Results 61 to 70 of about 18,239,073 (189)

Structural and mutational analysis of Methanosarcina mazei prenylated FMN synthase reveals the basis of its unique prenyl donor substrate specificity

open access: yesThe FEBS Journal, EarlyView.
Some prenylated flavin mononucleotide (prFMN) synthases exceptionally prefer dimethylallyl phosphate (DMAP) over dimethylallyl diphosphate (DMAPP), which is a common prenyl donor substrate for many prenyltransferases. Structural and mutagenic analyses of Methanosarcina mazei prFMN synthase, which prefers DMAP but can also accept DMAPP, elucidated its ...
Sou Fukuhara   +5 more
wiley   +1 more source

1, 3-Dipolar Cycloaddition of Diazomethane with Carbon-Carbon Unsaturated Systems Involving Nitrofuran Ring

open access: yesJournal of Synthetic Organic Chemistry, Japan, 1968
1, 3-Dipolar cycloaddition reaction of diazomethane with 5-nitro-2-furylacrylic acid gave 4- (5'-nitro-2'-furyl) -3-carbomethoxypyrazoline (3), mp 184485°C, in 80% yield. A similar reaction with 5-nitro-2-furylpropiolic acid afforded the corresponding isomeric mixture of the 2-pyrazole derivatives in 25% yield. (1) was refluxed in toluene to afford 2- (
SASAKI, Tadashi, SHOJI, Katsuhiko
openaire   +3 more sources

Fused 1,5-benzothiazepines from o-aminothiophenol and its derivatives as versatile synthons

open access: yesActa Chimica Slovenica, 2014
This review describes the reactions of o-aminothiophenol and its derivatives as building blocks for the synthesis of polyfunctionalised 1,5-benzothiazipines with pharmacological interest.
Batchu Chandra Sekhar
doaj  

Recent Applications of Propylene Carbonate as a Solvent in Sustainable Organic Synthesis

open access: yesChemSusChem, Volume 19, Issue 17, 14 September 2026.
This review evaluates propylene carbonate (PC) as a non‐toxic green solvent in organic synthesis, highlighting its performance in key reactions including cross‐couplings, asymmetric hydrogenations, peptide synthesis and biocatalysis. Across these processes, PC delivers yields comparable to conventional and alternative green solvents.
Laura G. Aguilar‐Sanchez   +1 more
wiley   +1 more source

Azaporphyrinoid‐Based Photo‐ and Electroactive Architectures for Advanced Functional Materials

open access: yesAdvanced Materials, Volume 38, Issue 51, 11 September 2026.
A long‐standing collaboration between the Torres and Guldi groups has yielded diverse azaporphyrinoid‐based donor‐acceptor nanohybrids with promising applications in solar energy conversion. This conspectus highlights key molecular platforms and structure‐function relationships that govern light and charge management, supporting the rational design of ...
Jorge Labella   +3 more
wiley   +1 more source

Alkoxyallenes in Modern Synthesis: Reactivity, Catalysis, and Complexity Generation

open access: yesAdvanced Synthesis &Catalysis, Volume 368, Issue 17, 1 September 2026.
The last decade has witnessed a remarkable transformation in alkoxyallene chemistry. Although historically employed as synthetic equivalents of acrolein or as versatile 3C synthons, alkoxyallenes are now increasingly recognized as highly adaptable platforms for synthetic design.
A. Lanfranco   +5 more
wiley   +1 more source

Intramolecular 1,3-Dipolar Cycloadditions of Norbornadiene-Tethered Nitrile Oxides

open access: yes, 2016
Efficient routes to the synthesis of norbornadiene-tethered nitrile oxides have been developed, and their intramolecular 1,3-dipolar cycloadditions were studied.
Geoffrey K. Tranmer (2520547)   +3 more
core   +1 more source

Die Jekyll‐und‐Hyde‐Natur von Tetrazolen in der Polymerwissenschaft: Von der intrinsischen elektronischen Dualität zur programmierbaren makromolekularen Funktion

open access: yesAngewandte Chemie, Volume 138, Issue 36, 1 September 2026.
Ein Heterocyclus – drei elektronische Identitäten. Dieses Minireview zeigt, wie das Substitutionsmuster von Tetrazolen deren Funktion in Polymeren bestimmt und eröffnet substitutionsdefinierte Designprinzipien für funktionelle Polymermaterialien. ZUSAMMENFASSUNG Die Natur vereint Stabilität und Responsivität in einzelnen molekularen Gerüsten und ...
Meryem S. Akdemir, Hatice Mutlu
wiley   +1 more source

The Jekyll and Hyde Nature of Tetrazoles in Polymer Science: From Intrinsic Electronic Duality to Programmable Macromolecular Function

open access: yesAngewandte Chemie International Edition, Volume 65, Issue 36, 1 September 2026.
Tetrazoles are reframed as substitution‐programmable heterocycles rather than static functional groups in polymer chemistry. By linking electronic identity to synthetic strategy and polymer architecture, this mini‐review establishes a design framework for translating tetrazole duality into predictable macromolecular function.
Meryem S. Akdemir, Hatice Mutlu
wiley   +1 more source

1,3‐Dipolar Cycloaddition of Nitroalkanes as a Tool of DOS/LOS‐Like Strategy for the Synthesis of Isoxazoles and Isoxazolines

open access: yesChemistryEurope, Volume 4, Issue 9, September 2026.
A broadly applicable synthetic platform based on a DOS/LOS‐like strategy is implemented for the case of sp3‐enriched isoxazole/isoxazoline building blocks. The method is based on a [3+2] cycloaddition of nitroalkanes and various alkenes or alkynes. The utility of the proposed approach is illustrated by the discovery of JAK2‐selective inhibitors.
Bohdan A. Chalyk   +12 more
wiley   +1 more source

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