanuric chloride followed by oxidation gave access to mono‐ and bis‐ethoxycarbonyl‐1,3,5 ...
P. Loew, C. D. Weis
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AbstractThe synthesis of variously substituted bis‐triazinylhydrazines and their subsequent oxidation preferably with chlorine in a two‐phase system to azo‐1,3,5‐triazines starting from cyanuric chloride is reported. Reaction of ethoxycarbonylhydrazine with cyanuric chloride followed by oxidation gave access to mono‐ and bis‐ethoxycarbonyl‐1,3,5 ...
P. Loew, C. D. Weis
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Tetrahedron, 2013
Abstract An efficient and practical procedure was developed to prepare novel imidazo[1,2-a][1,3,5]triazines and 3,4-dihydroimidazo[1,2-a][1,3,5]triazines with a good regioselectivity and high yields, starting from dicyandiamide and the corresponding arylamines. Mechanistic studies for the subsequent cyclocondensation with chloroacetaldehyde support a
Pascal Dao +2 more
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Abstract An efficient and practical procedure was developed to prepare novel imidazo[1,2-a][1,3,5]triazines and 3,4-dihydroimidazo[1,2-a][1,3,5]triazines with a good regioselectivity and high yields, starting from dicyandiamide and the corresponding arylamines. Mechanistic studies for the subsequent cyclocondensation with chloroacetaldehyde support a
Pascal Dao +2 more
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Derivatives of 2,4-dimethoxy-1,3,5-triazine
Acta Crystallographica Section C Crystal Structure Communications, 2003The crystal structure of three derivatives of 2,4-dimethoxy-1,3,5-triazine are described. In 4-(4,6-dimethoxy-1,3,5-triazin-2-yl)morpholine, C(9)H(14)N(4)O(3), the morpholine moiety adopts a chair conformation, and the dimethoxytriazine molecule adopts a butterfly conformation with respect to the two methoxy groups.
Natalya, Fridman +2 more
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Trisubstituted 1,3,5-Triazines. 6. Synthesis of 2,4,6-Tris(acetonyl)-1,3,5-triazine
Chemistry of Heterocyclic Compounds, 2003Acylation of 2,4,6-tris(tert-butoxycarbonylmethyl)-1,3,5-triazine with acetic anhydride in the presence of lithium hydride with subsequent removal of the tert-butoxycarbonyl groups with trifluoroacetic acid leads to 2,4,6-tris(acetonyl)-1,3,5-triazine, the cyclic analog of α-cyanoacetone.
A. V. Shastin +2 more
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Study on the 1,3,5-triazine gamma-radiolysis
Journal of Radioanalytical and Nuclear Chemistry, 2008Triazines are a class of molecules which have been found in meteorites such as Orgueil meteorite. Despite their poor resistance to UV radiation, these molecules survived millions of years inside a meteorite. The present work is dedicated to the examination of the radiation resistance of the simplest sym-triazine: 1,3,5-triazine.
Cataldo F, Ursini O, Angelini G
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