ChemCatChem, Volume 17, Issue 8, April 15, 2025.We highlight the potential of Lindqvist‐type polyoxometalate (POM)‐based compounds in catalysis, energy, and environmental applications. With their compact, symmetric structures, and reactive surface oxygen atoms, these compounds excel in catalytic oxidation, adsorption/separation, energy storage, and electrocatalysis.
Ailing Gao, Tsukasa Iwano, Sayaka Uchida
wiley +1 more source
Visible‐Light Enabled Synthesis of 1‐Aryl‐3‐Sulfonylmethyl‐1,2,4‐Triazoles by Arylazo Sulfones
Advanced Synthesis &Catalysis, Volume 367, Issue 6, March 18, 2025.Abstract We present a novel and highly efficient method for synthesizing polyfunctionalized 1,2,4‐triazoles. This approach leverages visible light and arylazo sulfones in combination with N‐vinyl amides, in the environmentally friendly solvent ethyl acetate.
Luca Nicchio +5 more
wiley +1 more source
Mn(iii)-Catalyzed Radical Reactions of 1,3-Dicarbonyl Compounds and Cyclopropanols with Vinyl Azides for Divergent Synthesis of Azaheterocycles [PDF]
, 2012 Mn(iii)-catalyzed formal [3+2]- and [3+3]-annulations have been developed using readily available vinyl azides with 1,3-dicarbonyl compounds and cyclopropanols. Vinyl azides were successfully applied as a three-atom unit including one nitrogen to prepare
Chiba, Shunsuke
core +2 more sources
Synthesis and crystal structures of new chiral 3-amino-2H-azirines and the Pd complex of one of them. [PDF]
Acta Crystallogr C Struct Chem, 2023 Linden A +4 more
europepmc +1 more source
Photochemical Synthons as Advanced Tools in Macromolecular Science [PDF]
, 2019 Die Kombination aus Polymerchemie und lichtinduzierten Verknüpfungsreaktionen zeigt sich als mächtiger Zusammenschluss, um innovative Materialien für eine Vielzahl von Herausforderungen zu erschließen.
Offenloch, Janin Tanja
core +2 more sources
Copper-Catalyzed Highly Enantioselective Addition of a Silicon Nucleophile to 3-Substituted 2H-Azirines Using an Si-B Reagent. [PDF]
Angew Chem Int Ed Engl, 2023 Zhao ZY, Cui M, Irran E, Oestreich M.
europepmc +1 more source
An overview on the N-heterocyclic carbene-catalyzed Aza-Benzoin condensation reaction [PDF]
, 2018 The N-heterocyclic carbene(NHCs)-catalyzed aza-benzoin condensation reaction is an efficient, single step strategy which employs easily available substrates, such as aldehydes and imines, to provide \u3b1-amino ketones.
D.C. Albanese, N. Gaggero
core +1 more source
Copper(II)-Catalyzed (3+2) Cycloaddition of 2H-Azirines to Six-Membered Cyclic Enols as a Route to Pyrrolo[3,2-c]quinolone, Chromeno[3,4-b]pyrrole, and Naphtho[1,8-ef]indole Scaffolds. [PDF]
Molecules, 2022 Sakharov PA +3 more
europepmc +1 more source
Highly Enantioselective Reductions of 2H-Azirines
Herein, we present the first highly enantioselective reduction of mono- and tri- substituted 2H-azirines mediated by a chiral copper-hydride complex. The reaction tolerates both alkylated and arylated 2H-azirines to afford free N-H aziridines in excellent yield (up to 96%) and enantioselectivity (up to 96% ee). A key finding was the stark difference in
Yinuo Zheng +4 more
openaire +1 more source
Enumeration of saturated and unsaturated substituted N-heterocycles
, 2023 Mathematical and computational approaches in chemistry and biochemistry fill a gap in respect to the analysis of the physicochemical features of compounds and their functionality and provide an overview of known as well as yet unknown, but hypothetically
Malycheva, Tatjana, Schuster, Stefan
core