Results 41 to 50 of about 88,292,358 (173)

Highly Efficient and Diastereoselective Synthesis of New Pyrazolylpyrrolizine and Pyrazolylpyrrolidine Derivates by a Three-Component Domino Process

open access: yesMolecules, 2014
Diastereoselective reactions between 4-formylpyrazoles, N-substituted maleimides and glycine derivates led to new series of pyrazolyldipyrrolo [3,4-a:3',4'-f]pyrrolizines and pyrazolylpyrrolo[3,4-c]pyrroles in good yields.
Jairo Quiroga   +6 more
doaj   +1 more source

The Fragmentation of 2,3-Dihydroisothiazol-3-one 1,1-Dioxide Derivatives: A Novel Cheletropic Process

open access: yesCHIMIA, 1992
Adducts obtained by 1,3-dipolar cycloadditions to 2,3-dihydroisothiazol-3-one 1,1-dioxides are inclined to undergo a cheletropic process, by which the newly formed heterocyclic part undergoes aromatization, while SO2 is extruded and an ...
Kaspar F. Burri
doaj   +2 more sources

Enabling Cross‐Coupling Reactivity of α‐Pentafluorosulfanyl Compounds with a Thermally Stable Organozinc α‐SF5 Reagent

open access: yesChemistry – A European Journal, EarlyView.
This work describes the first example of a thermally stable α‐SF5 organometallic reagent, which allows for extensive downstream functionalization by allylation and acylation reactions under copper catalysis, as well as palladium‐catalyzed Negishi‐type cross‐coupling conditions up to 96% yield. In silico analysis shines initial light on the requirements
Lujie Xu, David Rombach
wiley   +1 more source

Central sp3‐C Substitution Directs Supramolecular Assembly and Molecular Properties of Tris‐HBC Nanographenes

open access: yesChemistry – A European Journal, EarlyView.
Central sp3‐C substitution (─H, ─OH, ─CH3, ─OCH3, and ─OC2H5) directs supramolecular packing in tris‐HBC (hexa‐peri‐hexabenzocoronene) nanographenes, yielding diverse layered and porous architectures via modulation of intermolecular interactions. Comprehensive Raman, NMR, photophysical, and electrochemical analyses, supported by DFT/TD‐DFT calculations,
Panchami Mukund Hirave   +4 more
wiley   +1 more source

Intramolecular 1,3-Dipolar Cycloadditions of Norbornadiene-Tethered Nitrones†

open access: yes, 2016
Efficient routes to the synthesis of norbornadiene-tethered nitrones have been developed, and their intramolecular 1,3-dipolar cycloadditions were studied.
Geoffrey K. Tranmer (2520547)   +1 more
core   +2 more sources

Stereoselective synthesis of fused tetrahydroquinazolines through one-pot double [3 + 2] dipolar cycloadditions followed by [5 + 1] annulation

open access: yesBeilstein Journal of Organic Chemistry, 2016
The one-pot [3 + 2] cycloaddition of an azomethine ylide with a maleimide followed by another [3 + 2] cycloaddition of an azide with the second maleimide gives a 1,5-diamino intermediate which is used for a sequential aminomethylation reaction with ...
Xiaofeng Zhang   +6 more
doaj   +1 more source

Photochemical Generation and Spectroscopic Characterization of Parent 3‐Iminooxetane and 3‐Oxazoline From 3‐Azidooxetane

open access: yesChemistry – A European Journal, EarlyView.
Two previously uncharacterized heterocyclic imines, 3‐iminooxetane and 3‐oxazoline, are generated simultaneously by irradiation of 3‐azidooxetane under matrix isolation conditions. The infrared spectra provide reference data for future gas‐phase studies and may facilitate their search in the interstellar medium.
Mika Maehara   +4 more
wiley   +1 more source

1 : 3 Dipolar Cycloaddition of Benzonitrile Oxide on to Cinnamyl Arylamines

open access: yes, 1971
1:3 Dipolar Cycloaddition of Benzonitrile Oxide on to Cinnamyl Arylamines.
Mohan, Suresh   +2 more
openaire   +2 more sources

Photocatalyst‐Free Trifluoromethylation of Indolizines Through an Electron Donor–Acceptor Complex

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
A new photocatalyst‐free pathway for the direct C‐3‐trifluoromethylation of indolizines and imidazo[1,2‐a]pyridines through an electron donor–acceptor (EDA) complex is studied. This regioselective reaction supports a wide range of functional groups, indicating good versatility and robustness.
Corinne Coutant   +7 more
wiley   +1 more source

Photocatalysis‐Triggered Click Reactions and Applications

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Photoclick chemistry offers broad applications ranging from materials science to bioconjugation, with precise spatiotemporal control over click reactions. Initially limited to UV activation, recent advances have extended photoclick processes to the visible and NIR regions thanks to the photocatalysis.
Margaux Walter   +2 more
wiley   +1 more source

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