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ChemInform Abstract: RING TRANSFORMATIONS OF 4H‐PYRANS. PYRIDINES FROM 2‐AMINO‐4H‐PYRANS
Chemischer Informationsdienst, 1981AbstractAus den 2‐Amino‐4H‐pyranen (I) erhält man mit Nitrosylschwefelsäure und Essigsäure die entsprechend substituierten Pyridone (II).
C. SEOANE +3 more
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Structure of 2,4,4,6-tetraphenyl-4H-pyran
Acta Crystallographica Section C Crystal Structure Communications, 1990C 29 H 22 O cristallise dans P2 1 /c avec a=12,128, b=12,372, c=14,599A, β=105,57°, Z=4 ; affinement jusqu'a R=0,039. Le cycle 4H-pyrane est rigoureusement plan avec les cycles phenyl substitues sur les atomes C(sp 2 ) de C2 et C6. Le cycle presente une conformation bateau legerement tordue avec les angles bateau de 4,3 et 7,7° sur C(sp 2 ) et O ...
J. Vojtěchovský, J. Hašek
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Cyclopropanation of areno-condensed 4H-pyrans with dihalocarbenes
Chemistry of Heterocyclic Compounds, 2020The addition of dihalocarbenes to 1H-benzo[f]chromenes and 4H-chromenes gave a number of dihalotetrahydro(benzo)cyclopropa[b]-chromenes containing donor and acceptor substituents at different positions. It was found that in the case of 1,3-disubstituted 1H-benzo[f]-chromenes, the reaction proceeds diastereoselectively with the formation of trans ...
Irina А. Semenova +4 more
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Collection of Czechoslovak Chemical Communications, 1987
Base-catalyzed addition of β-dicarbonyl compounds to methylenemalonaldehydes led to tetracarbonyl compounds II which were dehydrated in an acid medium to 4H-pyran-5-carboxaldehydes III. In the addition of compounds containing a nitrile group, the primarily formed addition products were immediately cyclized to give directly 2-amino-4H-pyran-5 ...
Dalimil Dvořák +4 more
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Base-catalyzed addition of β-dicarbonyl compounds to methylenemalonaldehydes led to tetracarbonyl compounds II which were dehydrated in an acid medium to 4H-pyran-5-carboxaldehydes III. In the addition of compounds containing a nitrile group, the primarily formed addition products were immediately cyclized to give directly 2-amino-4H-pyran-5 ...
Dalimil Dvořák +4 more
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2,4,6-Triphenyl-4H-pyran-3,5-dicarboxaldehyde
Acta Crystallographica Section C Crystal Structure Communications, 1996The structure of 2,4,6-triphenyl-4H-pyran-3,5-dicarboxaldehyde, C25H18O3, a potential fungicide, has a pyran ring in a flattened boat conformation, but with C4 and O3 displaced from the basal plane by 0.299 and 0.159 A, respectively. The aldehyde groups display an ap orientation with respect to the double bonds of that plane.
S. Selladurai +5 more
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Synthesis and properties of 3-formyl-4H-pyrans
Chemistry of Heterocyclic Compounds, 1990The Vilsmeier formylation of 4H-pyrans afforded 3-formyl-4H-pyrans. These were converted to 3-formylpyrylium salts, from which pyridine or pyridine salts with an aldehyde group at C(3) were obtained. The reaction between 3-formyl-4-allyl-4H-pyran and methyltrifluoromethanesulfonate proceeded via a Koop rearrangement.
K. F. Suzdalev, A. V. Koblik
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4-Phenyl-4H-pyrans as IKCa channel blockers
Bioorganic & Medicinal Chemistry Letters, 2003AbstractFor Abstract see ChemInform Abstract in Full Text.
Klaus, Urbahns +3 more
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2009
A series of 3-hydroxy-6-methyl-2-((4-substitutedpiperazin-1-yl)methyl)-4H-pyran-4-on e structured compounds were synthesized by reacting 5-hydroxy-2-methyl-4H-pyran-4-one with suitable piperazine derivatives using Mannich reaction conditions. Antibacterial activities of the compounds for E. coli, S. paratyphi, S. flexneri, E.
Us, Demet +7 more
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A series of 3-hydroxy-6-methyl-2-((4-substitutedpiperazin-1-yl)methyl)-4H-pyran-4-on e structured compounds were synthesized by reacting 5-hydroxy-2-methyl-4H-pyran-4-one with suitable piperazine derivatives using Mannich reaction conditions. Antibacterial activities of the compounds for E. coli, S. paratyphi, S. flexneri, E.
Us, Demet +7 more
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Efficient and Convenient Method for the Synthesis of Poly Functionalised 4H‐Pyrans
Synthetic Communications, 2004AbstractFor Abstract see ChemInform Abstract in Full Text.
B. P. V. Lingaiah +6 more
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Chemischer Informationsdienst, 1977
AbstractDas Dihydropyran (Ia) oder sein 3‐Chlorderivat (Ib) werden lithiiert und die entstandenen Verbindungen (II) mit Alkyljodiden zu den Titelverbindungen (III) umgesetzt.
O. RIOBE, A. LEBOUC, J. DELAUNAY
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AbstractDas Dihydropyran (Ia) oder sein 3‐Chlorderivat (Ib) werden lithiiert und die entstandenen Verbindungen (II) mit Alkyljodiden zu den Titelverbindungen (III) umgesetzt.
O. RIOBE, A. LEBOUC, J. DELAUNAY
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