Results 31 to 40 of about 30,353 (185)

Robust β‐myrcene block copolymer elastomeric vitrimers

open access: yesPolymer International, EarlyView.
Myrcene‐based vitrimeric elastomers were compared: statistical (poly(styrene‐stat‐myrcene‐stat‐AAEMA)] versus ‘hard–soft’ diblock (poly(styrene)‐block‐poly(myrcene‐co‐AAEMA)). The diblock's ability to anchor the glassy poly(styrene) blocks in a self‐assembled microstructure was effective – leading to four times higher tensile stress and ten times ...
Chong Yang Du   +2 more
wiley   +1 more source

Olefin Polymerizations Oriented by Rational Designs of Group‐13 Compounds

open access: yesThe Chemical Record, EarlyView.
In coordination olefin polymerization chemistry, boron and aluminum compounds play important roles in both catalyst components and monomers. This personal account introduces our recent progress on the development of catalyst systems featured by the design of group‐13 counteranions, as well as the application of boronic acid‐crosslinked polyolefins to ...
Ryo Tanaka, Yu Zou
wiley   +1 more source

Influence of external nitrogen-containing donors on polymerization behavior of neodymium-based cis-1,4-polybutadiene rubber

open access: yesHecheng xiangjiao gongye
"Neodymium(Nd)-based catalyst in butadiene (Bd) polymerization has drawn interests due to its availability in affording higher cis-1,4-unit selectivity than transition metal (Ti, Co, Ni, etc.)-based catalysts[1-2].
LI Xin1, DONG Jing2, HAN Zhuo-ling1, WANG Feng1, ZHANG Xue-quan1, LIU Heng1*
doaj   +1 more source

Synthesis and Evaluation of Novel Thermoplastic Elastomers via Anionic Polymerization of Bio‐Based α‐Methyl‐p‐Methylstyrene

open access: yesJournal of Polymer Science, Volume 64, Issue 3, Page 743-751, 1 February 2026.
Bio‐based PAMMS‐PI‐PAMMS triblock copolymers prepared via sequential anionic polymerization display widely tunable tensile behavior. Variation of the block composition enables systematic control of strength and extensibility, offering a sustainable platform for thermoplastic elastomers. ABSTRACT In this study, we examined novel thermoplastic elastomers
Goki Hattori   +3 more
wiley   +1 more source

Controlled synthesis of neodymium-based cis-1,4-polybutadiene rubber bearing polystyrene microblock

open access: yesHecheng xiangjiao gongye
A series of neodymium-based cis-1,4-polybutadiene rubbers bearing polystyrene microblocks were prepared by adding styrene monomer in aging stage of neodymium-based catalyst, the effects of different styrene amount on the polyme-rization behavior and ...
ZHENG Hao, WANG Feng, ZHANG Xue-quan, LIU Heng
doaj   +1 more source

Optimizing Epoxy Vitrimer Composites With Sustainable Cellulose Nanofibril Reinforcements: Enhancing Thermal Dimensional Stability While Preserving Dynamic Covalent Behavior

open access: yesPolymer Composites, Volume 47, Issue 1, Page 164-175, 10 January 2026.
A vitrimer nanocomposite based on nanofibrillated cellulose was fabricated using controlled resin infiltration, without the need for any functionalization. It exhibited excellent thermal dimensional stability and recyclability, positioning it as a promising material for next‐generation, eco‐responsible composites and protective coating aligned with ...
Isis Castro‐Cabrera   +3 more
wiley   +1 more source

Structural and Dynamic Origins of Payne Effect Reduction by Steric Stabilization in Silica Reinforced Poly(butadiene) Nanocomposites

open access: yesPolymer Composites, Volume 47, Issue 1, Page 532-542, 10 January 2026.
Steric stabilisation of silica nanoparticles suppresses the Payne effect in poly(butadiene) nanocomposites and enables the thickness of the glassy layer to be quantified with QENS experiments. ABSTRACT Silica nanoparticles in polybutadiene nanocomposites cause significantly hindered polymer dynamics in the form of a glassy layer, which can extend more ...
James M. Hart   +7 more
wiley   +1 more source

Design and Applications of Multi‐Frequency Programmable Metamaterials for Adaptive Stealth

open access: yesAdvanced Functional Materials, Volume 36, Issue 5, 15 January 2026.
This article provides a comprehensive overview of metamaterials, including their fundamental principles, properties, synthesis techniques, and applications in stealth, as well as their challenges and future prospects. It covers topics that are more advanced than those typically discussed in existing review articles, while still being closely connected ...
Jonathan Tersur Orasugh   +4 more
wiley   +1 more source

Rheological Characterization of Low and High‐Solids‐Loaded Suspensions Using Capillary Rheometry

open access: yesPropellants, Explosives, Pyrotechnics, Volume 51, Issue 1, Page 144-156, January 2026.
ABSTRACT Controlled extrusion of viscous liquids with suspended solids depends critically on rheology. The rheology of a binder (9:1 mass ratio of cellulose acetate butyrate (CAB) to triacetin with a 55 wt.% diethyl ketone balance) loaded with dilute (0–15 wt.%) and concentrated (≥50 wt.%) granulated sugar loadings from three particle size ...
Jiselle Thornby   +7 more
wiley   +1 more source

Designing Oxide Fillers for Advanced Thermal Interface Materials: Recent Progress and Future Perspectives

open access: yesSmall Structures, Volume 7, Issue 1, January 2026.
This review highlights emerging advances in oxide‐based thermal interface materials (TIMs), from fundamental TIM concepts to key oxide fillers and rational design strategies that tailor filler morphology, hybrid architectures, surface chemistry, and 3D networks.
Su‐Jin Ha   +5 more
wiley   +1 more source

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