Pt(IV), Au(III) and Pd(II) complexes of Schiff bases derived from 2-furaldehyde and 4-amino antipyrine (4APF) are reported and characterized based on elemental analyses, IR 1H-NMR, electronic spectra, molar conductance, and thermal analysis (TG/DTG). The
Foziah A. Al-Saif
doaj +1 more source
New series of Cu(II) and Mn(II) complexes with Schiff base ligands derived from 2-furylmethylketone (Met), 2-furaldehyde (Fur), and 2-hydroxyacetopheneone (Hyd) have been synthesized in situ on SBA-15-NH2, MCM-48-NH2, and MCM-41-NH2 functionalized ...
Mihaela Mureseanu +6 more
doaj +1 more source
Heteronuclear 3 d/DyIII coordination clusters as catalysts in a domino reaction [PDF]
Three isoskeletal tetranuclear coordination clusters with general formula [MII2DyIII2L4(EtOH)6](ClO4)2·2 EtOH, (M=Co, 1; M=Ni, 2) and [NiII2DyIII2L4Cl2(CH3CN)2]·2 CH3CN (3), have been synthesized and characterized.
Bhattacharya +21 more
core +1 more source
<em>tert</em>-Butyl 1-(Furan-2-yl)-4-oxo-2,3,7-triazaspiro[4.5]dec-1-ene-7-carboxylate
A simple and novel route for synthesis of new spirocyclic compound is developed. The present work involves condensation of ethyl nipecotate with 2-furaldehyde followed by the MnO<sub>2</sub> oxidation to give the <em>β</em>-keto ...
Balladka Kunhanna Sarojini +3 more
doaj +1 more source
Efficient NiII2LnIII2 electrocyclization catalysts for the synthesis of trans-4,5-diaminocyclopent-2-enones from 2-furaldehyde and primary or secondary amines [PDF]
A series of heterometallic coordination clusters (CCs) [NiII2LnIII2(L1)4Cl2(CH3CN)2] 2CH3CN [Ln = Y (1Y), Sm (1Sm), Eu (1Eu), Gd (1Gd), or Tb (1Tb)] were synthesized by the reaction of (E)-2-(2-hydroxy-3-methoxybenzylidene-amino)phenol) (H2L1) with NiCl2·
Alaa Abdul-Sada +12 more
core +1 more source
5-Hydroxymethylfurfural content in foodstuffs determined by micellar electrokinetic chromatography [PDF]
Micellar electrokinetic chromatography (MEKC) has been applied for the determination of 5-hydroxymethylfurfural in several foodstuffs. A 75 mM phosphate buffer solution at pH 8.0 containing 100 mM sodium dodecylsulfate was used as background electrolyte (
Galcerán Huguet, M. Teresa +3 more
core +1 more source
Through ligand length and π‐electron density modulation, metal–organic frameworks (MOFs) improve mass transport and hydrogen atom transfer (HAT), thus improving biomass electrooxidation. ABSTRACT Controlling reaction pathways in electrocatalytic biomass upgrading remains challenging because mass transport, substrate adsorption, and elementary kinetics ...
Junjie Chen +12 more
wiley +1 more source
Research Progress of Polyoxometalate‐Integrated Frameworks: Syntheses, Properties, and Applications
This review systematically summarizes the integration of polyoxometalates with covalent organic frameworks, metal‐organic frameworks, hydrogen‐bonded organic frameworks, and emerging porous hosts. It highlights synergistic effects, synthesis strategies, and applications in catalysis, energy storage, sensing, and biomedicine, while addressing current ...
De‐Yin Wang +6 more
wiley +1 more source
Organocatalytic Enantioselective [4 + 4] Cycloadditions of Furan Ortho‐Quinodimethanes
The first organocatalytic enantioselective [4 + 4] cycloaddition of furan ortho‐quinodimethanes is presented. The reaction proceeds in good yields and with high enantioselectivities allowing for the formation of novel classes of cyclooctanoids. DFT calculations point to an intriguing mechanism, where the stereochemical outcome is attributed to ...
Niklas Lawaetz Østergaard +6 more
wiley +2 more sources
Geochemical analysis of Cenozoic fossil conifers at high latitudes: Implications for molecular preservation and environmental change [PDF]
Fossil materials record ancient life and their adapted environment. Arctic plant fossils are critical for our understanding of the Earth’s paleoenvironment when high latitudes were under ice-free conditions.
Witkowski, Caitlyn
core +1 more source

