Preparation of spirocyclic oxindoles by cyclisation of an oxime to a nitrone and dipolar cycloaddition. [PDF]
Ritchie BL, Longcake A, Coldham I.
europepmc +1 more source
Fluorinated Para-Quinone Monoacetal: Versatile Reactivity for Constructing Functionalized Scaffolds. [PDF]
Azami K, Morita M, Suzuki K, Ohmori K.
europepmc +1 more source
Skeletal Editing of Alkenes with Nitroarenes via Photoinduced Rearrangement of N─O═C Dipoles Forms Lactams and Amides. [PDF]
Qin H +7 more
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Recent advances of azomethine ylides for the synthesis of natural and synthetic bioactive pyrrolidines and spiropyrrolidines. [PDF]
Paira P +4 more
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Enantioselective Construction of Fluorinated Tertiary Stereocenters by Rh-Catalyzed [2 + 2 + 2] Cycloaddition of 1,6-Enynes with α-Fluoroacrylamides. [PDF]
Hamada S, Sato Y, Komiya Y, Tanaka K.
europepmc +1 more source
Nanoparticle-Catalysed 1,3-Dipolar Cycloadditions [PDF]
The 1,3-dipolar cycloadditions of azomethine-ylides and -imines, nitrones, nitrilimines, and azides catalysed by inorganic nanoparticles are described.
Giorgio Molteni, Alessandro Ponti
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Stereoselective Photoredox Catalyzed (3+3) Dipolar Cycloaddition of Nitrone with Aryl Cyclopropane
Angewandte Chemie, 2023AbstractBy resorting to the principle of remote activation, we herein demonstrate the first photoredox catalyzed (3+3) dipolar cycloaddition of nitrones with aryl cyclopropanes. Key to the fidelity of the reaction resides in a facile manner of substrate activation by single‐electron transfer (SET) oxidation with photoredox catalysis, and the reaction ...
Yao Xu +6 more
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Stereoselective Intramolecular 1,3-Dipolar Cycloadditions
An in depth account of intramolecular 1,3-dipolar cycloadditions involving dipoles such as nitrile oxides, silyl nitronates, H-nitrones, azides, and nitrilimines is presented with particular emphasis on the stereochemistry during the cyclo addition ...
Irishi N N Namboothiri, Alfred Hassner
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1,3-Dipolar Cycloadditions of MeOPEG-Bounded Azides
1,3-Dipolar cycloadditions of MeOPEG-supported azide 2 with a variety of dipolarophiles have been studied. 1-MeOPEGsupported 1,2,3-triazoles 4 and 5, 1,2,3,4-tetrazoles 12 and aziridine 14 were obtained in nearly quantitative yields. The removal of the
Giorgio Molteni, Paola del Buttero
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New Parabanate Products by 1, 3-Dipolar Cycloaddition Reaction (‘Criss-Cross’ Cycloaddition)
High Performance Polymers, 1999New parabanate products containing 1, 3, 5, 7-tetraazabicyclo[3, 3, 0]octane-2, 6-dione are described. The synthesis of αω-diisocyanato-telechelics starting from two diisocyanates having a preformed parabanic unit using a [3+2] dipolar cycloaddition reaction was studied.
Adrian A Caraculacu +2 more
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