Solvent‐Free Thermal Defect Engineering in Molecular Frameworks With Volatile Linkers
Thermal removal of neutral volatile linkers enables precise and solvent‐free generation of metal vacancies in MOFs. This strategy affords redox‐stable, coordinatively unsaturated FeII sites with tunable spin, ligand coordination, and catalytic behavior. The approach offers a general route to design defect‐functional materials through local coordination
Sonia Martínez‐Giménez +9 more
wiley +1 more source
Metabolomic Analysis of Feces vs. Cecum Content in Animals: A Comparative Study Investigated by <sup>1</sup>H-NMR. [PDF]
Li X +6 more
europepmc +1 more source
A high‐capacity polyimide‐linked porous organic polymer (HAT‐PTO) incorporating numerous redox‐active centers is synthesized via a hydrothermal reaction, delivering a high theoretical capacity of 484 mAh g−1. In situ hybridization with carboxyl‐functionalized multiwalled carbon nanotubes enhances conductivity and stability, achieving 397 mAh g−1 at C ...
Arindam Mal +7 more
wiley +1 more source
Metabolomic response to acute resistance exercise in healthy older adults by 1H-NMR. [PDF]
Moosavi D +3 more
europepmc +1 more source
The Cu\u3csub\u3eA\u3c/sub\u3e Center of a Soluble Domain from \u3cem\u3eThermus\u3c/em\u3e cytochrome ba\u3csub\u3e3\u3c/sub\u3e. An NMR Investigation of the Paramagnetic Protein. A Proton NMR Study of the Paramagnetic Active Site of the Cu\u3csub\u3eA\u3c/sub\u3e Variant of Amicyanin [PDF]
Holz, Richard C.
core +1 more source
The new Cu‐containing MOF (Me2NH2)(CuICl2)@[Cu4(INA)4Cl2O]·1.5dmf (3) contains a cation and an anion as guests and shows UV‐near‐mid‐IR absorption and near‐IR emission. MOF 3 shows gas‐solid reactivity in the presence of NH3 and HCOOH to yield two new 3D MOF.
Rajat Saha +10 more
wiley +1 more source
Taurine as a Protective Metabolite in Radiation-Induced Liver Disease: Evidence from <sup>1</sup>H NMR Metabolomics. [PDF]
Chung YH +5 more
europepmc +1 more source
The transient interactions between TFSI− anions and a diluent within an anion‐dictated electrolyte are revealed, which can reduce interfacial reorganization energy, thereby accelerating ion kinetics and markedly facilitating sustainable anion storage in high‐voltage graphite cathodes for dual‐ion batteries at fast charge and wide temperature range ...
Sungho Kim +9 more
wiley +1 more source
Determination of the Preferred Stereoisomer of Natural Product Bisabolol in Chloroform Solution through Quantum Chemical Calculations of <sup>1</sup>H NMR Chemical Shifts. [PDF]
Da Silva HC +3 more
europepmc +1 more source
COFs on MOFs: Layer‐by‐Layer Synthesis of MOF@COF Nanoparticles with Synergistic Adsorption
A layer‐by‐layer strategy enables the growth of crystalline covalent organic framework (COF) shells on metal–organic framework nanoparticles, creating core–shell structures with tunable porosity. Ordered interstitial mesopores are formed during shell growth, which are connected with the COF's intrinsic micropores, thereby enhancing water sorption. This
Ana Guillem‐Navajas +11 more
wiley +1 more source

